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公开(公告)号:IN168102B
公开(公告)日:1991-02-02
申请号:IN607DE1986
申请日:1986-07-10
Applicant: LUBRIZOL CORP
Inventor: DIBIASE STEPHEN AUGUSTINE , SOWERBY ROGER LEE , HIGGINS WILLIAM ALBERT
IPC: C10M135/02 , C10M135/06
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公开(公告)号:AU7691787A
公开(公告)日:1988-01-12
申请号:AU7691787
申请日:1987-06-19
Applicant: LUBRIZOL CORP
Inventor: SOWERBY ROGER LEE
IPC: C07D249/12 , C07F5/02 , C10L1/224 , C10L1/232 , C10L1/24 , C10L1/26 , C10L1/30 , C10M133/44 , C10M133/58 , C10M135/04 , C10M135/32 , C10M137/00 , C10M139/00 , C10M149/10 , C10M151/00 , C10M153/00 , C10M155/04 , C10N30/02 , C10N30/04 , C10N30/06 , C10N40/04 , C10N40/20 , C10N40/25 , C10L1/22
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公开(公告)号:IN177671B
公开(公告)日:1997-02-15
申请号:IN344DE1989
申请日:1989-04-17
Applicant: LUBRIZOL CORP
Inventor: DIBIASE STEPHEN AUGUSTINE , SOWERBY ROGER LEE , HIGGINS WILLIAM ALBERT
IPC: C10M135/02 , C10M135/06
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公开(公告)号:MX9207077A
公开(公告)日:1994-06-30
申请号:MX9207077
申请日:1992-12-07
Applicant: LUBRIZOL CORP
Inventor: DIBIASE STEPHEN A , SOWERBY ROGER LEE , HIGGINS WILLIAM ALBERT
IPC: C07G99/00 , C08K5/36 , C10M135/02 , C10M119/26
Abstract: Sulfur-containing compositions are described which are prepared by sulfurizing (A) at least one fatty acid ester of a polyhydric alcohol, or (B) at least one fatty acid, fatty acid ester of a monohydric alcohol, or a mixture thereof, or (C) at least one other olefin, or (D) mixtures of any two or more of (A), (B) and (C), in the presence of a catalytic amount of (E) at least one salt of at least one dithiocarbamic acid of the formula R1(R2)N-CSSH wherein R1 and R2 are each independently hydrocarbyl groups, or (F) at least one mercapto benzothiazole, or (G) mixtures of (E) and (F). Preferably, various mixtures of (A), (B) and (C) are sulfurized in accordance with the invention. The incorporation of a catalytic amount of salt of at least one dithiocarbamic acid of Formula I or at least one mercapto benzothiazole (or mixtures thereof) results in the preparation of sulfurized compositions which are characterized by excellent oil solubility and higher sulfur contents, and the compositions generally are lighter in color when compared to sulfurized compositions prepared in the absence of such catalysts. The sulfurized compositions prepared in accordance with the present invention are useful as general purpose antioxidants and friction modifiers for lubricating compositions and automatic transmission fluids and in particular, as additives in metal working lubricants. The above-described sulfurized compositions as well as sulfurized compositions prepared in the absence of catalysts (E) and/or (F) are useful in asphalt compositions.
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公开(公告)号:AU612646B2
公开(公告)日:1991-07-18
申请号:AU1546488
申请日:1988-03-11
Applicant: LUBRIZOL CORP
Inventor: BIASE STEPHEN AUGUSTINE DI , SOWERBY ROGER LEE
IPC: C07C35/06 , C07C67/00 , C07C313/00 , C07C319/02 , C07G99/00 , C10M135/04 , C10M155/04 , C10N30/06 , C10N70/00 , C07C148/00 , C07C149/12 , C07B35/06
Abstract: A process for producing a sulfurized olefin product substantially free of ash containing waste is disclosed. The process involves dehydrohalogenation of an olefin/sulfur halide complex by contacting the complex with a protic solvent in the absence of any metal ion. The process allows for the solvolytic dehydrohalogenation of the complex. The sulfurized olefin product obtained is isolated and may be subjected to further processing to remove any remaining halides. The resulting sulfurized olefin is a useful additive in lubricating oils.
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公开(公告)号:AT57180T
公开(公告)日:1990-10-15
申请号:AT86904701
申请日:1986-07-21
Applicant: LUBRIZOL CORP
Inventor: DIBIASE STEPHEN A , SOWERBY ROGER LEE , HIGGINS WILLIAM ALBERT
IPC: C07C323/00 , C08K5/36 , C08L95/00 , C10M135/02
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公开(公告)号:AU598742B2
公开(公告)日:1990-07-05
申请号:AU6148086
申请日:1986-07-21
Applicant: LUBRIZOL CORP
Inventor: BIASE STEPHEN A DI , SOWERBY ROGER LEE , HIGGINS WILLIAM ALBERT
IPC: C07G99/00 , C08K5/36 , C10M135/02 , C07C149/00 , C08L95/00 , C10M159/12 , C10M169/04
Abstract: Sulfur-containing compositions are described which are prepared by sulfurizing (A) at least one fatty acid ester of a polyhydric alcohol, or (B) at least one fatty acid, fatty acid ester of a monohydric alcohol, or a mixture thereof, or (C) at least one other olefin, or (D) mixtures of any two or more of (A), (B) and (C), in the presence of a catalytic amount of (E) at least one salt of at least one dithiocarbamic acid of the formula R1(R2)N-CSSH wherein R1 and R2 are each independently hydrocarbyl groups, or (F) at least one mercapto benzothiazole, or (G) mixtures of (E) and (F). Preferably, various mixtures of (A), (B) and (C) are sulfurized in accordance with the invention. The incorporation of a catalytic amount of salt of at least one dithiocarbamic acid of Formula I or at least one mercapto benzothiazole (or mixtures thereof) results in the preparation of sulfurized compositions which are characterized by excellent oil solubility and higher sulfur contents, and the compositions generally are lighter in color when compared to sulfurized compositions prepared in the absence of such catalysts. The sulfurized compositions prepared in accordance with the present invention are useful as general purpose antioxidants and friction modifiers for lubricating compositions and automatic transmission fluids and in particular, as additives in metal working lubricants. The above-described sulfurized compositions as well as sulfurized compositions prepared in the absence of catalysts (E) and/or (F) are useful in asphalt compositions.
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公开(公告)号:ZA865342B
公开(公告)日:1987-03-25
申请号:ZA865342
申请日:1986-07-17
Applicant: LUBRIZOL CORP
Inventor: DIBIASE STEPHEN A , SOWERBY ROGER LEE , HIGGINS WILLIAM ALBERT
IPC: C10M135/02 , B01J31/02 , B21B45/02 , B21C23/22 , B21D37/18 , C04B20060101 , C07C67/00 , C07C313/00 , C07C323/00 , C08H3/00 , C08K3/02 , C08K3/06 , C08L95/00 , C10C3/00 , C10M20060101 , C10M125/22 , C10M135/06 , C10M135/18 , C10M135/36 , C10N30/06 , C10N40/04 , C10N40/08 , C10N40/20 , C10M , C04B
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公开(公告)号:AU6148086A
公开(公告)日:1987-03-05
申请号:AU6148086
申请日:1986-07-21
Applicant: LUBRIZOL CORP
Inventor: DIBIASE STEPHEN A , SOWERBY ROGER LEE , HIGGINS WILLIAM ALBERT
IPC: C07G99/00 , C08K5/36 , C10M135/02 , C07C149/00 , C08L95/00
Abstract: Sulfur-containing compositions are described which are prepared by sulfurizing (A) at least one fatty acid ester of a polyhydric alcohol, or (B) at least one fatty acid, fatty acid ester of a monohydric alcohol, or a mixture thereof, or (C) at least one other olefin, or (D) mixtures of any two or more of (A), (B) and (C), in the presence of a catalytic amount of (E) at least one salt of at least one dithiocarbamic acid of the formula R1(R2)N-CSSH wherein R1 and R2 are each independently hydrocarbyl groups, or (F) at least one mercapto benzothiazole, or (G) mixtures of (E) and (F). Preferably, various mixtures of (A), (B) and (C) are sulfurized in accordance with the invention. The incorporation of a catalytic amount of salt of at least one dithiocarbamic acid of Formula I or at least one mercapto benzothiazole (or mixtures thereof) results in the preparation of sulfurized compositions which are characterized by excellent oil solubility and higher sulfur contents, and the compositions generally are lighter in color when compared to sulfurized compositions prepared in the absence of such catalysts. The sulfurized compositions prepared in accordance with the present invention are useful as general purpose antioxidants and friction modifiers for lubricating compositions and automatic transmission fluids and in particular, as additives in metal working lubricants. The above-described sulfurized compositions as well as sulfurized compositions prepared in the absence of catalysts (E) and/or (F) are useful in asphalt compositions.
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公开(公告)号:IN179989B
公开(公告)日:1998-01-03
申请号:IN513DE1990
申请日:1990-05-28
Applicant: LUBRIZOL CORP
Inventor: SOWERBY ROGER LEE , SCHARF CURTIS RICHARD
IPC: C08F210/14
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