Abstract:
Disclosed is a process for a melt processing a polyethylene terephthalate. The polyester particles have at least two melting peaks. The polyester particles may have an It. V. at their surface which is less than 0.25 dL/g higher than the It. V. at their center. The polyester particles may have not been solid stated. The melt processing device comprises a screw with a total length (9), L, a feed zone length (3) in the range from 0.1 SL and 0.45L, a taper angle, in the range from 0.5 degrees and 5.0 degrees and a compression ratio, CR, in the range from 2.0 and 5.0.
Abstract:
A process for producing non-solid-stated polyester polymer particles having one or more properties similar to polyester polymer particles that have undergone solid-state processing.
Abstract:
Base cup (30) for receiving a container body bottom (15) and for reducing heat gain to fluid contents in the container body (12). A passive base cup is made of foam and has a reflective layer (44) on a majority of the outer surface thereof, or made of plastic, with an outer reflective layer, and optionally a foam layer (46). An active base cup (60) server to actively cool the fluid in the container, by including a compartment (66) therein with a fluid (68) that can be frozen. Again, a reflective layer and an optional foam layer extend over a majority of the outer surface of the cup. The reflective layer (44) materials have a density different than the cup materials to facilitate recycling.
Abstract:
A crystallization process comprising passing a mass of amorphous crystallizäble polymer having a first thickness (ft) through the nip gap of counter-rotating rolls having a nip gap (ng)at an ft:ng ratio of at least 1.2 to crystallize the polymer to a degree of crystallinity of at least 15% and thereby produce a semi-crystalline polymer, and particulating the semi-crystalline polymer. Strain crystallizing a sheet or fiber by using a drafting step to elongate the sheet or fiber is no longer needed. A high degree of crystallinity is imparted almost instantaneously, even in slow to crystallize copolyesters. The process allows one to extrude a thinner crystallizable sheet, substantially retains the dimensiona) width of the sheet as it is passed through the compression rolls, and produces substantially optically clear sheet and pellets. Suitable polymers include polyethylene terephthalate or naphthalate homopolymers or copolymers.
Abstract:
Disclosed is a polyester composition comprising: a polyester consisting essentially of: diacid residues consisting essentially of terephthalic residues; and diol residues consisting essentially of about 92 to 98 mole percent ethylene glycol residues, about 1 to 4 mole percent diethylene glycol (DEG) residues, and about 1 to 4 mole percent 1,4-cyclohexanedimethanol (CHDM) residues; and having an inherent viscosity (IhV) which satisfies the equations IhV-X-Y = 0.74 to 0.80, wherein X is the mole fraction of CHDM and Y is the mole fraction of DEG; and at least one reheat enhancing aid in an amount sufficient to provide between about 5 and 25 % reheat improvement. Also disclosed are heat set containers suitable for packaging hot-filled liquids and processes for the manufacture of such heat set containers.
Abstract:
An apparatus and a method for molding of polyester articles having low acetaldehyde content directly from a melt without intermediate solidification of the molten polyester. A melt to mold process is used wherein an acetaldehyde stripping agent is mixed into a polyester melt before devolatilization in a flash tank. The devolatilized polyester is pumped out of the flash tank and injected into a mold, thus forming a shaped article. The apparatus may include one or more flash tanks in one devolatilization line, or multiple devolatilization lines may be used stemming from one main polymerization reactor. The final shaped article should contain less than 10 ppm of acetaldehyde.
Abstract:
Polyester compositions are disclosed that include polyester polymers or copolymers having incorporated therein carbon-coated iron particles that improve the reheat properties of the compositions. Processes for making such compositions are also disclosed. The carbon-coated iron particles may be incorporated in the polyester by melt compounding, or may be added at any stage of the polymerization, such as during the melt-phase of the polymerization. A range of particle sizes may be used, as well as a range of particle size distributions. The polyester compositions are suitable for use in packaging made from processes in which a reheat step is desirable.
Abstract:
Polyester compositions are disclosed that include polyester polymers or copolymers having incorporated therein titanium nitride particles and carbon-coated iron particles to improve the reheat properties of the compositions. The compositions may also exhibit reduced yellowness, and improved resistance to the effects of UV light. Processes for making such compositions are also disclosed. The particles may be incorporated in the polyester by melt compounding, or may be added at any stage of the polymerization, such as during the melt-phase of the polymerization. A range of particle sizes may be used, as well as a range of particle size distributions. The polyester compositions are suitable for use in packaging made from processes in which a reheat step is desirable, or decreased yellowness is desired, or increased resistance to the effects of ultraviolet light is desired, or any combination of the foregoing.
Abstract:
A bulk of polyester polymer particles comprising polyester polymer comprising greater than 75% virgin polyester polymer, the particles having: A) an It. V. of at least 0.72 dl/g, and B) 10 ppm or less of residual acetaldehyde; and C) at least two melting peaks, wherein one of said at least two melting peaks is a low peak melting point within a range of 140 degrees Celsius to 220 degrees Celsius and having a melting endotherm area of at least the absolute value of 1 J/g.