公开(公告)号：JP2007002049A

公开(公告)日：2007-01-11

申请号：JP2005181838

申请日：2005-06-22

Applicant: NISSAN MOTOR ,  MITSUBISHI CHEM CORP

Inventor： MURAMATSU HIRONOBU ,  UNNO HARUO ,  ODA TAKASHI ,  KAI YASUAKI ,  KAWA MANABU ,  SOMA MINORU ,  ASANO MARI

IPC: C08J3/20 ,  C08F2/44 ,  C08K3/22 ,  C08L101/00

Abstract: PROBLEM TO BE SOLVED: To prevent a molecular weight of an organic polymer from being lowered, when a polymer composite is produced from the organic polymer and alumina particles at a nano-order level having a major axis of 10-500 nm, and to prevent mechanical characteristics, such as impact resistance, of the polymer from being deteriorated, nor transparency thereof from being deteriorated by discoloration. SOLUTION: A method for producing the polymer composite comprises drying absorbed water contained in the alumina particles having the major axis of 10-500 nm, so as to attain a loss on heating to 150°C from room temperature of not more than 2 wt%, and then mixing the dried alumina particles with the organic polymer, so as to form them into the composite. COPYRIGHT: (C)2007,JPO&INPIT

公开(公告)号：JP2006057080A

公开(公告)日：2006-03-02

申请号：JP2005209159

申请日：2005-07-19

Applicant: Mitsubishi Chemicals Corp ,  Nissan Motor Co Ltd ,  三菱化学株式会社 ,  日産自動車株式会社

Inventor： KAWA MANABU ,  SOMA MINORU ,  MURAMATSU HIRONOBU ,  ITO TOMOHIRO ,  KAI YASUAKI ,  MOROHOSHI KATSUMI

IPC: C08L69/00 ,  C08J5/00 ,  C08K3/22

Abstract: PROBLEM TO BE SOLVED: To provide a thermoplastic resin composition containing an aromatic polycarbonate resin and particles of a metal oxide which is exemplified by silica, having a low coefficient of linear expansion, and having high transparency at the same time, while keeping stability in quality and processability in plastic molding.
SOLUTION: This thermoplastic resin composition contains the aromatic polycarbonate resin and the particles of the metal oxide, wherein the thermoplastic resin composition has a total light transmittance of ≥ 70%, when measured after molded into a molded product having a thickness of 1mm, and a coefficient of linear thermal expansion of 30-60 ppm/K, when measured by being raised in its temperature from 30°C to 80°C, and a chloroform-soluble component of the composition has a weight-average molecular weight in a range of 7×10
4 to 700×10
4 .
COPYRIGHT: (C)2006,JPO&NCIPI

Abstract translation: 待解决的问题：提供一种含有芳族聚碳酸酯树脂的热塑性树脂组合物和金属氧化物的颗粒，其由二氧化硅示例，具有低的线膨胀系数，同时具有高透明度，同时保持 塑料成型中质量稳定性和加工性。 解决方案：该热塑性树脂组合物含有芳族聚碳酸酯树脂和金属氧化物颗粒，其中热塑性树脂组合物在模制成厚度为1mm的模塑产品后测量时的总透光率≥70％ ，并且当通过在30℃至80℃的温度下升高而测量时，线性热膨胀系数为30-60ppm / K，组合物的氯仿可溶组分的重均分子量为 范围为7×10 4 至700×10 4 。 版权所有（C）2006，JPO＆NCIPI

公开(公告)号：JP2005325306A

公开(公告)日：2005-11-24

申请号：JP2004146766

申请日：2004-05-17

Applicant: Mitsubishi Chemicals Corp ,  Nissan Motor Co Ltd ,  三菱化学株式会社 ,  日産自動車株式会社

Inventor： MURAMATSU HIRONOBU ,  ITO TOMOHIRO ,  KAI YASUAKI ,  KAWA MANABU ,  SOMA MINORU

IPC: C08K9/00 ,  C08G64/20 ,  C08L69/00

Abstract: PROBLEM TO BE SOLVED: To uniformly disperse metal oxide particulates into the polycarbonate resin composition during a polycarbonate resin composition manufacturing process using melt polymerization, to improve the degree of polymerization of the polycarbonate resin constituting the polycarbonate resin composition, and to improve the mechanical strength, heat resistance, impact resistance, transparency, and dimensional stability of the polycarbonate resin composition. SOLUTION: A sol of metal oxide particulates is prepared, with its pH adjusted to be 6-8, and is mixed into a dicarbonate compound and into a diol compound. Melt polymerization of the two compounds is carried out for obtaining a polycarbonate resin composition with metal oxide particulates dispersed therein. COPYRIGHT: (C)2006,JPO&NCIPI

Abstract translation: 要解决的问题：为了在使用熔融聚合的聚碳酸酯树脂组合物制造过程中将金属氧化物微粒均匀分散到聚碳酸酯树脂组合物中，为了提高构成聚碳酸酯树脂组合物的聚碳酸酯树脂的聚合度， 机械强度，耐热性，耐冲击性，透明性和聚碳酸酯树脂组合物的尺寸稳定性。 解决方案：制备金属氧化物颗粒溶胶，将其pH调节至6-8，并混合到二碳酸酯化合物中并加入二醇化合物中。 进行两种化合物的熔融聚合，得到分散有金属氧化物微粒的聚碳酸酯树脂组合物。 版权所有（C）2006，JPO＆NCIPI

公开(公告)号：JP2008056556A

公开(公告)日：2008-03-13

申请号：JP2007199344

申请日：2007-07-31

Applicant: Mitsubishi Chemicals Corp ,  Nissan Motor Co Ltd ,  三菱化学株式会社 ,  日産自動車株式会社

Inventor： FUJITA NAOKO ,  KAWA MANABU ,  SOMA MINORU ,  ODA TAKASHI ,  UNNO HARUO ,  MOROHOSHI KATSUMI ,  ITO TOMOHIRO ,  KAI YASUAKI ,  MURAMATSU HIRONOBU

IPC: C01F7/02 ,  C08K9/06 ,  C08L69/00

Abstract: PROBLEM TO BE SOLVED: To provide surface-coated aluminum oxide nanoparticles which can be evenly incorporated into a polycarbonate resin in a satisfactorily dispersed state while keeping the molecular weight of the polycarbonate resin on at least a specific level, and a highly transparent polycarbonate resin composition which contains the surface-coated aluminum oxide nanoparticle and is excellent in mechanical strength, dimensional stability and thermal stability. SOLUTION: The surface-coated aluminum oxide nanoparticles have their surfaces coated with a dispersant and a silylating agent. When a sample surface is irradiated with a monochromatized Al-Kα line using an X-ray photoelectron spectroscope to calculate surface element proportions from the areas of the resultant photoelectron peaks, the contents (atm%) of nitrogen atoms, sulfur atoms derived from thiol groups and halogen atoms are each 2 or lower. When surface element proportions are calculated from the areas of the resultant photoelectron peaks attributable to Al2p and Si2s, the concentration of silicon atoms (mol%) is 0.05-30 based on the aluminum atoms. COPYRIGHT: (C)2008,JPO&INPIT

Abstract translation: 要解决的问题：提供可以以令人满意的分散状态均匀地掺入聚碳酸酯树脂中的表面被覆的氧化铝纳米颗粒，同时保持聚碳酸酯树脂的分子量至少具有特定的水平，并且高透明度 聚碳酸酯树脂组合物，其含有表面被覆的氧化铝纳米粒子，机械强度，尺寸稳定性，热稳定性优异。 表面涂覆的氧化铝纳米颗粒的表面涂覆有分散剂和甲硅烷基化剂。 当使用X射线光电子能谱仪用单色化的Al-Kα线照射样品表面，从所得光电子峰的面积计算表面元素比例时，氮原子的含量（atm％），衍生自硫醇基团的硫原子 卤素原子分别为2以下。 当从由Al2p和Si2s归属的所得光电子峰的面积计算表面元素比例时，硅原子的浓度（mol％）基于铝原子为0.05-30。 版权所有（C）2008，JPO＆INPIT

公开(公告)号：JP2007177137A

公开(公告)日：2007-07-12

申请号：JP2005378802

申请日：2005-12-28

Applicant: Mitsubishi Chemicals Corp ,  Nissan Motor Co Ltd ,  三菱化学株式会社 ,  日産自動車株式会社

Inventor： MOROHOSHI KATSUMI ,  KAI YASUAKI ,  MURAMATSU HIRONOBU ,  ITO TOMOHIRO ,  KAWA MANABU ,  SOMA MINORU

IPC: C09C1/00 ,  C01B33/146 ,  C01F7/02 ,  C08K3/22 ,  C08L101/00 ,  C09C1/28 ,  C09C1/40 ,  C09C3/08 ,  C09C3/10

CPC classification number: C09C1/3081

Abstract: PROBLEM TO BE SOLVED: To provide inorganic fine particles in nanometer order level having excellent dispersibility to a resin, and a resin composition using the same which has high mechanical properties such as elasticity, has a low coefficient of linear expansion, and is excellent in transparency. SOLUTION: The resin composition is obtained by blending and dispersing, into a resin, a particulate metal oxide derivative comprising a metal oxide (A), a compound (B) having the ability of forming a first chemical bond to the metal oxide (A), and a compound (C) having the ability of forming a second chemical bond to the compound (B) and also having miscibility with the resin. COPYRIGHT: (C)2007,JPO&INPIT

Abstract translation: 要解决的问题：为了提供具有优异的树脂分散性的纳米级的无机细颗粒，并且使用具有高弹性等机械性能的树脂组合物具有低的线性膨胀系数，并且是 透明度很好 解决方案：通过将树脂中的金属氧化物（A），具有与金属氧化物形成第一化学键的能力的化合物（B）共混并分散在树脂中而获得树脂组合物 （A）和具有与化合物（B）形成第二化学键的能力并且与树脂具有混溶性的化合物（C）。 版权所有（C）2007，JPO＆INPIT

公开(公告)号：JP2007031684A

公开(公告)日：2007-02-08

申请号：JP2005313187

申请日：2005-10-27

Applicant: Mitsubishi Chemicals Corp ,  Nissan Motor Co Ltd ,  三菱化学株式会社 ,  日産自動車株式会社

Inventor： ITO TOMOHIRO ,  UNNO HARUO ,  ODA TAKASHI ,  KAI YASUAKI ,  KAWA MANABU ,  SOMA MINORU

IPC: C08L101/00 ,  C08K3/22 ,  C08K9/04

CPC classification number: C08K5/521

Abstract: PROBLEM TO BE SOLVED: To provide a resin composition which includes high aspect ratio metal oxide particles being uniformly dispersed and is excellent in both the mechanical properties and transparency. SOLUTION: The resin composition comprises a resin and a metal oxide particle composite incorporated in the resin, in which the metal oxide particle composite comprises an organic phosphorus compound chemically bonded to the metal oxide particle. COPYRIGHT: (C)2007,JPO&INPIT

Abstract translation: 要解决的问题：提供包含均匀分散的高纵横比金属氧化物颗粒并且机械性能和透明性都优异的树脂组合物。 解决方案：树脂组合物包含树脂中掺入的树脂和金属氧化物颗粒复合物，其中金属氧化物颗粒复合物包含与金属氧化物颗粒化学键合的有机磷化合物。 版权所有（C）2007，JPO＆INPIT

公开(公告)号：JP2006315905A

公开(公告)日：2006-11-24

申请号：JP2005139927

申请日：2005-05-12

Applicant: Mitsubishi Chemicals Corp ,  Nissan Motor Co Ltd ,  三菱化学株式会社 ,  日産自動車株式会社

Inventor： ODA TAKASHI ,  KAI YASUAKI ,  ITO TOMOHIRO ,  MOROHOSHI KATSUMI ,  MURAMATSU HIRONOBU ,  KAWA MANABU ,  SOMA MINORU

IPC: C01B13/14 ,  C01F7/02 ,  C08K9/04 ,  C08L101/00

Abstract: PROBLEM TO BE SOLVED: To provide a resin composition in which both of mechanical properties and optical properties are excellent. SOLUTION: A metal oxide particle composite provided with metal oxide particles and organic acid salt comprised through surface treatment to the metal oxide particles is incorporated into a resin, so as to be the resin composition. COPYRIGHT: (C)2007,JPO&INPIT

Abstract translation: 要解决的问题：提供机械性能和光学性能都优异的树脂组合物。 解决方案：将通过金属氧化物颗粒的表面处理包含的金属氧化物颗粒和有机酸盐的金属氧化物颗粒复合物引入树脂中，以作为树脂组合物。 版权所有（C）2007，JPO＆INPIT

公开(公告)号：JP2006160879A

公开(公告)日：2006-06-22

申请号：JP2004354100

申请日：2004-12-07

Applicant: Mitsubishi Chemicals Corp ,  Nissan Motor Co Ltd ,  三菱化学株式会社 ,  日産自動車株式会社

Inventor： MURAMATSU HIRONOBU ,  ITO TOMOHIRO ,  KAI YASUAKI ,  MOROHOSHI KATSUMI ,  KAWA MANABU ,  SOMA MINORU

IPC: C08G81/02 ,  C08G64/30 ,  C08J3/215 ,  C08K3/00 ,  C08L69/00

Abstract: PROBLEM TO BE SOLVED: To provide a dispersant for inorganic fillers of a polycarbonate composition which is excellent in dispersing inorganic micro-particles at a nanometer order level and most suitable for the polycarbonate compositions having a sufficient degree of polymerization and excellent transparency.
SOLUTION: The dispersant for inorganic fillers of the polycarbonate composition contains a polycarboxylic acid and a polycarbonate and is prepared by ester-bonding and grafting at least part of the COOH groups in the polycarboxylic acid with the polycarbonate.
COPYRIGHT: (C)2006,JPO&NCIPI

Abstract translation: 解决的问题：提供一种聚碳酸酯组合物的无机填料用分散剂，该分散剂在纳米级分级上分散无机微粒子是优异的，最适用于具有足够聚合度和优异透明度的聚碳酸酯组合物。 解决方案：聚碳酸酯组合物的无机填料的分散剂包含多元羧酸和聚碳酸酯，并且通过使多元羧酸中的至少一部分COOH基与聚碳酸酯酯化和接枝来制备。 版权所有（C）2006，JPO＆NCIPI

公开(公告)号：JP2006056974A

公开(公告)日：2006-03-02

申请号：JP2004239406

申请日：2004-08-19

Applicant: Mitsubishi Chemicals Corp ,  Nissan Motor Co Ltd ,  三菱化学株式会社 ,  日産自動車株式会社

Inventor： ITO TOMOHIRO ,  MURAMATSU HIRONOBU ,  KAI YASUAKI ,  KAWA MANABU ,  SOMA MINORU

IPC: C08L69/00 ,  C08G64/00 ,  C08K9/06

Abstract: PROBLEM TO BE SOLVED: To provide a polycarbonate resin-based resin composition excellent in physical properties including mechanical strength, dimensional stability and heat resistance and having excellent transparency and color tone.
SOLUTION: The resin composition comprises a polycarbonate resin and metal oxide particles dispersed in the polycarbonate resin, wherein at least one kind of aliphatic hydrocarbon group and at least one kind of aromatic hydrocarbon group are bound onto the surface of the metal oxide particles.
COPYRIGHT: (C)2006,JPO&NCIPI

Abstract translation: 解决问题：提供具有机械强度，尺寸稳定性和耐热性等物理性能优异且透明性和色调优异的聚碳酸酯树脂系树脂组合物。 解决方案：树脂组合物包含分散在聚碳酸酯树脂中的聚碳酸酯树脂和金属氧化物颗粒，其中至少一种脂族烃基和至少一种芳族烃基结合到金属氧化物颗粒的表面上 。 版权所有（C）2006，JPO＆NCIPI