Compounds containing tertiary amino groups, a process for their
production and their use as catalysts
    13.
    发明授权
    Compounds containing tertiary amino groups, a process for their production and their use as catalysts 失效
    含有叔氨基的化合物,其制备方法及其用作催化剂

    公开(公告)号:US5482979A

    公开(公告)日:1996-01-09

    申请号:US255524

    申请日:1994-06-08

    Abstract: Compounds containing ester groups and tertiary amino groups and optionally hydroxyl groups are made by reacting optionally hydroxyfunctional acetoacetic acid esters of monofunctional or polyfunctional alcohols (particularly polyfunctional polyether polyols) with primary/tertiary polyamines (particularly diamines). These compounds are useful as optionally incorporable catalysts for the isocyanate addition reaction in the production of polyurethane foams by the isocyanate polyaddition process.

    Abstract translation: 含有酯基和叔氨基和任选的羟基的化合物是通过使任意的单功能或多官能醇(特别是多官能聚醚多元醇)的羟基官能的乙酰乙酸酯与伯/叔多胺(特别是二胺)反应制得的。 这些化合物可用作用于通过异氰酸酯加聚方法生产聚氨酯泡沫体中的异氰酸酯加成反应的任选的可加入的催化剂。

    Process for the preparation of ethercarboxylic acids
    16.
    发明授权
    Process for the preparation of ethercarboxylic acids 失效
    制备醚羧酸的方法

    公开(公告)号:US5523479A

    公开(公告)日:1996-06-04

    申请号:US230282

    申请日:1994-04-20

    CPC classification number: C07C67/31 C07C51/367

    Abstract: A process for the preparation of carboxylic acids which contain ether groups by the catalytically accelerated addition of alcoholic hydroxyl groups from mono- or polyhydric alcohols to tertiary-alkyl esters of .alpha.,.beta.-unsaturated carboxylic acids, and followed with acid hydrolysis of the tertiary-alkyl .beta.-ethercarboxylate obtained as intermediates in this way.

    Abstract translation: 通过催化加速将醇羟基从一元醇或多元醇加成加成α,β-不饱和羧酸的叔烷基酯,然后酸性水解叔丁醇,制备含有醚基团的羧酸的方法, 以此方式获得的作为中间体的β-羧酸叔丁酯。

    Process for preparing reaction injection moldings
    17.
    发明授权
    Process for preparing reaction injection moldings 失效
    反应注射成型制备工艺

    公开(公告)号:US5356946A

    公开(公告)日:1994-10-18

    申请号:US805735

    申请日:1991-12-09

    Abstract: Disclosed herein is a process for the preparation of a reaction injection molded elastomer comprising injecting a reaction mixture into a closed mold via a RIM machine, with the ratio of components being such that the isocyanate index is from about 70 to about 130, said reaction mixture comprising (a) an organic di- and/or polyisocyanate, (b) an amine terminated chain extender, and (c) a compound which is derived from the reaction of a polyfunctional acetoacetic acid ester and an aliphatic amine having amino groups of different reactivity.

    Abstract translation: 本文公开了一种制备反应注射成型弹性体的方法,包括通过RIM机将反应混合物注入闭合的模具中,其中组分的比例使得异氰酸酯指数为约70至约130,所述反应混合物 包括(a)有机二 - 和/或多异氰酸酯,(b)胺封端的扩链剂,和(c)衍生自多官能乙酰乙酸酯和具有不同反应性氨基的脂族胺反应的化合物 。

    Process for the preparation of N,N-disubstituted mono- and oligourethanes
    20.
    发明授权
    Process for the preparation of N,N-disubstituted mono- and oligourethanes 失效
    制备N,N-取代的单和二乙醚的方法

    公开(公告)号:US5130457A

    公开(公告)日:1992-07-14

    申请号:US25910

    申请日:1987-03-16

    CPC classification number: C07C271/06

    Abstract: N,N-disubstituted monourethanes and oligourethanes are produced by reacting (a) N-aliphatically and/or N-cycloaliphatically and/or N-araliphatically substituted monourethanes and/or oligourethanes with an alkylating agent in the presence of a solid alkali metal hydroxide. No solvent need by employed but if a solvent is used, that solvent should be an aprotic organic solvent. The alkali metal hydroxide must be used in an equivalent amount. A phase transfer catalyst may optionally be employed. The N,N-disubstituted urethanes obtained by this process are useful in the production of dyes, pharmaceutical products and thermostable synthetic materials.

    Abstract translation: N,N-二取代的单氨基甲酸酯和低聚氨酯通过在固体碱金属氢氧化物存在下使(a)N-脂族和/或N-环脂和/或N-芳香取代的单氨基甲酸酯和/或低聚氨酯与烷基化剂反应来制备。 无需使用溶剂,但如果使用溶剂,该溶剂应为非质子有机溶剂。 碱金属氢氧化物必须以等量使用。 可以任选地使用相转移催化剂。 通过该方法获得的N,N-二取代的聚氨酯可用于制备染料,药物产品和耐热合成材料。

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