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公开(公告)号：CA3086353A1
公开(公告)日：2019-06-27
申请号：CA3086353
申请日：2018-12-11
Applicant: BASF SE
Inventor： JACOBMEIER OLAF , KALUSCHKE TOBIAS , RENNER CHRISTIAN , THATER MICHAEL
Abstract: The present invention relates to a method for producing polyurethane hard foam composite elements containing at least one top layer and a polyurethane hard foam layer, in which method (a) polyisocyanates are mixed with (b) compounds comprising at least two hydrogen atoms reactive with isocyanate groups, optionally (c) flame retardant, (d) propellant, (e) catalyst, and optionally (f) auxiliaries and additives to form a reaction mixture, which reaction mixture is applied to the top layer and cures to form the polyurethane hard foam. The component (b) contains at least one polyether alcohol (b1), produced by alkoxylation of a starter or a starter mixture having a mean functionality of 4 to 8 and a hydroxyl number in the range between 300 and 600 mg KOH/g, at least one aromatic Mannich condensate (b2), which can be alkoxylated, producible by reacting an aromatic compound, which at an aromatic ring carries at least one hydroxyl group and/or at least one -NHR group, where R is any organic group or hydrogen, with one or more aldehydes and/or ketones and one or more primary or secondary amines, and at least one aromatic polyester polyol (b3). The proportion of aromatic Mannich condensate is more than 5% by weight to less than 20% by weight, in relation to the total weight of component (b). The present invention further relates to a polyurethane hard foam composite element that can be obtained in accordance with such a method.
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公开(公告)号：PL2900719T3
公开(公告)日：2017-05-31
申请号：PL13762135
申请日：2013-09-16
Applicant: BASF SE
Inventor： KAMPF GUNNAR , JACOBMEIER OLAF , KALUSCHKE TOBIAS , KÖNIG CHRISTIAN
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13.发明专利
公开(公告)号：AU2013322927A1
公开(公告)日：2015-04-09
申请号：AU2013322927
申请日：2013-09-16
Applicant: BASF SE
Inventor： KAMPF GUNNAR , JACOBMEIER OLAF , KALUSCHKE TOBIAS , KONIG CHRISTIAN
Abstract: The invention relates to a method for producing rigid polyurethane or polyisocyanurate foams, having the step of reacting A) at least one polyisocyanate, B) at least one fatty-acid modified polyether polyol, C) at least one polyether polyol, D) optionally one or more polyols which differ from those of components B) and C), E) optionally one or more flame retardants, F) one or more propellants, G) one or more catalysts, and H) optionally other auxiliary agents and/or additives. The invention is characterized in that component C) is obtained using a method having the steps of c1) reacting ortho- tolylenediamine and optionally other co-starters with at least one alkylene oxide comprising ethylene oxide, the content of ethylene oxide being more than 20 wt.% relative to the quantity by weight of the alkylene oxides, and then c2) reacting the reaction product from step c1) with at least one alkylene oxide comprising propylene oxide in the presence of a catalyst, the content of 1,2-propylene oxide being more than 20 wt.% relative to the quantity by weight of the alkylene oxides. The invention further relates to the polyol components comprising the aforementioned components B) and C) and optionally D), E), F), G), and H).
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14.发明专利
公开(公告)号：PL3105274T3
公开(公告)日：2018-08-31
申请号：PL15702428
申请日：2015-01-27
Applicant: BASF SE
Inventor： KALUSCHKE TOBIAS , KAMPF GUNNAR
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Patent Agency Ranking
公开(公告)号：PL3036267T3
公开(公告)日：2018-03-30
申请号：PL14750724
申请日：2014-08-12
Applicant: BASF SE
Inventor： KALUSCHKE TOBIAS , KAMPF GUNNAR
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公开(公告)号：LT3036267T
公开(公告)日：2017-12-27
申请号：LT14750724
申请日：2014-08-12
Applicant: BASF SE
Inventor： KALUSCHKE TOBIAS , KAMPF GUNNAR
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17.发明专利
公开(公告)号：ZA201502823B
公开(公告)日：2017-11-29
申请号：ZA201502823
申请日：2015-04-24
Applicant: BASF SE
Inventor： KÖNIG CHRISTIAN , KALUSCHKE TOBIAS , JACOBMEIER OLAF , KAMPF GUNNAR
Abstract: The invention relates to a method for producing rigid polyurethane or polyisocyanurate foams, having the step of reacting A) at least one polyisocyanate, B) at least one fatty-acid modified polyether polyol, C) at least one polyether polyol, D) optionally one or more polyols which differ from those of components B) and C), E) optionally one or more flame retardants, F) one or more propellants, G) one or more catalysts, and H) optionally other auxiliary agents and/or additives. The invention is characterized in that component C) is obtained using a method having the steps of c1) reacting ortho- tolylenediamine and optionally other co-starters with at least one alkylene oxide comprising ethylene oxide, the content of ethylene oxide being more than 20 wt.% relative to the quantity by weight of the alkylene oxides, and then c2) reacting the reaction product from step c1) with at least one alkylene oxide comprising propylene oxide in the presence of a catalyst, the content of 1,2-propylene oxide being more than 20 wt.% relative to the quantity by weight of the alkylene oxides. The invention further relates to the polyol components comprising the aforementioned components B) and C) and optionally D), E), F), G), and H).
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公开(公告)号：ES2615477T3
公开(公告)日：2017-06-07
申请号：ES13762135
申请日：2013-09-16
Applicant: BASF SE
Inventor： KAMPF GUNNAR , JACOBMEIER OLAF , KALUSCHKE TOBIAS , KÖNIG CHRISTIAN
Abstract: Procedimiento para producir espumas rígidas de poliuretano o espumas rígidas de poliisocianurato, el cual comprende la reacción de A) al menos un poliisocianato, B) al menos un poliol de poliéter modificado en el ácido graso, C) al menos un poliol de poliéter, D) eventualmente uno o varios polioles que se diferencian de aquellos de los componentes B) y C), E) eventualmente uno o varios agentes ignífugos, F) uno o varios agentes sopladores, G) uno o varios catalizadores, y H) eventualmente otros adyuvantes y/o aditivos, caracterizado porque el componente C) se obtiene a través de un procedimiento que comprende c1) la reacción de orto - toluileno diamina y eventualmente otros co-iniciadores con al menos un óxido de alquileno que comprende óxido de etileno, donde el contenido de óxido de etileno asciende a más del 20 % n peso, referido a la cantidad en peso de los óxidos de alquileno, y a continuación c2) la reacción del producto de reacción de la etapa c1) con al menos un óxido de alquileno que comprende óxido de propileno, donde el contenido de óxido de 1,2 -propileno asciende a más de 20 % en peso, referido a la cantidad en peso de los óxidos de alquileno, en presencia de un catalizador.
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公开(公告)号：CA2938060A1
公开(公告)日：2015-08-20
申请号：CA2938060
申请日：2015-01-27
Applicant: BASF SE
Inventor： KALUSCHKE TOBIAS , KAMPF GUNNAR
Abstract: The present invention relates to polyester polyols that are obtained or obtainable by means of esterification of from 10 to 70 mol-% of at least one compound selected from the group consisting of terephthalic acid (TPA), dimethyl terephthalate (DMT), polyethylene terephthalate (PET), phthalic acid anhydride (PSA), phthalic acid, and isophthalic acid, of from 0.1 to 30 mol-% of one or more fatty acids and/or fatty acid derivatives, of from 10 to 70 mol-% of one or more aliphatic or cycloaliphatic diols having 2 to 18 C atoms or alkoxylates thereof, of from 5 to 70 mol-% of a polyether polyol, produced by alkoxylation of an aromatic starter molecule having a functionality that is greater than or equal to 2, and of from 0 to 70 mol-% of a tri- or polyol differing from the polyether polyol, in each case relative to the total amount of components employed, with the sum of the amounts of the components employed being 100 mol-%. The present invention further relates to a method for producing polyurethane rigid foams or polyisocyanurate rigid foams comprising the reaction of an isocyanate component with a polyol component (PK) containing a polyester polyol according to the invention and other components, wherein the polyol component as such, as well as the polyurethane rigid foam or polyisocyanurate rigid foam are obtained or obtainable by the method according to the invention. The present invention also relates to the use of a polyester polyol (P1) according to the invention for generating polyurethane rigid foams or polyisocyanurate rigid foams.
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