ELECTROLYTE FORMATION FOR A SOLID OXIDE FUEL CELL DEVICE
    14.
    发明申请
    ELECTROLYTE FORMATION FOR A SOLID OXIDE FUEL CELL DEVICE 审中-公开
    固体氧化物燃料电池装置的电解质形成

    公开(公告)号:WO2014126716A1

    公开(公告)日:2014-08-21

    申请号:PCT/US2014/013729

    申请日:2014-01-30

    Abstract: A method of fabricating a SSZ/SDC bi-layer electrolyte solid oxide fuel cell, comprising the steps of: fabricating an NiO-YSZ anode substrate from a mixed NiO and yttria-stabilized zirconia by tape casting; sequentially depositing a NiO-SSZ buffer layer, a thin SSZ electrolyte layer and a SDC electrolyte on the NiO-YSZ anode substrate by a particle suspension coating or spraying process, wherein the layers are co-fired at high temperature to densify the electrolyte layers to at least about 96% of their theoretical densities; and painting/spraying a SSC-SDC slurry on the SDC electrolyte to form a porous SSC-SDC cathode. A SSZ/SDC bi-layer electrolyte cell device and a method of using such device are also discussed.

    Abstract translation: 一种制造SSZ / SDC双层电解质固体氧化物燃料电池的方法,包括以下步骤:通过胶带铸造从混合的NiO和氧化钇稳定的氧化锆制造NiO-YSZ阳极基板; 通过颗粒悬浮涂布或喷涂方法在NiO-YSZ阳极基底上依次沉积NiO-SSZ缓冲层,薄SSZ电解质层和SDC电解质,其中这些层在高温下共烧以使电解质层致密化 至少约96%的理论密度; 并在SDC电解液上喷涂/喷涂SSC-SDC浆料,形成多孔SSC-SDC阴极。 还讨论了SSZ / SDC双层电解质电池单元及其使用方法。

    BENZO [1,2-B:4,5-B'] DITHIOPHENE-THIENOTHIOPHENE BASED CONJUGATED POLYMERS
    15.
    发明申请
    BENZO [1,2-B:4,5-B'] DITHIOPHENE-THIENOTHIOPHENE BASED CONJUGATED POLYMERS 审中-公开
    苯并[1,2-B:4,5-B']二苯基乙烯基联苯聚合物

    公开(公告)号:WO2014088795A1

    公开(公告)日:2014-06-12

    申请号:PCT/US2013/070674

    申请日:2013-11-19

    Abstract: Compositions, synthesis and applications for furan, thiophene and selenophene derivatized benzo[1,2-b:3,4-b']dithiophene(BDT)-thienothiophene (BDT-TT) based polymers, namely, poly[(4,8-bis(5-(2-ethyhexyl)selenophen-2-yl)-benzo[1,2-b;4,5-b']dithiophene)-2,6-diyl-alt-(4-(2-ethylhexanoyl)-3-fluorothieno[3,4-b]thiophene)-2-6-diyl (CS-15), poly[(4,8-bis(5-(2-ethyhexyl)selenophen-2-yl)-benzo[l,2-b;4,5-b']dithiophene)-2,6-diyl-alt-(4-(2-ethylhexyl)-3-fluorothieno[3,4-b]thiophene)-2- carboxylate-2-6-diyl (CS-16), poly[(4,8-bis(5-(2-ethyhexyl)furan-2-yl)-benzo[1,2-b;4,5-b']dithiophene)-2,6-diyl-alt-(4-(2-ethylhexyl)-3-fluorothieno[3,4-b]thiophene)-2-carboxylate-2-6-diyl (CS-18) and poly[(4,8-bis(5-hexylfuran-2-yl)-benzo[1,2-b;4,5-b']dithiophene)-2,6-diyl-alt-(4-(2-ethylhexanoyl)-3-fluorothieno[3,4-b]thiophene)-2-6-diyl (CS-24) are disclosed. Further, an organic solar cell constructed of a derivatized benzo[l,2-b:3,4-b']dithiophene(BDT)-thienothiophene (BDT-TT) based polymer is discussed.

    Abstract translation: 呋喃,噻吩和硒吩衍生的苯并[1,2-b:3,4-b']二噻吩(BDT) - 噻吩并噻吩(BDT-TT)基聚合物的组合物,合成和应用,即聚[(4,8- 双(5-(2-乙基己基)硒吩-2-基) - 苯并[1,2-b:4,5-b']二噻吩)-2,6-二基 - 交替 - (4-(2-乙基己) -3-氟噻吩并[3,4-b]噻吩)-2-6-二基(CS-15),聚[(4,8-双(5-(2-乙基己基)硒吩-2-基) (4-(2-乙基己基)-3-氟噻吩并[3,4-b]噻吩)-2-羧酸叔丁酯 (CS-16),聚[(4,8-双(5-(2-乙基己基)呋喃-2-基) - 苯并[1,2-b; 4,5-b']二噻吩 )-2,6-二基-2-(4-(2-乙基己基)-3-氟噻吩并[3,4-b]噻吩)-2-羧酸酯-2,6-二基(CS-18)和聚[ 4,8-双(5- hexylfuran -2-基) - 苯并[1,2-b:4,5-b']二噻吩)-2,6-二基 - 交替 - (4-(2-乙基己) - 公开了3-氟噻吩并[3,4-b]噻吩)-2-6-二基(CS-24)。 此外,讨论了由衍生的苯并[1,2-b:3,4-b']二噻吩(BDT) - 噻吩并噻吩(BDT-TT)基聚合物构成的有机太阳能电池。

    COMPOSITIONS AND APPLICATIONS OF THREE COMPONENT BENZO[1,2-B:4,5-B]DITHIOPHENE-THIENOTHIOPHENE RANDOMLY SUBSTITUTED POLYMERS FOR ORGANIC SOLAR CELLS
    20.
    发明公开
    COMPOSITIONS AND APPLICATIONS OF THREE COMPONENT BENZO[1,2-B:4,5-B]DITHIOPHENE-THIENOTHIOPHENE RANDOMLY SUBSTITUTED POLYMERS FOR ORGANIC SOLAR CELLS 审中-公开
    组合物和应用偶发取代三组分苯并[1,2-B:4,5-B]联噻吩并噻吩聚合物有机太阳能电池

    公开(公告)号:EP3149787A1

    公开(公告)日:2017-04-05

    申请号:EP15798705.8

    申请日:2015-05-28

    Abstract: A polymer having two different sets of repeat units consisting essentially of: (Formula 1) and Additionally, in the polymer R1 can be selected from the group consisting of alkyl group, alkoxy group, aryl groups and combinations thereof. In the polymer, n and m can be greater than 1. In the polymer, x and y can be different from each other and independently selected from the group consisting of: an alkoxy group, a substituted alkoxy group, an aryl group, an alkyl group, a substituted alkyl group, (Formula 2), where y = 1-3, (Formula 3) where y = 0-12, (Formula 4) where R2 is selected from the group consisting of H, alkyl groups, and aryl groups, (Formula 5) where R3 is selected from the group consisting of H, alkyl groups, and aryl groups, (Formula 6) where R4 and R5 are independently selected from the group consisting of H, alkyl groups, and aryl groups, --NR6R7 where R6 and R7 are independently selected from the group consisting of H, alkyl groups, and aryl groups.

    Abstract translation: 具有两组不同的重复单元基本上由一种聚合物:在聚合物-R1(式1)和另外,可以选自烷基,烷氧基,芳基和它们的组合中选择。 在聚合物中,n和m可以是大于1.在聚合物中,x和选自所选y可以是从不同的海誓山盟和unabhängig:在烷基的烷氧基,一个substituiertem烷氧基,芳基的 其中R 2选自下组:选自H,烷基,和芳基烷基,取代的烷基,(式2),其中y = 1-3,(式3),其中y = 0-12,(式4) 基团,其中R 3选自下组:选自H,烷基,和芳基(式5),(式6)其中,R4和R5是unabhängig选自选自H选择,烷基,和芳基, - -NR6R7,其中R6和R7unabhängig选自选自H,烷基,和芳基。

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