BISCARBODIIMIDES AND POLYCARBODIIMIDES AND METHOD FOR THEIR PREPARATION
    12.
    发明申请
    BISCARBODIIMIDES AND POLYCARBODIIMIDES AND METHOD FOR THEIR PREPARATION 审中-公开
    双十二碳二亚胺和聚碳二亚胺及其制备方法

    公开(公告)号:WO2017172313A1

    公开(公告)日:2017-10-05

    申请号:PCT/US2017/021385

    申请日:2017-03-08

    Abstract: The present disclosure describes a method of synthesizing carbodiimides comprising providing an alkylisothiourea, providing a thiophilic reagent to the reaction mixture and reacting under conditions sufficient to provide the carbodiimide, and wherein the carbodiimide is a polycarbodiimide or a biscarbodiimide. The present disclosure further describes methods for isolating the carbodiimides. The present disclosure additionally describes isolated carbodiimide compositions.

    Abstract translation:

    本公开描述了合成包括提供alkylisothiourea碳二亚胺,提供亲硫试剂到反应混合物中,并足以提供碳二亚胺的条件下进行反应的方法,并且其中,所述碳化二亚胺是聚碳化二亚胺或双碳二亚胺 。 本公开进一步描述了分离碳二亚胺的方法。 本公开另外描述了分离的碳二亚胺组合物。

    METHODS FOR FORMING 1,3,5,7-TETRAALKYL-6-(2,4-DIMETHOXYPHENYL)-2,4,8-TRIOXA-6-PHOSPHAADAMANTANE

    公开(公告)号:WO2018175671A1

    公开(公告)日:2018-09-27

    申请号:PCT/US2018/023678

    申请日:2018-03-22

    Abstract: A method for forming 1,3,5,7-tetraalkyl-6-(2,4-dimethoxyphenyl)-2,4,8-trioxa-6-phosphaadamantane includes obtaining a solution comprising an ethereal solvent and an aluminum hydride, adding dichloro(2,4-dimethoxyphenyl)phosphine to the solution to produce 2,4-dimethoxyphenylphosphine, and reacting the 2,4-dimethoxyphenylphosphine with an acidic mixture comprising diones to produce 1,3,5,7-tetraalkyl-6-(2,4-dimethoxyphenyl)-2,4,8-trioxa-6-phosphaadamantane. The solution has a temperature from greater than -20 C to 50 C throughout the method. Another method for forming 1,3,5,7-tetraalkyl-6-(2,4-dimethoxyphenyl)-2,4,8-trioxa-6-phosphaadamantane includes obtaining dichloro(2,4-dimethoxyphenyl)phosphine, forming 2,4-dimethoxyphenylphosphine by adding the dichloro(2,4-dimethoxyphenyl)phosphine to a solution comprising at least one solvent and an aluminum hydride, reacting the 2,4-dimethoxyphenylphosphine with a mixture to produce 1,3,5,7-tetraalkyl-6-(2,4-dimethoxyphenyl)-2,4,8-trioxa-6-phosphaadamantane. The mixture includes an acid selected from the group consisting of Lewis acids, sulfonic Bronsted acids, and mixtures thereof, an aromatic or non-aromatic hydrocarbons; and acetylacetone.

    AN OLEFIN POLYMERIZATION CATALYST
    17.
    发明申请
    AN OLEFIN POLYMERIZATION CATALYST 审中-公开
    一种烯烃聚合催化剂

    公开(公告)号:WO2017173074A1

    公开(公告)日:2017-10-05

    申请号:PCT/US2017/025009

    申请日:2017-03-30

    Abstract: An olefin polymerization catalyst system comprising: a procatalyst component comprising a metal-ligand complex of Formula (I) wherein each X is independently a monodentate or polydentate ligand that is neutral, monoanionic, or dianionic, wherein n is an integer, and wherein X and n are chosen such that the metal-ligand complex of Formula (I) is overall neutral; wherein each R1 and R5 independently is selected from (C1-C40)hydrocarbyls, substituted (C1-C40)hydrocarbyls; (C1-C-40)heterohydrocarbyls and substituted (C1-C40)heterohydrocarbyls; wherein each R2 and R4 independently is selected from (C1-C40)hydrocarbyls andsubstituted (C1-C40)hydrocarbyls; wherein R3 is selected from the group consisting of a (C3-C40)hydrocarbylene, substituted (C3-C40)hydrocarbylene, [(C+Si)3-(C+Si)40]organosilylene, substituted [(C+Si)3-(C+Si)40]organosilylene, [(C+Ge)3-(C+Ge)40]organogermylene, or substituted [(C+Ge)3-(C+Ge)40]organogermylene; wherein each N independently is nitrogen; and optionally, two or more R1-5 groups each independently can combine together to form mono-aza ring structures, with such ring structures having from 5 to 16 atoms in the ring excluding any hydrogen atoms.

    Abstract translation: 烯烃聚合催化剂体系,其包含:包含式(I)的金属 - 配体络合物的前催化剂组分,其中每个X独立地为中性,单阴离子或双阴离子的单齿或多齿配体,其中n 是整数,并且其中选择X和n使得式(I)的金属 - 配体络合物总体上是中性的; 其中每个R 1和R 5独立地选自(C 1 -C 40)烃基,取代的(C 1 -C 40)烃基; (C1-C40)杂烃基和取代的(C1-C40)杂烃基; 其中每个R 2和R 4独立地选自(C 1 -C 40)烃基和取代的(C 1 -C 40)烃基; 其中R3选自(C3-C40)亚烃基,取代的(C3-C40)亚烃基,[(C + Si)3-(C + Si)40] (C + Si)40]有机亚甲硅烷基,[(C + Ge)3-(C + Ge)40]有机亚锗烷基或取代的[(C + Ge)3- 其中每个N独立地为氮; 并且任选地,两个或更多个R 1至R 5基团各自独立地可以结合在一起形成单氮杂环结构,其中这样的环结构在环中具有5至16个原子,排除任何氢原子。

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