公开(公告)号：US10000600B2

公开(公告)日：2018-06-19

申请号：US14913640

申请日：2014-08-18

Applicant: BASF SE

Inventor： Daniel Kehrloesser ,  Joost Leswin ,  Daniel Specker ,  Konrad Roschmann ,  Matthias Gerst ,  Harm Wiese

IPC: C08F265/06 ,  C08F285/00 ,  C09D151/00 ,  B01J13/16 ,  C08F265/04

CPC classification number: C08F265/06 ,  B01J13/16 ,  C08F265/04 ,  C08F285/00 ,  C09D7/41 ,  C09D7/42 ,  C09D7/65 ,  C09D7/66 ,  C09D151/003

Abstract: The present invention relates to a process for producing emulsion polymer particles having a core-shell structure, wherein the weight ratio of the shells is within specific limits, and also to their use in paints, paper coatings, foams and cosmetic compositions.

公开(公告)号：US11958992B2

公开(公告)日：2024-04-16

申请号：US16652445

申请日：2018-09-28

Applicant: BASF SE

Inventor： Dirk Wulff ,  Ulrike Licht ,  Thomas Christ ,  Matthias Gerst

IPC: C09J7/35 ,  C08F220/18 ,  C09J133/08 ,  C09J133/10 ,  C08L67/02

CPC classification number: C09J133/08 ,  C08F220/1808 ,  C09J7/35 ,  C09J133/10 ,  C08L67/02 ,  C09J2203/334 ,  C09J2301/416 ,  C09J2427/006 ,  Y10T428/2809 ,  Y10T428/2891 ,  C08F220/1808 ,  C08F220/14 ,  C08F220/14 ,  C08F220/06 ,  C08F220/302

Abstract: Plasticizer migration-resistant, UV-curable hotmelt adhesive for graphics films and labels made of plasticized PVC
Described here is a UV-curable hotmelt adhesive largely resistant to plasticizer migration and comprising a UV-crosslinkable poly(meth)acrylate formed from methyl acrylate, C4-18 alkyl (meth)acrylate, monomer with acid groups, copolymerized photoinitiator and optionally further monomers. The hotmelt adhesive further comprises an aliphatic polyester polymer. The use of the hotmelt adhesive on graphics films and self-adhesive labels made of plasticized PVC is also described.

公开(公告)号：US11174333B2

公开(公告)日：2021-11-16

申请号：US16322612

申请日：2017-07-26

Applicant: BASF SE

Inventor： Andrea Misske ,  Anja Thomas ,  Christoph Fleckenstein ,  Friederike Fleischhaker ,  Szilard Csihony ,  Matthias Gerst ,  Stephan Moebius ,  Ulrike Licht ,  Andreas Schwarz ,  Eric Neuhaus

IPC: C08F290/04 ,  C08F120/30 ,  C08F2/22 ,  C08F220/30 ,  C08F220/14

Abstract: The present invention describes novel macromonomers containing polyisobutene groups and homo- or copolymers thereof.

公开(公告)号：US10344190B2

公开(公告)日：2019-07-09

申请号：US15326369

申请日：2015-07-13

Applicant: BASF SE

Inventor： Lisa Houillot ,  Valerie Wilms ,  Paola Uribe Arocha ,  Maximillian Ruellmann ,  Matthias Gerst

IPC: C09J103/02 ,  C08L3/02 ,  C08L33/08 ,  C09J4/00 ,  C09J105/00 ,  C09J133/06 ,  C09J101/02 ,  C09J133/08 ,  C08L33/06

Abstract: The present invention relates to a polymer dispersion comprising A) at least one first phase comprising a) at least one chain growth addition polymer P constructed from 1 to 99.9 wt % of at least one ester from ethylenically unsaturated monomers, as monomer A, 0 to 20 wt % of at least one ethylenically unsaturated carbonitrile, as monomer B, 0.1 to 5 wt % of at least one acid-functional ethylenically unsaturated monomer, as monomer C, 0 to 5 wt % of at least one monomer which, alone or with a crosslinking agent, has crosslinking effect and which is different from the monomers A to C, as monomer D, 0 to 20 wt % of at least one ethylenically unsaturated monomer which forms a chain growth addition homopolymer having a glass transition temperature ≥50° C. and which is different from the monomers A to D, as monomer E, the sum of the total amount of the monomers A to E making 100 wt %, a1) optionally at least one polymer seed, b) 10 to 60 parts by weight, based on 100 parts by weight of polymer P, of at least one saccharide compound S, and B) a second phase comprising c) at least one solvent. The present invention also relates to a method for producing the polymer dispersion of the invention, to a polymerization powder, to an adhesive bonding formulation comprising the polymer dispersion of the invention, and to the use of the formulation of the invention as an adhesive.

公开(公告)号：US09574077B2

公开(公告)日：2017-02-21

申请号：US14987394

申请日：2016-01-04

Applicant: BASF SE

Inventor： Matthias Gerst ,  Gerhard Auchter ,  Gledison Fonseca ,  Cornelis Petrus Beyers

IPC: C08F2/16 ,  C08L19/02 ,  C08L25/04 ,  C08L33/12 ,  C08F220/12 ,  C09J133/06

CPC classification number: C08L33/12 ,  C08F220/12 ,  C08L25/04 ,  C09J133/066 ,  Y10T428/2852

Abstract: The present invention relates to aqueous polymer dispersions having a polymer content of at least 55% by weight that are suitable for pressure sensitive adhesives. The invention also relates to a process for preparing these aqueous polymer dispersions and also to the use of the aqueous polymer dispersions in pressure sensitive adhesives and, respectively, pressure sensitive adhesive compositions, especially in pressure sensitive adhesives for transparent substrates, such as plastics labels. The aqueous polymer dispersions have a polymer content of at least 55% by weight, based on the total weight of the dispersion, the polymer being composed of ethylenically unsaturated monomers M and having a glass transition temperature below −10° C., in which the dispersed polymer particles have a polymodal particle size distribution, in which at least 70% by weight have a particle diameter of below 350 nm.

Abstract translation: 本发明涉及聚合物含量为至少55重量％的聚合物分散体，其适用于压敏粘合剂。 本发明还涉及一种制备这些含水聚合物分散体的方法，还涉及使用压敏粘合剂中的聚合物水分散体和压敏粘合剂组合物，特别是用于透明基材例如塑料标签的压敏粘合剂。 聚合物水分散体的聚合物含量至少为55重量％，基于分散体的总重量，聚合物由烯键式不饱和单体M组成并具有低于-10℃的玻璃化转变温度，其中 分散的聚合物颗粒具有多晶粒度分布，其中至少70重量％的粒径小于350nm。

公开(公告)号：US20150122418A1

公开(公告)日：2015-05-07

申请号：US14405732

申请日：2013-05-29

Applicant: BASF SE

Inventor： Matthias Gerst ,  Michael Gross ,  Rafael Galvan

IPC: C09J133/14 ,  C08K3/28 ,  B32B37/12

CPC classification number: C09J133/08 ,  B32B37/12 ,  B32B2037/1269 ,  B32B2333/08 ,  C08F2/06 ,  C08K3/28 ,  C08L33/08 ,  C09J5/00 ,  C09J133/02 ,  C09J133/14 ,  C09J2433/00 ,  C08F2220/1825 ,  C08F220/14 ,  C08F220/06 ,  C08F2222/1013 ,  C08F2220/1858

Abstract: Disclosed herein are compositions comprising a first copolymer derived from monomers comprising a (meth)acrylate monomer, an acid monomer, and optionally at least one additional monomer selected from the group consisting of styrene, α-methyl-styrene, vinyl toluene, and mixtures thereof, wherein the first copolymer is derived in the absence of a molecular weight regulator and wherein the first copolymer has a weight average molecular weight of less than 10,000 Daltons, and methods of making the same. The compositions and methods disclosed can be used, for instance, in pressure-sensitive adhesive applications.

Abstract translation: 本文公开了包含衍生自包含（甲基）丙烯酸酯单体，酸单体和任选的至少一种选自苯乙烯，α-甲基 - 苯乙烯，乙烯基甲苯及其混合物中的至少一种另外的单体的单体的第一共聚物的组合物 其中第一共聚物是在不存在分子量调节剂的情况下衍生的，其中第一共聚物的重均分子量小于10,000道尔顿，及其制备方法。 所公开的组合物和方法可以用于例如压敏粘合剂应用中。