Abstract:
Embodiments are directed to monophosphaguanidine ligands and the bis ligated metal-complexes formed therefrom, wherein the metal-ligand complexes are polymerization catalysts comprising the following structure (I).
Abstract:
The present disclosure describes a method of synthesizing carbodiimides comprising providing an alkylisothiourea, providing a thiophilic reagent to the reaction mixture and reacting under conditions sufficient to provide the carbodiimide, and wherein the carbodiimide is a polycarbodiimide or a biscarbodiimide. The present disclosure further describes methods for isolating the carbodiimides. The present disclosure additionally describes isolated carbodiimide compositions.
Abstract:
Embodiments of the present application are directed to procatalysts, and catalyst systems including procatalysts, including a metal-ligand complex having the structure of formula (I): [Formula I].
Abstract:
An aqueous dispersion comprising: (a) at least one of an acrylic polymer and an inorganic pigment; (b) 4,5-dichloro-2-n-octyl-4-isothiazolin-3-one; and (c) an alkyl acetoacetate.
Abstract:
A method for forming 1,3,5,7-tetraalkyl-6-(2,4-dimethoxyphenyl)-2,4,8-trioxa-6-phosphaadamantane includes obtaining a solution comprising an ethereal solvent and an aluminum hydride, adding dichloro(2,4-dimethoxyphenyl)phosphine to the solution to produce 2,4-dimethoxyphenylphosphine, and reacting the 2,4-dimethoxyphenylphosphine with an acidic mixture comprising diones to produce 1,3,5,7-tetraalkyl-6-(2,4-dimethoxyphenyl)-2,4,8-trioxa-6-phosphaadamantane. The solution has a temperature from greater than -20 C to 50 C throughout the method. Another method for forming 1,3,5,7-tetraalkyl-6-(2,4-dimethoxyphenyl)-2,4,8-trioxa-6-phosphaadamantane includes obtaining dichloro(2,4-dimethoxyphenyl)phosphine, forming 2,4-dimethoxyphenylphosphine by adding the dichloro(2,4-dimethoxyphenyl)phosphine to a solution comprising at least one solvent and an aluminum hydride, reacting the 2,4-dimethoxyphenylphosphine with a mixture to produce 1,3,5,7-tetraalkyl-6-(2,4-dimethoxyphenyl)-2,4,8-trioxa-6-phosphaadamantane. The mixture includes an acid selected from the group consisting of Lewis acids, sulfonic Bronsted acids, and mixtures thereof, an aromatic or non-aromatic hydrocarbons; and acetylacetone.
Abstract:
An olefin polymerization catalyst system comprising: a procatalyst component comprising a metal-ligand complex of Formula (I) wherein each X is independently a monodentate or polydentate ligand that is neutral, monoanionic, or dianionic, wherein n is an integer, and wherein X and n are chosen such that the metal-ligand complex of Formula (I) is overall neutral; wherein each R1 and R5 independently is selected from (C1-C40)hydrocarbyls, substituted (C1-C40)hydrocarbyls; (C1-C-40)heterohydrocarbyls and substituted (C1-C40)heterohydrocarbyls; wherein each R2 and R4 independently is selected from (C1-C40)hydrocarbyls andsubstituted (C1-C40)hydrocarbyls; wherein R3 is selected from the group consisting of a (C3-C40)hydrocarbylene, substituted (C3-C40)hydrocarbylene, [(C+Si)3-(C+Si)40]organosilylene, substituted [(C+Si)3-(C+Si)40]organosilylene, [(C+Ge)3-(C+Ge)40]organogermylene, or substituted [(C+Ge)3-(C+Ge)40]organogermylene; wherein each N independently is nitrogen; and optionally, two or more R1-5 groups each independently can combine together to form mono-aza ring structures, with such ring structures having from 5 to 16 atoms in the ring excluding any hydrogen atoms.
Abstract:
Embodiments of the present application are directed to procatalysts, and catalyst systems including procatalysts, including a metal-ligand complex having the structure of formula (I):
Abstract:
Processes for polymerizing polyolefins include contacting ethylene and optionally one or more (C 3 -C 12 )α-olefin in the presence of a catalyst system, wherein the catalyst system comprises a metal-ligand complex having a structure according to formula (I):
Abstract:
Embodiments are directed to catalyst systems comprising at least one metal ligand complex and to processes for polyolefin polymerization incorporating the catalyst systems. The metal ligand complexes have the following structures: (I)