公开(公告)号：US2818416A

公开(公告)日：1957-12-31

申请号：US32522452

申请日：1952-12-10

Applicant: ETHYL CORP

Inventor： BROWN JEROME E ,  HYMIN SHAPIRO ,  DE WITT EARL G

IPC: C07F17/00 ,  C10L1/30

CPC classification number: C07F17/00 ,  C10L1/30 ,  C10L1/305 ,  C10M1/08 ,  C10M2227/08 ,  C10M2227/081 ,  C10N2250/10

公开(公告)号：US3306917A

公开(公告)日：1967-02-28

申请号：US47669865

申请日：1965-08-02

Applicant: ETHYL CORP

Inventor： HYMIN SHAPIRO ,  DE WITT EARL G ,  BROWN JEROME E

IPC: C07F17/00

CPC classification number: C07F17/00 ,  Y02P20/582

公开(公告)号：US3285946A

公开(公告)日：1966-11-15

申请号：US54875555

申请日：1955-11-23

Applicant: ETHYL CORP

Inventor： DE WITT EARL G ,  BROWN JEROME E ,  HYMIN SHAPIRO

IPC: C07F17/02 ,  C10L1/10 ,  C10L1/30

CPC classification number: C10L1/305 ,  C07F17/02 ,  C10L1/103

公开(公告)号：US3130017A

公开(公告)日：1964-04-21

申请号：US71604358

申请日：1958-02-19

Applicant: ETHYL CORP

Inventor： HYMIN SHAPIRO ,  DE WITT EARL G ,  BROWN JEROME E

IPC: C07F17/00 ,  C10L1/14 ,  C10L1/28 ,  C10L1/30

CPC classification number: C07F17/00 ,  C10L1/14 ,  C10L1/28 ,  C10L1/303 ,  C10L1/305

公开(公告)号：US3110577A

公开(公告)日：1963-11-12

申请号：US80414159

申请日：1959-04-06

Applicant: ETHYL CORP

Inventor： BROWN JEROME E ,  HYMIN SHAPIRO ,  DE WITT EARL G

IPC: C07F15/04 ,  C10L1/30

CPC classification number: C10L1/305 ,  C07F15/04

公开(公告)号：US3041155A

公开(公告)日：1962-06-26

申请号：US1592560

申请日：1960-03-09

Applicant: ETHYL CORP

Inventor： BROWN JEROME E ,  DE WITT EARL G ,  HYMIN SHAPIRO

IPC: C07F13/00 ,  C10L1/30

CPC classification number: C10L1/305 ,  C07F13/00

公开(公告)号：US2976304A

公开(公告)日：1961-03-21

申请号：US71118358

申请日：1958-01-27

Applicant: ETHYL CORP

Inventor： DE WITT EARL G ,  BROWN JEROME E ,  HYMIN SHAPIRO

IPC: C07F17/00

CPC classification number: C07F17/00

公开(公告)号：US2964548A

公开(公告)日：1960-12-13

申请号：US83169559

申请日：1959-08-05

Applicant: ETHYL CORP

Inventor： BROWN JEROME E ,  DE WITT EARL G ,  HYMIN SHAPIRO

IPC: C07F17/00

CPC classification number: C07F17/00

公开(公告)号：US3086034A

公开(公告)日：1963-04-16

申请号：US82421459

申请日：1959-07-01

Applicant: ETHYL CORP

Inventor： BROWN JEROME E ,  DE WITT EARL G ,  HYMIN SHAPIRO

IPC: C07F15/04

CPC classification number: C07F15/04

公开(公告)号：US3006742A

公开(公告)日：1961-10-31

申请号：US77029058

申请日：1958-10-29

Applicant: ETHYL CORP

Inventor： BROWN JEROME E ,  HYMIN SHAPIRO ,  DE WITT EARL G

IPC: C07F17/00 ,  C10L1/30

CPC classification number: C07F17/00 ,  C10L1/305 ,  C10L1/306

Abstract: A gasoline composition contains 0,5 to 6,34 grams of lead per United States gallon as an organolead compound and from 0,005 to 1 gram of nickel per United States gallon as a cyclopentadienyl compound of formula Ni Ax By Cz where A is a substituted or unsubstituted cyclopentadienyl radical, B and C are electron donating groups, x is 1 or 2, y is 1 to 4 and z is 0 or 1 to 4. The composition may also contain halohydrocarbon scavengers, and compounds of phosphorus, arsenic, antimony and bismuth. Lists of suitable compounds are given. In examples, gasolines and anti-knock compositions contain cyclopentadienyl nickel nitrosyl, butycyclopentadienyl nickel nitrosyl, methylcyclopentadienyl nickel nitrosyl, phenylcyclopentadienyl methyl nickel carbonyl, methylisopropylcyclopentadienyl ethyl nickel phosphorus trichloride, octylcyclopentadienyl phenyl nickel ammonia, indenyl nickel nitrosyl, cyclopentadienyl nickel carbonyl hydride, ethylcyclopentadienyl nickel nitrosyl, benzyl eyclopentadienyl tricyano nickel, methylcyclopentadienyl methyl nickel carbonyl, cyclopentadienyl ethyl nickel carbonyl, cyclopentadienyl phenyl nickel carbonyl or dimethylcyclopentadienyl nickel nitrosyl as the nickel compound. The lead compound is chosen from tetraethyl lead, tetramethyl lead, tetraphenyl lead, tetraoctyl lead, butyl triethyl lead, tetratolyl lead and methyltriethyl lead. Additional ingredients present in some instances are chosen from dibromobutane, dibromotoluene, ethylene dichloride and trichlorobenzene; tricresyl phosphate, trimethylphosphate, dimethylxylyl phosphate, tri-(b -chloroisopropyl) thionophosphate, tri-(2-ethylhexyl) phosphate, phenyl dimethylphosphate, methyl diphenyl phosphate, trixylyl arsine, triphenyl arsine, triphenyl stibine, triethyl antimonite, tributyl bismuthine and triphenyl bismuthine.