RHEOLOGY MODIFIED OLEFIN-BASED POLYMER COMPOSITION AND METHOD FOR MAKING IT

    公开(公告)号:WO2022240932A1

    公开(公告)日:2022-11-17

    申请号:PCT/US2022/028687

    申请日:2022-05-11

    Abstract: A process to form a rheology modified composition, the process comprising applying radiation, and optionally heat, to a composition that comprises at least the following component: a) an olefin-based polymer comprising a total unsaturation ≥ 0.20 /1000C; and wherein the radiation is applied using an electron beam (e-beam) at a dosage selected from 0.1 MRad to 1.5 MRad; and wherein component a is selected from a telechelic polyolefin of the formula A1L1L2A2, an unsaturated polyolefin of the formula A1L1, or an ethylene/alpha-olefin interpolymer. A process to form a rheology modified composition, the process comprising applying heat, and optionally radiation, to a composition that comprises at least the following components: a) an olefin-based polymer, as described above, comprising a total unsaturation ≥ 0.20 /1000C; b) from 1.0 to 100 ppm of a peroxide, based on the weight of the composition.

    IMPACT MODIFIED COMPOSITIONS FOR LOW TEMPERATURE USE CONTAINERS
    14.
    发明申请
    IMPACT MODIFIED COMPOSITIONS FOR LOW TEMPERATURE USE CONTAINERS 审中-公开
    用于低温使用容器的冲击改性组合物

    公开(公告)号:WO2018049300A1

    公开(公告)日:2018-03-15

    申请号:PCT/US2017/050896

    申请日:2017-09-11

    Abstract: Embodiments relate to compositions comprising: (a) from 60 wt% to 90 wt% of a propylene polymer base that has a melt flow rate from 2 g/10 min to 100 g/10 min according to ASTM D1238 (230 °C/2.16 kg); (b) from 2 wt% to 39.5 wt% of an olefin block copolymer; and (c) from 0.5 wt% to 20 wt% of a composite component comprising a crystalline block composite or a block composite. In certain embodiments, the composition may further comprise: (d) from 1 wt% to 30 wt% a polyolefin copolymer, the polyolefin copolymer being derived from ethylene and at least one of a C3 to C10 alpha-olefin, having a melt index from 100 g/10 min to 2000 g/10 min according to ASTM D1238 (190 °C/2.16 kg), and having a density from 0.860 g/cc to 0.900 g/cc. In further embodiments, the composition may further comprise: (e) from 0.1 wt% to 5 wt% of an antioxidant.

    Abstract translation: 实施方式涉及组合物,其包含:(a)60wt%至90wt%的丙烯聚合物基料,其具有根据 ASTM D1238(230℃/ 2.16kg); (b)2重量%至39.5重量%的烯烃嵌段共聚物; 和(c)0.5重量%至20重量%的包含结晶嵌段复合材料或嵌段复合材料的复合组分。 在某些实施方案中,所述组合物可进一步包含:(d)1重量%至30重量%的聚烯烃共聚物,所述聚烯烃共聚物衍生自乙烯和至少一种C3至C10α-烯烃,其熔体指数为 根据ASTM D1238(190℃/ 2.16kg)为100g / 10min至2000g / 10min,并且具有0.860g / cc至0.900g / cc的密度。 在进一步的实施方案中,组合物可以进一步包含:(e)0.1wt%-5wt%的抗氧化剂。

    IMPACT MODIFIED COMPOSITIONS FOR LOW TEMPERATURE USE CONTAINERS
    15.
    发明申请
    IMPACT MODIFIED COMPOSITIONS FOR LOW TEMPERATURE USE CONTAINERS 审中-公开
    用于低温使用容器的冲击改性组合物

    公开(公告)号:WO2017173293A1

    公开(公告)日:2017-10-05

    申请号:PCT/US2017/025415

    申请日:2017-03-31

    Abstract: A modifier for forming sub-ambient temperature use containers includes (a) from 10 wt% to 50 wt% of a block composite, a specified block composite, or a crystalline block composite, (b) from 20 wt% to 90 wt% of a first polyolefin copolymer, the first polyolefin copolymer being derived from ethylene and at least one of a C 3 to C 10 alpha-olefin, having a melt index from 0.5 g/10 min to 1500 g/10 min, and having a density from 0.850 g/cm 3 to 0.910 g/cm 3 , and (c) optionally, from 30 wt% to 70 wt% of a second polyolefin copolymer, the second polyolefin copolymer being derived from ethylene and at least one of a C 3 to C 10 alpha-olefin, having a melt index from 100 g/10 min to 2000 g/10 min, and having a density from 0.860 g/cm 3 to 0.900 g/cm 3 .

    Abstract translation: 用于形成低于室温的使用容器的改性剂包括(a)10重量%至50重量%的嵌段复合材料,特定的嵌段复合材料或结晶嵌段复合材料,(b)来自 20重量%至90重量%的第一聚烯烃共聚物,所述第一聚烯烃共聚物衍生自乙烯和至少一种C 3至C 10α-烯烃, 具有0.5g / 10min至1500g / 10min的熔体指数,并具有0.850g / cm 3至0.910g / cm 3的密度,和( c)任选地,30重量%至70重量%的第二聚烯烃共聚物,所述第二聚烯烃共聚物衍生自乙烯和C 3至C 10至少一个 其具有100g / 10min至2000g / 10min的熔体指数并且具有0.860g / cm 3至0.900g / cm 3的密度的α-烯烃, SUP>

    IMPACT MODIFIED COMPOSITIONS FOR LOW TEMPERATURE USE CONTAINERS
    16.
    发明申请
    IMPACT MODIFIED COMPOSITIONS FOR LOW TEMPERATURE USE CONTAINERS 审中-公开
    用于低温使用容器的冲击改性组合物

    公开(公告)号:WO2017171915A1

    公开(公告)日:2017-10-05

    申请号:PCT/US2016/051263

    申请日:2016-09-12

    Abstract: A modifier for forming sub-ambient temperature use containers includes (a) from 10 wt% to 50 wt% of a block composite, a specified block composite, or a crystalline block composite, (b) from 20 wt% to 90 wt% of a first polyolefin copolymer, the first polyolefin copolymer being derived from ethylene and at least one of a C 3 to C 10 alpha-olefin, having a melt index from 0.5 g/10 min to 1500 g/10 min, and having a density from 0.850 g/cm 3 to 0.910 g/cm 3 , and (c) optionally, from 30 wt% to 60 wt% of a second polyolefin copolymer, the second polyolefin copolymer being derived from ethylene and at least one of a C 3 to C 10 alpha-olefin, having a melt index from 100 g/10 min to 2000 g/10 min, and having a density from 0.860 g/cm3 to 0.900 g/cm 3 .

    Abstract translation: 用于形成低于室温的使用容器的改性剂包括(a)10重量%至50重量%的嵌段复合材料,特定的嵌段复合材料或结晶嵌段复合材料,(b)来自 20重量%至90重量%的第一聚烯烃共聚物,所述第一聚烯烃共聚物衍生自乙烯和至少一种C 3至C 10α-烯烃, 具有0.5g / 10min至1500g / 10min的熔体指数,并具有0.850g / cm 3至0.910g / cm 3的密度,和( c)任选地,30重量%至60重量%的第二聚烯烃共聚物,所述第二聚烯烃共聚物衍生自乙烯以及C 3至C 10至少一种 ,其具有100g / 10min至2000g / 10min的熔体指数,并具有0.860g / cm 3至0.900g / cm 3的密度。

    THERMOPLASTIC VULCANIZATE INCLUDING A BLOCK COMPOSITE
    17.
    发明申请
    THERMOPLASTIC VULCANIZATE INCLUDING A BLOCK COMPOSITE 审中-公开
    热塑性钒酸盐包括块状复合材料

    公开(公告)号:WO2016105977A1

    公开(公告)日:2016-06-30

    申请号:PCT/US2015/065232

    申请日:2015-12-11

    CPC classification number: C08L23/16 C08F297/083 C08L23/14 C08L53/00

    Abstract: A thermoplastic vulcanizate composition includes (A) greater than 15 wt% of a block composite that has (i) an ethylene/alpha-olefin/diene interpolymer in which the alpha-olefin is an alpha olefin monomer having from 3 to 10 carbon atoms and the diene is a diene monomer having from 2 to 25 carbon atoms, (ii) a propylene based polymer, and (iii) a block copolymer comprising a soft block and a hard block in which the soft block has the same composition as the ethylene/alpha-olefin/diene polymer and the hard block has the same composition as the propylene based polymer; and (B) a remainder of a curative system and optionally at least one of a vulcanizable elastomer, a thermoplastic polyolefin, and an oil.

    Abstract translation: 热塑性硫化橡胶组合物包括(A)大于15重量%的嵌段复合材料,其具有(i)乙烯/α-烯烃/二烯互聚物,其中α-烯烃是具有3至10个碳原子的α-烯烃单体和 二烯是具有2至25个碳原子的二烯单体,(ii)丙烯基聚合物,和(iii)包含软嵌段和硬嵌段的嵌段共聚物,其中软嵌段具有与乙烯/ α-烯烃/二烯聚合物和硬嵌段具有与丙烯基聚合物相同的组成; 和(B)固化体系的其余部分和任选的可硫化弹性体,热塑性聚烯烃和油中的至少一种。

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