REMOVAL OF MONOMERIC ALIPHATIC DIISOCYANATE IN AN ALIPHATIC POLYISOCYANATE USING SCAVENGERS

    公开(公告)号:US20220403207A1

    公开(公告)日:2022-12-22

    申请号:US17770309

    申请日:2020-10-23

    Applicant: BASF SE

    Abstract: The present invention relates to a process for the effective removal of residual monomeric aliphatic isocyanate from a reaction mixture comprising aliphatic polyisocyanate comprising (i) providing a reactor containing a scavenger comprising a zeolitic material, wherein the zeolitic material comprises SiO2 and optionally X2O3 in its framework structure, wherein X is a trivalent element; (ii) providing a reaction mixture comprising aliphatic polyisocyanate and monomeric aliphatic isocyanate; (iii) contacting the scavenger in the reactor with the reaction mixture provided in (ii) at a temperature lower than the boiling point of the residual monomeric aliphatic isocyanate for obtaining a product comprising aliphatic polyisocyanate with a reduced monomeric aliphatic isocyanate content, wherein if the zeolitic material comprises X2O3, the zeolitic material has an SiO2 to X2O3 molar ratio higher than 2.8:1, preferably higher than 5:1, more preferably higher than 30:1.

    PREPARATION OF POLYISOCYANATES HAVING ISOCYANURATE GROUPS AND THEIR USE
    17.
    发明申请
    PREPARATION OF POLYISOCYANATES HAVING ISOCYANURATE GROUPS AND THEIR USE 有权
    具有异氰酸酯基团的聚异氰酸酯的制备及其使用

    公开(公告)号:US20130303758A1

    公开(公告)日:2013-11-14

    申请号:US13889603

    申请日:2013-05-08

    Applicant: BASF SE

    Abstract: The present invention relates to a novel process for preparing polyisocyanates having isocyanurate groups by a partial trimerization of (cyclo)aliphatic diisocyanates in the presence of at least one trimerization catalyst from the group of ammonium salts of lactames and to the use of the thus obtainable polyisocyanates having isocyanurate groups as a polyisocyanate component in polyurethane coatings.

    Abstract translation: 本发明涉及一种制备具有异氰脲酸酯基团的多异氰酸酯的新方法,所述多异氰酸酯基通过(环)脂族二异氰酸酯在至少一种三聚化催化剂存在下由内酯类的铵盐进行部分三聚反应,以及使用如此获得的多异氰酸酯 在聚氨酯涂料中具有异氰脲酸酯基团作为多异氰酸酯组分。

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