Abstract:
A method is provided for recovering mercury from a crude oil into an alkaline ammonium sulfide contacting solution. Soluble mercury complexes in the contacting solution are converted to particulate mercury. The particulate mercury can be recovered by filtering, and the ammonium sulfide in the contacting solution recycled to the aqueous contacting solution.
Abstract:
A subsea storage unit (SSU) with a flexible bag (flexible bladder or expandable skin) is used for produced water storage. The use of the SSU allows the solids to settle out in the storage vessel that would otherwise have settled out and accumulated on underwater surfaces, removal of hydrocarbons and the smoothing out of variations in water quality resulting from process upsets. Solids that remain in suspension and exit the SSU will then disperse without any appreciable settlement to be completely dispersed. Accumulated solids can be retrieved with the expandable skin, which can then be replaced for continued service.
Abstract:
Methods and systems relate to the in-situ removal of heavy metals such as mercury, arsenic, etc., from produced fluids such as gases and crudes from a subterranean hydrocarbon-bearing formation. A sufficient amount of a fixing agent is injected into formation with a dilution fluid. The fixing agent reacts with the heavy metals forming precipitate, or is extracted heavy metals into the dilution fluid as soluble complexes. In one embodiment, the heavy metal precipitates remain in the formation. After the recovery of the produced fluid, the dilution fluid containing the heavy metal complexes is separated from the produced fluid, generating a treated produced fluid having a reduced concentration of heavy metals. In one embodiment, the dilution fluid is water, and the wastewater containing the heavy metal complexes after recovery can be recycled by injection into a reservoir.