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公开(公告)号:CA1004181A
公开(公告)日:1977-01-25
申请号:CA153422
申请日:1972-10-06
Applicant: HOECHST AG
Inventor: BERGNER DIETER , KOHLHAAS RUDOLF
Abstract: 1415684 Metal oxido compounds HOECHST AG 9 Oct 1972 [7 Oct 1971] 46535/72 Heading C1A [Also in Divisions C6-C7] A crystalline oxido compound of ruthenium and/or iridium with gallium, indium, thallium, copper, zinc or cobalt is formed by heating a mixture or solution comprising thermally decomposable compounds of the relevant metals at a temperature below 900‹ C. in the presence or air or oxygen. Suitable decomposable compounds include the formates, acetates, oxalates, tartrates, oleates, citrates, stearates, naphthenates and resinates of any of the above metals and the chlorides, nitrosochlorides, nitrosonitrates, complex compounds and carbonyls of ruthenium and iridium.
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公开(公告)号:FI50514C
公开(公告)日:1976-04-12
申请号:FI86670
申请日:1970-03-25
Applicant: HOECHST AG
Inventor: BAECHLE HANS TUISKO , KOHLHAAS RUDOLF
IPC: C01B21/22
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公开(公告)号:CA886484A
公开(公告)日:1971-11-23
申请号:CA886484D
Applicant: HOECHST AG
Inventor: HLOCH ALBERT , MEDIC NIKOLAJ , KOHLHAAS RUDOLF
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公开(公告)号:FI50514B
公开(公告)日:1975-12-31
申请号:FI86670
申请日:1970-03-25
Applicant: HOECHST AG
Inventor: BAECHLE HANS TUISKO , KOHLHAAS RUDOLF
IPC: C01B21/22
Abstract: To produce N2O, ammonium nitrate is decomposed in an aqueous, chloride-containing solution in nitric acid while an ammonia atmosphere is maintained above the reaction mixture. The preferred temperature range of the solution is 110 DEG -125 DEG C. The atmosphere of ammonia is maintained by introducing at least part of the required ammonia into the gas volume of the reaction vessel. The decomposition of the ammonium nitrate and the formation of N2O is enhanced by the presence of catalytically active ions of manganese, copper, cerium, lead, bismuth, cobalt and nickel; manganese, especially in its bivalent form, being preferred.
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公开(公告)号:DE2230109A1
公开(公告)日:1974-01-10
申请号:DE2230109
申请日:1972-06-21
Applicant: HOECHST AG
Inventor: JOERCHEL EGON DR , KOHLHAAS RUDOLF
IPC: C01B25/10
Abstract: The process comprises (a) reacting phosphorus tribromide and oxygen in the presence of nitrogen oxides in an organic solvent at 0-120 degrees C, and (b) separating the formed phosphorus oxybromide by crystallisation or vacuum distilln. Use of solvent gives high yields of pure phosphorus oxybromide without risks of explosions, and allows reaction to be effected continuously. The solvent consists of a halohydrocarbon with a b.p. below 150 degrees C. After reaction the solvent may be removed by distilln. and the phosphorus oxybromide isolated by crystallisation, or alternatively phosphorus oxybromide is separated by distn. under 10-300 mm Hg at 60-100 degrees C. Reaction is effected at 0.5-10 atm. using 0.01-5 wt.% nitrogen oxides, calculated as NO2, based on phosphorus tribromide, and 20-90 vol. % solvent.
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公开(公告)号:AU3693771A
公开(公告)日:1973-06-21
申请号:AU3693771
申请日:1971-12-16
Applicant: HOECHST AG
Inventor: KOHLHAAS RUDOLF , WICK DIETER , RUSSOW JURGEN , SCHWINDT HERBERT
IPC: C09C1/20
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公开(公告)号:CA815552A
公开(公告)日:1969-06-17
申请号:CA815552D
Applicant: HOECHST AG
Inventor: MEDIC NIKOLAJ , NEISES HELMUT , KOHLHAAS RUDOLF , HLOCH ALBERT
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公开(公告)号:CA747821A
公开(公告)日:1966-12-06
申请号:CA747821D
Applicant: HOECHST AG
Inventor: ROPER WOLFGANG , KOHLHAAS RUDOLF
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公开(公告)号:AU4742072A
公开(公告)日:1974-04-11
申请号:AU4742072
申请日:1972-10-05
Applicant: HOECHST AG
Inventor: BERGNER DIETER , KOHLHAAS RUDOLF
IPC: C23F13/00 , C25B11/04 , C25B11/10 , C25D17/10 , B32B15/04 , C01G45/02 , C01G55/00 , C23C3/04 , B01K3/06 , C01B7/06
Abstract: 1415684 Metal oxido compounds HOECHST AG 9 Oct 1972 [7 Oct 1971] 46535/72 Heading C1A [Also in Divisions C6-C7] A crystalline oxido compound of ruthenium and/or iridium with gallium, indium, thallium, copper, zinc or cobalt is formed by heating a mixture or solution comprising thermally decomposable compounds of the relevant metals at a temperature below 900‹ C. in the presence or air or oxygen. Suitable decomposable compounds include the formates, acetates, oxalates, tartrates, oleates, citrates, stearates, naphthenates and resinates of any of the above metals and the chlorides, nitrosochlorides, nitrosonitrates, complex compounds and carbonyls of ruthenium and iridium.
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公开(公告)号:AU4452272A
公开(公告)日:1974-01-17
申请号:AU4452272
申请日:1972-07-13
Applicant: HOECHST AG
Inventor: KOHLHAAS RUDOLF , KIEFER ERHARD , MASCHMANN MANFRED
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