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    HYDROCARBON CONVERSION USING LARGE CRYSTAL ZEOLITE CATALYST
    12.
    发明申请
    HYDROCARBON CONVERSION USING LARGE CRYSTAL ZEOLITE CATALYST 审中-公开
    使用大型水晶沸石催化剂的碳氢化合物转化

    公开(公告)号：WO1998016468A1

    公开(公告)日：1998-04-23

    申请号：PCT/US1997018943

    申请日：1997-10-17

    Applicant: EXXON CHEMICAL PATENTS INC.

    Inventor： EXXON CHEMICAL PATENTS INC. ,  SMITH, Robert, S. ,  VERDUIJN, Johannes, P.

    IPC: C01B39/02

    CPC classification number: C10G45/64 ,  C01B39/02 ,  C01B39/04 ,  C07C2/66 ,  C07C4/06 ,  C07C5/2708 ,  C07C5/41 ,  C07C6/123 ,  C07C6/126 ,  C07C2529/18 ,  C07C2529/50 ,  C07C2529/65 ,  C07C2529/70 ,  C10G11/05 ,  C10G29/205 ,  C10G35/095 ,  C07C15/00

    Abstract: A process for converting hydrocarbons by contacting a hydrocarbon feedstream under hydrocarbon conversion conditions with a large crystal zeolite catalyst. The large crystal zeolite of the catalyst used in the hydrocarbon conversion process is made by heating an aqueous zeolite synthesis mixture under agitation to a temperature equal to or less than the effective nucleation temperature of the synthesis mixture. After this step, the aqueous synthesis mixture is heated in the absence of agitation to a temperature equal to or greater than the effective nucleation temperature of the aqueous zeolite synthesis mixture. The process finds particular application in hydrocarbon conversion processes where reduced non-selective acidity is important for reaction selectivity and/or the maintenance of catalyst activity, e.g., toluene disproportionation, dealkylation, alkylation, and transalkylation.

    Abstract translation: 一种通过在烃转化条件下与烃类进料流与大型晶体沸石催化剂接触来转化烃的方法。 在烃转化过程中使用的催化剂的大晶体沸石是通过在搅拌下将沸石合成混合物加热到等于或小于合成混合物的有效成核温度的温度来制备的。 在该步骤之后，将水性合成混合物在不加搅拌的条件下加热到等于或大于沸石合成混合物的有效成核温度的温度。 该方法在烃转化方法中具有特殊应用，其中降低的非选择性酸度对于反应选择性和/或维持催化剂活性，例如甲苯歧化，脱烷基化，烷基化和烷基转移是重要的。

    IMPROVED METHOD FOR PREPARING SUPPORTED METALLOCENE CATALYST SYSTEMS
    13.
    发明申请
    IMPROVED METHOD FOR PREPARING SUPPORTED METALLOCENE CATALYST SYSTEMS 审中-公开
    用于制备支持的金属催化剂体系的改进方法

    公开(公告)号：WO1998013393A1

    公开(公告)日：1998-04-02

    申请号：PCT/US1997014533

    申请日：1997-08-19

    Applicant: EXXON CHEMICAL PATENTS INC.

    Inventor： EXXON CHEMICAL PATENTS INC. ,  CHANG, Main

    IPC: C08F04/642

    CPC classification number: C08F10/00 ,  C08F4/63912 ,  C08F4/63916 ,  C08F4/63927

    Abstract: This invention relates generally to supported metallocene catalyst systems and to methods for their production and use. Specifically, this invention relates to a method for preparing supported metallocene catalyst systems using an aliphatic solvent. The catalyst systems prepared by these methods exhibit increased activity.

    Abstract translation: 本发明一般涉及负载型茂金属催化剂体系及其生产和使用方法。 具体地说，本发明涉及使用脂肪族溶剂制备负载型茂金属催化剂体系的方法。 通过这些方法制备的催化剂体系表现出增加的活性。

    PROCESS FOR INCREASED OLEFIN YIELDS FROM HEAVY FEEDSTOCKS
    16.
    发明申请
    PROCESS FOR INCREASED OLEFIN YIELDS FROM HEAVY FEEDSTOCKS 审中-公开
    从重型饲料中提高橄榄油的方法

    公开(公告)号：WO1998007808A1

    公开(公告)日：1998-02-26

    申请号：PCT/US1997014765

    申请日：1997-08-22

    Applicant: EXXON CHEMICAL PATENTS INC. ,  IACCINO, Larry, L. ,  COUTE, Nicholas, P.

    Inventor： EXXON CHEMICAL PATENTS INC.

    IPC: C10G69/06

    CPC classification number: C10G65/00 ,  C10G65/12 ,  C10G69/04 ,  C10G69/06

    Abstract: A process for upgrading petroleum feedstocks boiling in the distillate plus range, which feedstocks, when cracked, result in unexpected high yields of olefins. The feedstock is hydroprocessed in at least one reaction zone countercurrent to the flow of a hydrogen-containing treat gas. The hydroprocessed feedstock is then subjected to thermal cracking in a steam cracker or to catalytic cracking in a fluid catalytic cracking process. The resulting product slate will contain an increase in olefins compared with the same feedstock, but processed in by a conventional co-current hydroprocessing process.

    Abstract translation: 用于升级馏出物加范围沸腾的石油原料的方法，当裂化时，原料产生意料之外的高产率的烯烃。 原料在与含氢处理气体的流动逆流的至少一个反应区中进行加氢处理。 然后将加氢处理的原料在蒸汽裂化器中进行热裂解或在流化催化裂化过程中进行催化裂化。 与相同的原料相比，所得到的产品板岩将含有增加的烯烃，但是通过常规的并流加氢处理方法进行加工。

    BREATHABLE FILM/NWF-LAMINATES HAVING HIGH WVTR PREPARED FROM MELT EMBOSSED POLYOLEFIN/FILLER PRECURSOR FILMS
    18.
    发明申请
    BREATHABLE FILM/NWF-LAMINATES HAVING HIGH WVTR PREPARED FROM MELT EMBOSSED POLYOLEFIN/FILLER PRECURSOR FILMS 审中-公开
    具有高熔点熔融聚烯烃/填料前体膜的高阻燃性薄膜/ NWF层压板

    公开(公告)号：WO1998005502A1

    公开(公告)日：1998-02-12

    申请号：PCT/US1997013580

    申请日：1997-07-31

    Applicant: EXXON CHEMICAL PATENTS INC.

    Inventor： EXXON CHEMICAL PATENTS INC. ,  MIDDLESWORTH, Jeffrey, A. ,  BRADY, Kevin, A.

    IPC: B32B31/12

    CPC classification number: B32B27/20 ,  B29C55/005 ,  B29K2023/06 ,  B29K2023/0641 ,  B29K2023/083 ,  B29K2105/16 ,  B32B5/022 ,  B32B27/12 ,  B32B27/32 ,  B32B37/153 ,  B32B38/0032 ,  B32B38/0036 ,  B32B38/06 ,  B32B2038/0028 ,  B32B2305/20 ,  B32B2307/31 ,  C08J5/18 ,  C08J2323/08

    Abstract: Films, made of polyethylenes and fillers, and articles made therefrom greater WVTR than previously available films based on conventional Zeigler-Natta based polyethylenes. The polyethylenes are produced in a metallocene-catalyzed production process. The films may be made by a cast film process, and may be made in widely varying filler content, generally polyethylene to filler ratios of 30/70 to 70/30. The metallocene based polyethylenes when combined with filler also permit the extrusion of thinner films leading to lighter weight and softer films. The m-polyethylenes utilized for making such films typically have a Composition Distribution Breadth Index above 50 %, an Mw/Mn below 3, and an Mz/Mw below 2. The films may be used advantageously in composite structures with fabrics (either woven or non-woven) to fabricate such articles as house-wrap.

    Abstract translation: 由聚乙烯和填料制成的膜，以及由其制备的制品比基于常规的基于Zeigler-Natta的聚乙烯的先前可获得的膜更大的WVTR。 聚乙烯是在金属茂催化的生产过程中生产的。 膜可以通过流延膜方法制造，并且可以制备成广泛变化的填料含量，通常聚乙烯与填料比为30/70至70/30。 当与填料组合时，基于金属茂的聚乙烯也允许挤出更薄的膜，导致更轻的重量和较软的膜。 用于制备这种膜的m-聚乙烯通常具有高于50％的组分分布宽度指数，Mw / Mn低于3，Mz / Mw低于2。该膜可有利地用于具有织物的复合结构（编织物或织物 无纺布）制造这样的物品作为房屋包装。

    POLYOLEFIN/FILLER FILMS HAVING INCREASED WVTR AND METHOD FOR MAKING
    19.
    发明申请
    POLYOLEFIN/FILLER FILMS HAVING INCREASED WVTR AND METHOD FOR MAKING 审中-公开
    具有增加的WVTR的聚烯烃/填料膜和制造方法

    公开(公告)号：WO1998005501A1

    公开(公告)日：1998-02-12

    申请号：PCT/US1997013578

    申请日：1997-07-31

    Applicant: EXXON CHEMICAL PATENTS INC.

    Inventor： EXXON CHEMICAL PATENTS INC. ,  MIDDLESWORTH, Jeffrey, A. ,  BRADY, Kevin, A.

    IPC: B32B31/12

    CPC classification number: B32B27/20 ,  B29C55/005 ,  B29K2023/06 ,  B29K2023/0641 ,  B29K2023/083 ,  B29K2995/0068 ,  B32B27/08 ,  B32B27/32 ,  B32B2038/0028 ,  B32B2323/04 ,  B32B2555/02

    Abstract: Films, made of polyethylenes and fillers, and articles made therefrom greater WVTR than previously available films based on conventional Zeigler-Natta based polyethylenes. The polyethylenes are produced in a metallocene-catalyzed production process. The films may be made by a cast film process, and may be made in widely varying filler content, generally polyethylene to filler ratios of 30/70 to 70/30. The metallocene based polyethylenes when combined with filler also permit the extrusion of thinner films leading to lighter weight and softer films. The m-polyethylenes utilized for making such films typically have a Composition Distribution Breadth Index above 50 %, a Mw/Mn below 3, and a Mz/Mw below 2.

    Abstract translation: 由聚乙烯和填料制成的膜，以及由其制备的制品比基于常规的基于Zeigler-Natta的聚乙烯的先前可获得的膜更大的WVTR。 聚乙烯是在金属茂催化的生产过程中生产的。 膜可以通过流延膜方法制造，并且可以制备成广泛变化的填料含量，通常聚乙烯与填料比为30/70至70/30。 当与填料组合时，基于金属茂的聚乙烯也允许挤出更薄的膜，导致更轻的重量和较软的膜。 用于制备这种膜的m-聚乙烯通常具有高于50％的组分分布宽度指数，Mw / Mn低于3，Mz / Mw低于2。

    POLAR MONOMER CONTAINING COPOLYMERS DERIVED FROM OLEFINS USEFUL AS LUBRICANT AND FUEL OIL ADDITIVES, PROCESSES FOR PREPARATION OF SUCH COPOLYMERS AND ADDITIVES AND USE THEREOF
    20.
    发明申请
    POLAR MONOMER CONTAINING COPOLYMERS DERIVED FROM OLEFINS USEFUL AS LUBRICANT AND FUEL OIL ADDITIVES, PROCESSES FOR PREPARATION OF SUCH COPOLYMERS AND ADDITIVES AND USE THEREOF 审中-公开
    含有烯烃的极性单体作为润滑剂和燃料油添加剂有用，制备这种共聚物和添加剂的方法及其用途

    公开(公告)号：WO1998003617A1

    公开(公告)日：1998-01-29

    申请号：PCT/US1997012125

    申请日：1997-07-14

    Applicant: EXXON CHEMICAL PATENTS INC.

    Inventor： EXXON CHEMICAL PATENTS INC. ,  EMERT, Jacob, Isaac ,  ROSSI, Albert ,  GINDELBERGER, David, Edward ,  STANAT, Jon, Edmond ,  STOKES, James, Peter ,  SHER, Jaimes

    IPC: C10M145/14

    CPC classification number: C10M157/00 ,  C08F10/00 ,  C08F210/00 ,  C08F210/02 ,  C08F210/16 ,  C10L1/195 ,  C10L1/198 ,  C10L1/236 ,  C10L1/238 ,  C10L1/2468 ,  C10L1/2475 ,  C10L1/303 ,  C10L1/305 ,  C10L10/00 ,  C10M145/14 ,  C10M149/06 ,  C10M2209/084 ,  C10M2215/04 ,  C10M2215/042 ,  C10M2215/26 ,  C10M2217/024 ,  C10M2217/046 ,  C10M2217/06 ,  C10N2270/02 ,  C08F4/7006 ,  C08F210/06 ,  C08F210/08 ,  C08F216/36 ,  C08F220/12 ,  C08F220/14

    Abstract: Polar monomer-containing copolymers derived from at least one alpha , beta unsaturated carbonyl compound, such as alkyl acrylates and one or more olefins, such olefins including ethylene and C3-C20 alpha -olefins such as propylene and 1-butene, which copolymers have (a) an average ethylene sequence length, ESL, of from about 1.0 to less than about 3.0; (b) an average of at least 5 branches per 100 carbon atoms of the copolymer chains comprising the copolymer; (c) at least about 50 % of said branches being methyl and/or ethyl branches; (d) substantially all of said incorporated polar monomer is present at the terminal position of said branches; (e) at least about 30 % of said copolymer chains terminated with a vinyl or vinylene group; (f) a number average molecular weight, Mn, of from about 300 to about 15,000 when the copolymer is intended for dispersant or wax crystal modifier uses and up to about 500,000 where intended for viscosity modifier uses; and (g) substantial solubility in hydrocarbon and/or synthetic base oil. The copolymers are produced using late-transition-metal catalyst systems and, as an olefin monomer source other than ethylene preferably inexpensive, highly dilute refinery or steam cracker feed streams that have undergone only limited clean-up steps. Fuel and lubricating oil additives, particularly dispersants, wax crystal modifiers and flow improvers, are produced. Where functionalization and derivatization of these copolymers are required for such additives it is facilitated by the olefinic structures available in the copolymer chains.

    Abstract translation: 由至少一种α，β不饱和羰基化合物衍生的含极性单体的共聚物，如丙烯酸烷基酯和一种或多种烯烃，包括乙烯和C 3 -C 20α-烯烃如丙烯和1-丁烯的烯烃，该共聚物具有 a）平均乙烯序列长度，ESL为约1.0至小于约3.0; （b）包含共聚物的共聚物链中每100个碳原子平均至少5个分支; （c）至少约50％的所述分支是甲基和/或乙基支链; （d）基本上所有掺入的极性单体存在于所述分支的末端位置; （e）至少约30％的所述共聚物链用乙烯基或亚乙烯基封端; （f）当共聚物用于分散剂或蜡晶体改性剂时，数均分子量Mn为约300至约15,000，并且高达约500,000，用于粘度调节剂用途; 和（g）在烃和/或合成基础油中的实质溶解度。 共聚物使用后过渡金属催化剂体系生产，并且作为除乙烯以外的烯烃单体源，优选廉价，高度稀释的炼油厂或蒸汽裂化器进料流仅经过有限的清理步骤。 生产燃料和润滑油添加剂，特别是分散剂，蜡结晶改性剂和流动改进剂。 在这些添加剂需要这些共聚物的官能化和衍生化的情况下，通过共聚物链中可用的烯属结构来促进这些共聚物的功能化和衍生。

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