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公开(公告)号：WO2016176021A1
公开(公告)日：2016-11-03
申请号：PCT/US2016/026453
申请日：2016-04-07
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor： HUKKANEN, Eric J. , BARTON, Bryan E. , BILLOVITS, Gerald F. , PATTON, Jasson T. , NICOLI, Edoardo , PETERSON, Thomas H.
CPC classification number: D01F6/04 , C08F10/00 , D01F6/30 , D01F6/46 , D01F9/21 , D01F11/124 , D06M11/80 , D06M13/51
Abstract: In one instance, the present disclosure describes a method for preparing a carbonaceous article comprising: providing a crosslinked polyolefin fabricated article; stabilizing the crosslinked polyolefin fabricated article by air oxidation to provide a stabilized fabricated article; treating with a boron-containing liquid (BCL) during or intermediate to at least one of the preceding steps; and carbonizing the stabilized fabricated article. In one instance the present disclosure describes a method for preparing a stabilized article.
Abstract translation: 在一个实例中，本公开描述了一种制备碳质制品的方法，包括：提供交联的聚烯烃制品; 通过空气氧化稳定交联聚烯烃制品，以提供稳定的制造制品; 在至少一个前述步骤中或之前用含硼液体（BCL）处理; 并将稳定的制造物品碳化。 在一个实例中，本公开描述了制备稳定化制品的方法。
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12.发明申请PROCESSES FOR PREPARING CARBON FIBERS USING SULFUR TRIOXIDE IN A HALOGENATED SOLVENT 审中-公开用三氯化硫在硫化氢溶液中制备碳纤维的方法
公开(公告)号：WO2014011462A1
公开(公告)日：2014-01-16
申请号：PCT/US2013/049196
申请日：2013-07-03
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor： PATTON, Jasson T. , BARTON, Bryan E. , BERNIUS, Mark T. , CHEN, Xiaoyun , HUKKANEN, Eric J. , RHOTON, Christina A. , LYSENKO, Zenon
CPC classification number: D01F9/21 , D01F9/14 , D06M11/55 , D06M2101/20
Abstract: Disclosed here are processes for preparing carbonized polymers (preferably carbon fibers), comprising sulfonating a polymer with a sulfonating agent that comprises SO 3 dissolved in a solvent to form a sulfonated polymer; treating the sulfonated polymer with a heated solvent, wherein the temperature of the solvent is at least 95 °C; and carbonizing the resulting product by heating it to a temperature of 500-3000 °C. Carbon fibers made according to these methods are also disclosed herein.
Abstract translation: 这里公开了制备碳化聚合物（优选碳纤维）的方法，其包括用包含溶解在溶剂中的SO 3形成磺化聚合物的磺化剂磺化聚合物; 用加热的溶剂处理磺化聚合物，其中溶剂的温度为至少95℃; 并将所得产物加热至500-3000℃的温度进行碳化。 根据这些方法制造的碳纤维也在本文中公开。
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13.发明申请TWO-STEP SULFONATION PROCESS FOR THE CONVERSION OF POLYMER FIBERS TO CARBON FIBERS 审中-公开聚碳纤维转换成碳纤维的两步骤硫化工艺
公开(公告)号：WO2014011460A1
公开(公告)日：2014-01-16
申请号：PCT/US2013/049192
申请日：2013-07-03
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor： BARTON, Bryan E. , PATTON, Jasson T. , HUKKANEN, Eric J. , BERNIUS, Mark T.
Abstract: Disclosed herein are processes for preparing carbon fibers, comprising: sulfonating a polymer fiber with a sulfonating agent that is fuming sulfuric acid, sulfuric acid, chlorosulfonic acid, or a combination thereof; treating the sulfonated polymer with a heated solvent, wherein the temperature of the heated solvent is at least 95 ℃; and carbonizing the resulting product by heating it to a temperature of 500-3000 ℃. Carbon fibers prepared according to these methods are also disclosed herein.
Abstract translation: 本文公开了制备碳纤维的方法，包括：用发烟硫酸，硫酸，氯磺酸或其组合的磺化剂磺化聚合物纤维; 用加热的溶剂处理磺化聚合物，其中加热溶剂的温度为至少95℃; 并将所得产物加热至500-3000℃的温度进行碳化。 根据这些方法制备的碳纤维也在本文中公开。
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公开(公告)号：WO2019133699A1
公开(公告)日：2019-07-04
申请号：PCT/US2018/067655
申请日：2018-12-27
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor： SUN, Lixin , SZUROMI, Endre , KLOSIN, Jerzy , CARNAHAN, Edmund M. , PATTON, Jasson T. , LIAO, Longyan
IPC: C08F110/02 , C08F8/42 , C08F2/38 , C07F5/06
Abstract: The present disclosure relates to a capped dual-headed organoaluminum composition having the formula (I) and processes to prepare the same. In at least one aspect, the capped dual-headed organoaluminum compositions can be used in olefin polymerization.
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公开(公告)号：WO2016176023A1
公开(公告)日：2016-11-03
申请号：PCT/US2016/026457
申请日：2016-04-07
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor： HUKKANEN, Eric J. , BARTON, Bryan E. , BILLOVITS, Gerald F. , DERSTINE, Christopher W. , PATTON, Jasson T.
CPC classification number: C08K5/55 , C08F10/00 , C08K3/38 , D01F6/04 , D01F9/21 , D01F11/06 , D01F11/124 , D06M11/80 , D06M13/51
Abstract: A method for preparing a carbonized article comprising: (a) providing a polyolefin resin; (b) forming a fabricated article from the polyolefin resin; (c) crosslinking the fabricated article; (d) stabilizing the fabricated article in a boron-containing oxidizing environment (BOE); and (e) carbonizing the fabricated article. The present disclosure further describes a method for preparing a stabilized article.
Abstract translation: 一种制备碳化制品的方法，包括：（a）提供聚烯烃树脂; （b）从所述聚烯烃树脂形成制品; （c）交联制造的制品; （d）在含硼氧化环境（BOE）中稳定制造的制品; 和（e）将制成的制品碳化。 本公开进一步描述了制备稳定制品的方法。
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Patent Agency Ranking
公开(公告)号：WO2016176022A1
公开(公告)日：2016-11-03
申请号：PCT/US2016/026456
申请日：2016-04-07
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor： HUKKANEN, Eric J. , BARTON, Bryan E. , BILLOVITS, Gerald F. , PATTON, Jasson T.
CPC classification number: D01F11/06 , C08F10/00 , D01F6/04 , D01F6/30 , D01F9/21 , D01F11/124 , D06M11/80 , D06M11/82 , D06M2101/20
Abstract: The present disclosure describes a method for preparing a carbonized article comprising providing a fabricated polyolefin article; crosslinking the fabricated article with a boron-containing species (BCS); stabilizing the fabricated article by air oxidation; and carbonizing the fabricated article. The present disclosure further describes preparing a stabilized article.
Abstract translation: 本公开描述了一种制备碳化制品的方法，包括提供制造的聚烯烃制品; 用含硼物质（BCS）交联制造的制品; 通过空气氧化稳定制造的物品; 并将制成的制品碳化。 本公开进一步描述了制备稳定的制品。
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公开(公告)号：WO2015042387A1
公开(公告)日：2015-03-26
申请号：PCT/US2014/056540
申请日：2014-09-19
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor： BARTON, Bryan E. , BEHR, Michael J. , PATTON, Jasson T. , HUKKANEN, Eric J.
CPC classification number: D01F9/21 , D06M11/82 , D06M13/51 , D06M2101/20 , D06M2101/40
Abstract: A process includes treating a stabilized polyolefin fiber with a boron source followed by heating the fiber to a temperature 1000 degrees Celsius or higher in an inert atmosphere so as to convert the stabilized polyolefin fiber in to a carbon fiber.
Abstract translation: 一种方法包括用硼源处理稳定的聚烯烃纤维，然后在惰性气氛中将纤维加热到1000摄氏度或更高的温度，以将稳定的聚烯烃纤维转化为碳纤维。
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公开(公告)号：EP3768731A1
公开(公告)日：2021-01-27
申请号：EP19714947.9
申请日：2019-03-18
Applicant: Dow Global Technologies LLC
Inventor： OBER, Matthias S. , LIAO, Longyan , PATTON, Jasson T. , MUKHOPADHYAY, Sukrit , KLOSIN, Jerzy , DEVORE, David D.
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19.发明公开PROCESS FOR TELOMERIZATION OF BUTADIENE USING A MONO-ORTHOALKOXY SUBSTITUTED CATALYST 有权VERFAHREN ZUR TELOMERISIERUNG VON BUTADIEN MITHILEL EINES MONO-ORTHOALKOXY-SUBSTITUIERTEN KATALYSATORS
公开(公告)号：EP2655305A1
公开(公告)日：2013-10-30
申请号：EP11808436.7
申请日：2011-12-14
Applicant: Dow Global Technologies LLC
Inventor： BRIGGS, John R. , PATTON, Jasson T. , BEIGZADEH, Daryoosh , MARGL, Peter M. , HAGEN, Henk , VERMAIRE-LOUW, Sonet
IPC: C07C41/06 , C07C41/20 , C07C43/188 , C07F9/02
CPC classification number: C07C41/06 , C07C1/20 , C07C41/20 , C07F9/5022 , C07C43/15 , C07C43/04 , C07C11/02
Abstract: A process for the telomerization of butadiene comprises reacting 1,3-butadiene and an alkanol, in the presence of a catalyst promoter and an alkoxydimerization catalyst comprising a Group VIII transition metal and a triarylphosphine ligand, which includes one phenyl that is mono-ortho-alkoxy substituted and at least one other phenyl including at least one substituent that withdraws electrons from the phosphorus atom. The product includes an alkoxy-substituted octadiene, which may then be used to produce 1-octene. The catalyst shows improved stability, activity and selectivity toward the alkoxy-substituted octadiene.
Abstract translation: 用于丁二烯调聚的方法包括在催化剂促进剂和包含第VIII族过渡金属和三芳基膦配体的烷氧基二聚化催化剂的存在下使1,3-丁二烯和链烷醇反应，其包括一个苯基， 烷氧基取代的和至少一种其它苯基，包括至少一个从磷原子撤出电子的取代基。 该产物包括烷氧基取代的辛二烯，然后可以用它来生产1-辛烯。 该催化剂显示改进的对烷氧基取代的辛二烯的稳定性，活性和选择性。
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20.发明公开TWO-STEP SULFONATION PROCESS FOR THE CONVERSION OF POLYMER FIBERS TO CARBON FIBERS 有权VERFAHREN ZUR CARBONISIERUNG VON POLYMEREN
公开(公告)号：EP2872681A1
公开(公告)日：2015-05-20
申请号：EP13739326.0
申请日：2013-07-03
Applicant: Dow Global Technologies LLC
Inventor： BARTON, Bryan E. , PATTON, Jasson T. , HUKKANEN, Eric J. , BERNIUS, Mark T.
Abstract: Disclosed herein are processes for preparing carbon fibers, comprising: sulfonating a polymer fiber with a sulfonating agent that is fuming sulfuric acid, sulfuric acid, chlorosulfonic acid, or a combination thereof; treating the sulfonated polymer with a heated solvent, wherein the temperature of the heated solvent is at least 95° C.; and carbonizing the resulting product by heating it to a temperature of 501-3000° C. Carbon fibers prepared according to these methods are also disclosed herein.
Abstract translation: 本文公开了制备碳纤维的方法，包括：用发烟硫酸，硫酸，氯磺酸或其组合的磺化剂磺化聚合物纤维; 用加热的溶剂处理磺化聚合物，其中加热溶剂的温度为至少95℃。 并将所得产物加热至501-3000℃。根据这些方法制备的碳纤维也在本文中公开。
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