公开(公告)号：DE2651419A1

公开(公告)日：1978-05-18

申请号：DE2651419

申请日：1976-11-11

Applicant: DEGUSSA ,  HENKEL KGAA

Inventor： STRACK HANS DIPL CHEM DR ,  ROEBKE WOLFGANG DIPL CHEM DR ,  KNEITEL DIETER ,  PARR EHRFRIED

IPC: C11D3/08 ,  C01B39/16 ,  C04B28/08 ,  C11D3/00 ,  C11D3/12 ,  C01B33/26

Abstract: There are produced crystalline zeolite powders of Type A with the composition 1.0+/-0.2 M2/nO:Al2O3:1.85+/-0.5 SiO2.y H2O where M is a metal cation, n is its valence and y has a value up to 6 with 50 weight % of the particles not over 4.9 mu and with a particle spectrum -Fraction ( mu ) Portion (weight %) -

公开(公告)号：CH631946A5

公开(公告)日：1982-09-15

申请号：CH1374577

申请日：1977-11-10

Applicant: DEGUSSA ,  HENKEL KGAA

Inventor： STRACK HANS DR ,  ROEBKE WOLFGANG DR ,  KNEITEL DIETER ,  PARR EHRFRIED

IPC: C11D3/08 ,  B01J20/18 ,  C01B39/16 ,  C04B28/08 ,  C11D3/00 ,  C11D3/12 ,  C01B33/28

公开(公告)号：CH631945A5

公开(公告)日：1982-09-15

申请号：CH1374477

申请日：1977-11-10

Applicant: DEGUSSA ,  HENKEL KGAA

Inventor： STRACK HANS DR ,  ROEBKE WOLFGANG DR ,  KNEITEL DIETER ,  PARR EHRFRIED

IPC: C11D3/08 ,  B01J20/18 ,  C01B39/16 ,  C04B28/08 ,  C11D3/00 ,  C11D3/12 ,  C01B33/28

公开(公告)号：CA1082163A

公开(公告)日：1980-07-22

申请号：CA290584

申请日：1977-11-10

Applicant: DEGUSSA ,  HENKEL KGAA

Inventor： STRACK HANS ,  ROEBKE WOLFGANG ,  KNEITEL DIETER ,  PARR EHRFRIED

IPC: C11D3/08 ,  C01B39/16 ,  C04B28/08 ,  C11D3/00 ,  C11D3/12 ,  B01J29/28

Abstract: The present invention provides a crystalline type-A zeolite powder having the composition1.0 ? 0.2 M2/nO : Al2O3 : 1.85 ? 0.5 SiO2 ? Y H2O. wherein M represents a metal cation, n its valency and y a value of up to 6, and containing 50% by weight of particles of a size below a maximum of 4.9 .mu.m as well as having the following particle spectrum fraction proportion (.mu.m) (% by weight)

公开(公告)号：CA1082162A

公开(公告)日：1980-07-22

申请号：CA289971

申请日：1977-11-01

Applicant: DEGUSSA ,  HENKEL KGAA

Inventor： STRACK HANS ,  ROEBKE WOLFGANG ,  KNEITEL DIETER ,  PARR EHRFRIED

IPC: C11D3/08 ,  B01J20/18 ,  C01B39/16 ,  C04B28/08 ,  C11D3/00 ,  C11D3/12 ,  B01J29/28

Abstract: The present invention provides a crystalline type-A zeolite powder having the composition 1.0 ? 0.2 M2/nO : Al2O3 : 1.85 ? 0.5 SiO2 ? y H2O, wherein M represents a metal cation, n its valency and y a value of up to 6, and containing 50% by weight of particles of a size below a maximum of 4.3 .mu.m as well as having the following particle spectrum The zeolites are useful inter alia as phosphate substitutes in washing, rinsing and cleansing agents.

公开(公告)号：DE2447021A1

公开(公告)日：1976-05-13

申请号：DE2447021

申请日：1974-10-02

Applicant: HENKEL & CIE GMBH ,  DEGUSSA

Inventor： ROEBKE WOLFGANG DIPL CHEM DR ,  KNEITEL DIETER ,  PARR EHRFRIED

IPC: B01J20/18 ,  B01J39/02 ,  B01J39/14 ,  C01B39/16 ,  C02F1/42 ,  C04B28/08 ,  C11D3/08 ,  C11D3/12 ,  C01B33/28 ,  C02B1/40

公开(公告)号：CH631949A5

公开(公告)日：1982-09-15

申请号：CH1374877

申请日：1977-11-10

Applicant: DEGUSSA ,  HENKEL KGAA

Inventor： STRACK HANS DR ,  ROEBKE WOLFGANG DR ,  KNEITEL DIETER ,  PARR EHRFRIED

IPC: C11D3/08 ,  B01J20/18 ,  C01B39/16 ,  C04B28/08 ,  C11D3/00 ,  C11D3/12 ,  C01B33/28

公开(公告)号：CA1083554A

公开(公告)日：1980-08-12

申请号：CA290676

申请日：1977-11-10

Applicant: DEGUSSA ,  HENKEL KGAA

Inventor： STRACK HANS ,  ROEBKE WOLFGANG ,  KNEITEL DIETER ,  PARR EHRFRIED

IPC: C11D3/08 ,  B01J20/18 ,  C01B39/16 ,  C04B28/08 ,  C11D3/00 ,  C11D3/12 ,  B01J29/28

Abstract: The present invention provides a crystalline type-A zeolite powder having the composition 1.0 ? 0.2 M2/nO : Al2O3: 1.85 ? 0.5 SiO2 ? y H2O, wherein M represents a metal cation, n its valency and y a value of up to 6, and containing 50% by weight of particles of a size below a maximum of 5.9 .mu.m as well as having the following particle spectrum. The zeolitic molecular sieves are useful inter alia in washing, cleansing and rinsing agents as substitutes for phosphate.

公开(公告)号：CA1083123A

公开(公告)日：1980-08-05

申请号：CA290655

申请日：1977-11-10

Applicant: DEGUSSA ,  HENKEL KGAA

Inventor： STRACK HANS ,  ROEBKE WOLFGANG ,  KNEITEL DIETER ,  PARR EHRFRIED

IPC: C11D3/08 ,  B01J20/18 ,  C01B39/16 ,  C04B28/08 ,  C11D3/00 ,  C11D3/12 ,  B01J29/28

Abstract: The present invention provides a crystalline type-A zeolite powder having the composition 1.0 ? 0.2 M2/nO : Al2O3 : 1.85 ? 0.5 SiO2 ? y H2O, wherein M represents a metal cation, n its valency and y a value of up to 6, and containing 50% by weight of particles of a size below a maximum of 6.2 .mu.m as well as having the following particle spectrum The zeolitic seive is useful inter alia as a phosphate substitute in the washing, rinsing and cleansing agents.

公开(公告)号：CA1057272A

公开(公告)日：1979-06-26

申请号：CA236911

申请日：1975-10-02

Applicant: DEGUSSA ,  HENKEL KGAA

Inventor： ROEBKE WOLGANG ,  KNEITEL DIETER ,  PARR EHRFRIED

IPC: B01J20/18 ,  B01J39/02 ,  B01J39/14 ,  C01B39/16 ,  C02F1/42 ,  C04B28/08 ,  C11D3/08 ,  C11D3/12 ,  B01J29/28

Abstract: The present invention provides a process for producing an A-type zeolite molecular sieve based on crystalline alumino silicates containing water of hydration and at least 99.5, by weight of particles having diameters smaller than 45 .mu.m by hydrothermal crystallization of an aluminate sodium tetrasilicate synthesis mixture in which the components of the synthesis mixture, which are in a molar ratio of SiO2 : Al2O3 less than 1.9 : 1 and in a molar ratio of water : alkali metal oxide of at least 30 : 1 are intimately mixed prior to the precipitation of an amorphous initial product, and after the crystallization the aluminium silicate suspension is tempered under cryatllizing conditions and is sheared during at least one of the crystallization and the tempering. The A-type zeolitic molecular seive so obtained has 99.5% of the particles with diameters below 45 .mu.m and a defined particle spectrum which makes is particularly useful as an ion exchanger, for example in the softening of water and as a phosphate substitute in detergents.