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公开(公告)号：JP2009114078A
公开(公告)日：2009-05-28
申请号：JP2007285429
申请日：2007-11-01
Inventor： ISHITA MIO , NISHIZAWA YOSHINORI
IPC: C07C51/353 , C07B61/00 , C07C53/126
Abstract: PROBLEM TO BE SOLVED: To provide a method for efficiently producing a cross-coupling compound by a reaction of a Grignard compound with an alkyl halide.
SOLUTION: This method for producing the cross-coupling compound represented by the following formula (3): R
1 -R
2 (wherein, R
1 is a 1-15C alkyl group; R
2 is a 1-30C alkyl group having a carboxy group) comprises reacting the Grignard compound represented by the following formula (1): R
1 MgX (wherein, X is a halogen atom) with an alkyl halide represented by the following formula (2): R
2 -X' (wherein, X' is a halogen atom) in the presence of a crown ether compound and a copper compound.
COPYRIGHT: (C)2009,JPO&INPITAbstract translation: 待解决的问题：提供通过格氏化合物与烷基卤反应有效地制备交叉偶联化合物的方法。 解决方案：用于制备由下式（3）表示的交叉偶联化合物的方法：R
1 -R 2（其中，R 1 是1-15C烷基; R 2是具有羧基的1-30C烷基）包括使由下式（1）表示的格氏化合物：R -
公开(公告)号：JP2008297263A
公开(公告)日：2008-12-11
申请号：JP2007146271
申请日：2007-05-31
Inventor： USUNAMI FUMIKO , TANAMACHI HIROTO , ISHITA MIO
Abstract: PROBLEM TO BE SOLVED: To provide a hair cosmetic that restores or controls a structural change in the inside of the hair occurring in a chemical treatment, drying with a dryer or a daily hair care action and provides the hair with excellent softness and flexible touch from wetting to drying.
SOLUTION: Th hair cosmetic includes: (A) a tertiary amine represented by formula (1) [wherein R
1 is a 6-24C alkyl group or alkenyl group; R
2 and R
3 are each a 1-6C alkyl group or a group of -(AO)
m H (wherein A is a 2-4C alkylene group; and m is a number of 1-6)] or its salt; (B) a branched-chain fatty acid represented by formula (2) (wherein R
4 is a methyl group or an ethyl group; and p is 3-36) or its salt; and (C) silicones and water.
COPYRIGHT: (C)2009,JPO&INPITAbstract translation: 要解决的问题：提供恢复或控制化学处理中发生的毛发内部结构变化的毛发化妆品，用干衣机干燥或每日头发护理作用，并且使头发具有优异的柔软性和 从润湿到干燥的柔韧触感。 本发明的化妆品包括：（A）由式（1）表示的叔胺[其中R“SP”为6-24C烷基或烯基; R
2 和R 3 分别为1-6C烷基或 - （AO） H（其中A为2 -4C亚烷基; m为1-6）]或其盐; （B）由式（2）表示的支链脂肪酸（其中R 4是甲基或乙基; p是3-36）或其盐; 和（C）硅酮和水。 版权所有（C）2009，JPO＆INPIT -
公开(公告)号：JP2007176924A
公开(公告)日：2007-07-12
申请号：JP2006216964
申请日：2006-08-09
Inventor： USUNAMI FUMIKO , TANAMACHI HIROTO , NAGAI MINORU , ISHITA MIO
Abstract: PROBLEM TO BE SOLVED: To provide a hair cosmetic capable of repairing or suppressing the structural change at the inside of the hairs formed by a chemical treatment, drying by a dryer and daily hair care actions and also imparting a good suppleness and pliable feeling from moistened time to even after drying.
SOLUTION: This hair cosmetic comprises (A) an amideamine compound (1) [wherein, R
1 is am 11-23C aliphatic hydrocarbon group; R
2 is H or a 1-4C alkyl; and (m) is 2-4] or its salt, (B) an aromatic alcohol (2) [wherein, R
4 is H, methyl or methoxy; Y is a single bond or a 1-3C alkylene or an alkenylene; Z is H or OH; and (p), (q) are each 0-5 number], (C) a branched fatty acid (3) [wherein, R
5 is methyl or ethyl; and (n) is 3-36] or its salt, and water.
COPYRIGHT: (C)2007,JPO&INPITAbstract translation: 要解决的问题：提供一种能够修复或抑制通过化学处理形成的毛发内部的结构变化，通过干燥器干燥和每日头发护理动作并且还赋予良好的柔软性和柔韧性的头发化妆品 从潮湿的时间到干燥后的感觉。 解决方案：该毛发化妆品包含（A）酰胺胺化合物（1）[其中，R SP 1为11-23个脂肪族烃基; R
2 是H或1-4C烷基; 和（m）为2-4]或其盐，（B）芳族醇（2）[其中，R 4为H，甲基或甲氧基; Y是单键或1-3C亚烷基或亚烯基; Z是H或OH; 和（p），（q）各自为0-5数]，（C）支链脂肪酸（3）[其中，R 5为甲基或乙基; 和（n）为3-36]或其盐和水。 版权所有（C）2007，JPO＆INPIT -
公开(公告)号：JP2011111401A
公开(公告)日：2011-06-09
申请号：JP2009267496
申请日：2009-11-25
Inventor： FUKUI TAKASHI , KAWADA TAKASHI , ISHITA MIO
CPC classification number: A61K8/0254 , A61K8/064 , A61K8/19 , A61K8/27 , A61K8/29 , A61K8/31 , A61K8/33 , A61K8/37 , A61K8/42 , A61K8/585 , A61K8/891 , A61K2800/412 , A61K2800/623 , A61Q17/04
Abstract: PROBLEM TO BE SOLVED: To provide a cosmetic showing high moisture-retaining property, and to provide a cosmetic excellent in ultraviolet protection effect. SOLUTION: The W/O emulsion cosmetic includes (A) a plate-like powder with a surface treated with alkylalkoxysilane, (B) an oil that is in a solid state at 25°C, (C) an oil that is in a liquid state at 25°C, which is chosen from a hydrocarbon oil, an ester oil and an ether oil and (D) water, provided that the mass ratio of component (B) to (A) ä(B)/(A)} is 0.01-5. COPYRIGHT: (C)2011,JPO&INPIT
Abstract translation: 待解决的问题：提供具有高保湿性的化妆品，并提供优异的紫外线防护效果的化妆品。 解决方案：W / O乳液化妆品包括（A）具有用烷基烷氧基硅烷表面处理的板状粉末，（B）在25℃下为固态的油，（C） 在选自烃油，酯油和醚油和（D）水中的25℃的液态下，条件是组分（B）与（A）ä（B）/（ A）}为0.01-5。 版权所有（C）2011，JPO＆INPIT
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公开(公告)号：JP2010150191A
公开(公告)日：2010-07-08
申请号：JP2008330601
申请日：2008-12-25
Inventor： ISHITA MIO
IPC: C07C51/36 , C07B61/00 , C07C53/21 , C07C67/343 , C07C69/65
Abstract: PROBLEM TO BE SOLVED: To provide a method for simply and efficiently producing fluorinated fatty acids from industrially available raw materials.
SOLUTION: The method for producing a fluorinated fatty acid ester represented by formula (3) (wherein R
1 is hydrogen or a 1-10C alkyl group which may have a substituent; R
2 is a 1-20C alkylene group which may have a substituent; R
3 is a 1-6C alkyl group; and R
4 is fluorine or a 1-20C fluorine-containing alkyl group which may have a substituent) comprises reacting an ester compound represented by formula (1) (wherein R
1 , R
2 and R
3 are the same as defined above) with a phosphonium salt represented by formula (2) (wherein R
4 is the same as defined above; R
5 to R
7 are each a 1-10C alkyl group or a 6-15C aryl group which may have a substituent; and X
- is a halogen ion or a triflate anion in the presence of a metal amide compound or a metal hydride).
COPYRIGHT: (C)2010,JPO&INPITAbstract translation: 要解决的问题：提供从工业上可获得的原料简单有效地生产氟化脂肪酸的方法。 解决方案：由式（3）表示的氟化脂肪酸酯的制备方法（其中R 1 SP 1是氢或可以具有取代基的1-10C烷基; R
2 是可以具有取代基的1-20C亚烷基; R“3”是1-6C烷基; R“SP”4是氟或1 可以具有取代基的-20℃的含氟烷基）包括使由式（1）表示的酯化合物（其中R 1 ，R 2 和R 3与上述定义相同）与式（2）表示的鏻盐（其中R 4 与上述定义相同; R 5 至 R“S”是每个1-10C的烷基或可以具有取代基的6-15C的芳基; X - 是卤素离子或三氟甲磺酸根阴离子 存在金属酰胺化合物或金属氢化物）。 版权所有（C）2010，JPO＆INPIT -
Patent Agency Ranking
公开(公告)号：JP2007176923A
公开(公告)日：2007-07-12
申请号：JP2006216963
申请日：2006-08-09
Inventor： USUNAMI FUMIKO , TANAMACHI HIROTO , NAGAI MINORU , ISHITA MIO
Abstract: PROBLEM TO BE SOLVED: To provide a hair cosmetic repairing or suppressing the structural change at the inside of hairs and also capable of imparting a good flexibility.
SOLUTION: This hair cosmetic comprises the components (A), (B), (C) and water. (A) a tertiary amine expressed by formula (1) [wherein, R
1 is a 6-24C alkyl or an alkenyl; R
2 , R
3 are each a 1-6C alkyl or -(AO)
m H (wherein, A is a 2-4C alkylene; and (m) is 1-6 number)] or its salt, (B) an aromatic alcohol including benzyl alcohol, benzyloxyethanol, etc., and (C) a branched fatty acid including 18-methyleicosanoic acid, 16-methylheptadecanoic acid, 16-methyloctadecanoic acid, etc.
COPYRIGHT: (C)2007,JPO&INPITAbstract translation: 要解决的问题：提供修护或抑制毛发内部的结构变化的毛发化妆品，并且还能够赋予良好的柔韧性。 本发明的化妆品包括组分（A），（B），（C）和水。 （A）由式（1）表示的叔胺[其中R 1是6-24C烷基或链烯基; R（SP）2，R SP 3，各自为1-6C烷基或 - （AO）H（其中，A为2-4C亚烷基 ;（m）为1-6数）]或其盐，（B）包括苄醇，苄氧基乙醇等的芳族醇，（C）包含18-甲基十一烷酸，16-甲基十五烷酸， 16-甲基十八烷酸等。版权所有（C）2007，JPO＆INPIT
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公开(公告)号：JP2007176922A
公开(公告)日：2007-07-12
申请号：JP2006216962
申请日：2006-08-09
Inventor： USUNAMI FUMIKO , TANAMACHI HIROTO , NAGAI MINORU , ISHITA MIO
Abstract: PROBLEM TO BE SOLVED: To provide a hair wash excellent in foaming/foam quality and touch feeling on rinsing and finishing, and also capable of repairing or suppressing the hair damage/fatigue destruction.
SOLUTION: This hair wash comprises the following components (A) to (C). (A) a sulfuric acid salt type surfactant expressed by formula: R
1 -O-(C
2 H
4 O)
m -SO
3 M [wherein, R
1 is an 8-18C alkyl or an alkenyl; (m) is 0 or a positive integer; and M is an alkali metal, an alkaline earth metal or ammonium], having that m=0 is 30-45%, m=1 is 18-27%, m=2 is 10-20%, and rest of m=3 in the total sulfuric salts, and also having the total of m=0 to 2 as ≥70%, (B) an amphoteric surfactant and (C) a branched fatty acid expressed by general formula (2) [R
2 is methyl or ethyl; and (n) is 3 to 36] or its salt.
COPYRIGHT: (C)2007,JPO&INPITAbstract translation: 要解决的问题：提供发泡/泡沫质量优异的洗发和漂洗和整理的触感，并且还能够修复或抑制头发损伤/疲劳破坏。 该洗发剂包含以下成分（A）〜（C）。 （A）由下式表示的硫酸盐型表面活性剂：R
-O-（C 2 H 4 O） 3其中R 1是8-18C烷基或链烯基; （m）为0或正整数; 并且M为碱金属，碱土金属或铵]，其中m = 0为30-45％，m = 1为18-27％，m = 2为10-20％，m = 3的其余部分 在总硫酸盐中，m = 0〜2的总和≥70％，（B）两性表面活性剂和（C）由通式（2）表示的支链脂肪酸[R 2＆ / SP>是甲基或乙基; 和（n）为3〜36]或其盐。 版权所有（C）2007，JPO＆INPIT -
公开(公告)号：JP2012144453A
公开(公告)日：2012-08-02
申请号：JP2011002078
申请日：2011-01-07
Inventor： SUGAI YOSHIYA , TAKIGAWA HIROBUMI , SAITO HIROAKI , ARAKI HIROYUKI , ISHITA MIO
Abstract: PROBLEM TO BE SOLVED: To provide an antimicrobial agent which is effective for preventing and improving acne and treating and preventing dermatologic therapy such as atopic dematitis.SOLUTION: The antimicrobial agent comprises a fatty acid derivative represented by general formula (1) (wherein, X denotes a 2 to 14C alkyl group; and y denotes an integer of 5 to 15) or its salt as an active constituent.
Abstract translation: 要解决的问题：提供一种有效预防和改善痤疮并治疗和预防皮肤病治疗如特应性皮炎的抗微生物剂。 解决方案：抗微生物剂包含由通式（1）表示的脂肪酸衍生物（其中X表示2〜14C烷基，y表示5〜15的整数）或其盐作为活性成分。 版权所有（C）2012，JPO＆INPIT
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公开(公告)号：JP2009149546A
公开(公告)日：2009-07-09
申请号：JP2007327735
申请日：2007-12-19
Inventor： ISHITA MIO , FUJIMORI TAKETOSHI , NISHIZAWA YOSHINORI
IPC: C07C51/353 , C07B61/00 , C07C53/126
Abstract: PROBLEM TO BE SOLVED: To provide a simple and efficient method for producing a useful branched fatty acid using industrially available raw materials. SOLUTION: The method for producing a branched fatty acid comprises (a) causing a cyclic ester represented by formula (1) (in the formula, n represents an integer of 9 to 17) to react with hydrogen bromide in an acetic acid solvent to obtain a bromocarboxylic acid represented by formula (2): Br-(CH 2 ) n -CO 2 H (in the formula, n is the same as defined above) and (b) subsequently causing the resulting bromocarboxylic acid to react with a Grignard reagent represented by formula (3): R 1 MgX (in the formula, R 1 represents a 3-8C branched alkyl group, and X represents a halogen atom) to obtain a 13-26C branched fatty acid represented by formula (4): R 1 -(CH 2 ) n -CO 2 H (in the formula, R 1 is the same as defined above, and n is the same as defined above). COPYRIGHT: (C)2009,JPO&INPIT
Abstract translation: 待解决的问题：提供使用工业上可获得的原料制备有用的支链脂肪酸的简单有效的方法。 解决方案：支链脂肪酸的制备方法包括：（a）使式（1）表示的环状酯（式中，n表示9〜17的整数）与溴化氢在乙酸中反应 溶剂以得到由式（2）表示的溴代羧酸：Br-（CH 2 SB 2）SB（H 2）（式中， n与上述定义相同）和（b）随后使得到的溴羧酸与由式（3）表示的格利雅试剂反应：式中，R
1 表示3-8C支链烷基，X表示卤素原子），得到由式（4）表示的13-26C支链脂肪酸：R - （CH < （式中，R 1 ）H（在式中，R SP 1与上述定义相同，n 与上述相同）。 版权所有（C）2009，JPO＆INPIT -
公开(公告)号：JP2008297264A
公开(公告)日：2008-12-11
申请号：JP2007146272
申请日：2007-05-31
Inventor： USUNAMI FUMIKO , TANAMACHI HIROTO , ISHITA MIO
Abstract: PROBLEM TO BE SOLVED: To provide a hair cosmetic that restores or controls a structural change in the inside of the hair occurring in a chemical treatment, drying with a dryer or a daily hair care action and can form the hair with excellent softness and flexible touch from wetting to drying.
SOLUTION: The hair cosmetic includes: (A) an ether amine represented by formula (1) (wherein R
1 is a 6-24C alkyl group or alkenyl group; R
2 is a 2-5C alkylene group; R
3 and R
4 are each a hydrogen atom, a 1-6C alkyl group or a group of -(AO)
m H (wherein A is a 2-4C alkylene group; and m is a number of 1-6); and a is an integer of 2-8) or its salt; and (B) a branched-chain fatty acid represented by formula (2) (wherein R
5 is a methyl group or an ethyl group; and p is 3-36) or its salt and water.
COPYRIGHT: (C)2009,JPO&INPITAbstract translation: 要解决的问题：提供一种能够恢复或控制在化学处理中发生的毛发内部的结构变化，用干燥器干燥或每日头发护理作用的毛发化妆品，并且可以形成具有优异柔软度的头发 柔软的触感从润湿到干燥。 毛发化妆品包括：（A）由式（1）表示的醚胺（其中R
1 是6-24C烷基或烯基; R 2 < / SP>是2-5C亚烷基; R 3和R 4都是氢原子，1-6C烷基或 - （AO）基团） H（其中A为2-4C亚烷基; m为1-6的数）; a为2-8的整数）或其盐; 和（B）由式（2）表示的支链脂肪酸（其中R 5是甲基或乙基，p是3-36）或其盐和水。 版权所有（C）2009，JPO＆INPIT
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