公开(公告)号：US12286416B2

公开(公告)日：2025-04-29

申请号：US17423518

申请日：2020-01-17

Applicant: BASF SE

Inventor： Peter Rudolf ,  Indre Thiel ,  Thomas Maximilian Wurm ,  Joaquim Henrique Teles ,  Jan-Dirk Arndt

IPC: C07D327/04

Abstract: Provided is a process for the preparation of a compound with at least one five-membered cyclic monothiocarbonate group. A compound C1 with at least one halohydrin group is used as starting material. Compound C1 is reacted with phosgene or an alkyl chloroformate to give an adduct C2. The adduct C2 is reacted with a compound that includes anionic sulfur to obtain the compound with at least one five-membered cyclic monothiocarbonate group.

公开(公告)号：US11958823B2

公开(公告)日：2024-04-16

申请号：US16639339

申请日：2018-08-07

Applicant: BASF SE

Inventor： Peter Rudolf ,  Indre Thiel ,  Hans-Josef Thomas ,  Hannes Blattmann

IPC: C07D327/04 ,  C08G71/04

CPC classification number: C07D327/04 ,  C08G71/04

Abstract: Object of the invention is a process for the manufacturing of a polymer with urethane groups, wherein in a first alternative A) a five-membered cyclic monothiocarbonate B) a compound with at least two amino groups, selected from primary or secondary amino groups, and C) a compound which at least two functional groups that react with a group —SH or, in case of a carbon-carbon triple bond as functional group that react with a group —SH, a compound with at least one carbon-carbon triple bond are reacted or wherein in a second alternative A) a five-membered cyclic monothiocarbonate and D) a compound with at least one primary or secondary amino group and at least one functional group that reacts with a group —SH.

公开(公告)号：US11292780B2

公开(公告)日：2022-04-05

申请号：US16634255

申请日：2018-08-14

Applicant: BASF SE

Inventor： Bilguun Bayarmagnai ,  Thomas Schaub ,  Verena Mormul ,  Peter Rudolf

IPC: C07D317/40 ,  B01J31/22 ,  C08F124/00 ,  H01M10/0567

Abstract: The present invention relates to a process for preparing cyclic carbonates of formula Ia or Ib or mixtures thereof (Ia) (Ib) comprising the process step: a) reacting a propargylic alcohol of formula II (II) with carbon dioxide in the presence of at least one transition metal catalyst TMC1, which comprises a transition metal selected from metals of groups 10, 11 and 12 of the periodic table of the elements according to IUPAC and at least one bulky ligand.

公开(公告)号：US10889559B2

公开(公告)日：2021-01-12

申请号：US16633870

申请日：2018-08-07

Applicant: BASF SE

Inventor： Peter Rudolf ,  Jan-Dirk Arndt ,  Nicole Holub ,  Verena Mormul ,  Indre Thiel

IPC: C07D327/04 ,  B01J21/06 ,  C07C69/96 ,  C07C323/12

Abstract: Process for the preparation of a compound with at least one monothiocarbonate group by reacting:—a compound with at least one mercaptoalcohol group and—a dialkylcarbonate, in the presence of a catalyst wherein the catalyst is a salt of a metal selected from group IIIb or IVb of the periodic system.

公开(公告)号：US20230340205A1

公开(公告)日：2023-10-26

申请号：US18018534

申请日：2021-07-23

Applicant: BASF SE

Inventor： Bernd BRUCHMANN ,  Peter Rudolf ,  Markus Meise ,  Elliot Christ ,  Juergen Ruehe ,  Tassilo Gleede

IPC: C08G75/045

CPC classification number: C08G75/045

Abstract: A process can be used for preparing a compound A having n groups of formula





(I). In Formula (I), X is C2-C12-alkylene or C2-C12-alkylene substituted with C1-C4-alkoxy, C1-C4-alkylthio, and/or interrupted with O or S; R1, R2, and R3 are independently of one another hydrogen or C1-C4-alkyl: and n is an integer of 1, 2, 3, 4, 5, or 6. The process involves reacting a compound B having n —SH groups with a compound C of formula





(II), in the presence of a free radical generator.

公开(公告)号：US20230094796A1

公开(公告)日：2023-03-30

申请号：US17758683

申请日：2021-01-05

Applicant: BASF SE

Inventor： Thomas SCHAUB ,  Peter Rudolf ,  Ulrike Licht ,  A. Stephen K. Hashmi ,  Saumya Dabral ,  Chloe Johnson

IPC: C07D317/40 ,  B01J31/04 ,  B01J31/18 ,  B01J31/24

Abstract: A process can be used for preparing cyclic carbonates with an exocyclic vinylidene group by reacting a propargylic alcohol with CO2 in the presence of a silver catalyst having at least one bulky ligand a lipophilic carboxylate ligand. After completion of the reaction, the catalyst is separated from the cyclic carbonate by the use of two organic solvents of different polarity and having a miscibility gap. The silver catalyst is enriched in the less polar solvent and the cyclic carbonate in the more polar solvent.

公开(公告)号：US11613524B2

公开(公告)日：2023-03-28

申请号：US16951207

申请日：2020-11-18

Applicant: BASF SE

Inventor： Thomas Schaub ,  Peter Rudolf ,  Ulrike Licht ,  Verena Mormul ,  Saumya Dabral

IPC: C07D317/36 ,  C08F136/20 ,  C09J4/00

Abstract: A compound of formula (I) wherein R1 is hydrogen or an organic radical of 1 to 100 carbon atoms, R2, R3 are independently hydrogen or an organic radical of 1 to 100 carbons, Z is a single bond or a divalent organic group of 1 to 100 carbons, A is an (n+m)-valent organic group of 1 to 1 000 000 carbons, X is a single bond or a divalent organic group of 1 to 40 carbons, n is an integer from 1 to 1000, m is 0, 1, or 2, the sum of n+m being an integer from 2 to 1002. Such compounds are obtainable from specific 4-oxy-but-2-yn-1-ol derivatives, or used as intermediate(s), crosslinker(s), or monomer(s) in polymerization or oligomerization reactions, or for two-component compositions having such compound(s) and multifunctional hardener(s). Such compound(s) may be used to prepare polyunsaturated compounds, by reaction with an (oligo/poly)-functional nucleophile, or polymers.

公开(公告)号：US20220185773A1

公开(公告)日：2022-06-16

申请号：US17594554

申请日：2020-04-23

Applicant: BASF SE

Inventor： Peter Rudolf ,  Elliot Christ ,  Bernd Bruchmann ,  Indre Thiel ,  Thomas Maximilian Wurm

IPC: C07C319/14

Abstract: A process synthesizes a compound with at least one alkylene group and at least one thiol or thiolate group. The process involves reacting a compound with at least one five-membered cyclic monothiocarbonate group with a starter selected from a compound with at least one thiol group, from a compound with at least one hydroxy group, or from a basic inorganic composed; to obtain a compound with at least one alkylene group and at least one thiol or thiolate group and carbon dioxide.

公开(公告)号：US20220073492A1

公开(公告)日：2022-03-10

申请号：US17423518

申请日：2020-01-17

Applicant: BASF SE

Inventor： Peter Rudolf ,  Indre Thiel ,  Thomas Maximilian Wurm ,  Joaquim Henrique Teles ,  Jan-Dirk Arndt

IPC: C07D327/04

Abstract: Provided is a process for the preparation of a compound with at least one five-membered cyclic monothiocarbonate group. A compound C1 with at least one halohydrin group is used as starting material. Compound C1 is reacted with phosgene or an alkyl chloroformate to give an adduct C2. The adduct C2 is reacted with a compound that includes anionic sulfur to obtain the compound with at least one five-membered cyclic monothiocarbonate group.

公开(公告)号：US11247979B2

公开(公告)日：2022-02-15

申请号：US16634230

申请日：2018-08-07

Applicant: BASF SE

Inventor： Peter Rudolf ,  Indre Thiel ,  Markus Jegelka ,  Jan-Dirk Arndt ,  Joaquim Henrique Teles

IPC: C07D327/04 ,  C07D411/12

Abstract: Process for the preparation of a compound with at least one five-membered cyclic monothiocarbonate group wherein a) a compound with at least one epoxy group is used as starting material b) the compound is reacted with phosgene or an alkyl chloroformate thus giving an adduct and c) the adduct is reacted with a compound comprising anionic sulfurthus obtaining the compound with at least one five-membered cyclic monothiocarbonate group.