公开(公告)号：DE69628057D1

公开(公告)日：2003-06-12

申请号：DE69628057

申请日：1996-03-22

Applicant: PHILLIPS PETROLEUM CO

Inventor： BROWN RONALD E ,  REED LARRY E ,  GREENWOOD GIL J ,  HARPER TIMOTHY P ,  SCHARRE MARK D

IPC: C09K3/00 ,  C10G9/14 ,  C10G9/16 ,  C10G9/00

Abstract: The rate of formation of carbon on the surfaces of thermal cracking tubes and the production of carbon monoxide during thermal cracking of hydrocarbons are inhibited by the use of cracking tubes treated with an antifoulant, including tin compound, silicon compound and sulfur compounds in the presence of a reducing gas such as hydrogen. Additionally, the concentration of carbon monoxide in a pyrolytic cracking process product stream is reduced by the treatment of the thermal cracking tubes of such process with a reducing gas having a concentration of a sulfur compound.

公开(公告)号：DE69621503T2

公开(公告)日：2003-01-09

申请号：DE69621503

申请日：1996-03-22

Applicant: PHILLIPS PETROLEUM CO

Inventor： BROWN RONALD E ,  HARPER TIMOTHY P ,  REED LARRY E ,  SCHARRE MARK D ,  GREENWOOD GIL J

IPC: C09K3/00 ,  C10G9/14 ,  C10G9/16

Abstract: The rate of formation of carbon on the surfaces of thermal cracking tubes and the production of carbon monoxide during thermal cracking of hydrocarbons are inhibited by the use of cracking tubes treated with an antifoulant, including tin compound, silicon compound and sulfur compounds in the presence of a reducing gas such as hydrogen. Additionally, the concentration of carbon monoxide in a pyrolytic cracking process product stream is reduced by the treatment of the thermal cracking tubes of such process with a reducing gas having a concentration of a sulfur compound.

公开(公告)号：AT185589T

公开(公告)日：1999-10-15

申请号：AT95113299

申请日：1995-08-24

Applicant: PHILLIPS PETROLEUM CO

Inventor： REED LARRY E ,  BROWN RONALD E ,  DEGRAFFENRIED JAMES P ,  MURTHA TIMOTHY P ,  GREENWOOD GIL J ,  HARPER TIMOTHY P ,  SCHARRE MARK D

IPC: C10G75/04 ,  C10G9/16 ,  C21D1/34 ,  C21D1/52

Abstract: A novel method for treating the radiant tubes of a fired pyrolysis heater with an antifoulant composition for inhibiting the formation and deposition of coke thereon. Such novel method includes introducing the antifoulant into the crossover conduit between the convection tubes and radiant tubes of the fired pyrolysis heater.

公开(公告)号：BR9601103A

公开(公告)日：1998-01-06

申请号：BR9601103

申请日：1996-03-22

Applicant: PHILLIPS PETROLEUM CO

Inventor： BROWN RONALD E ,  REED LARRY E ,  GREENWOOD GIL J ,  HARPER TIMOTHY P ,  SCHARRE MARK D

IPC: C09K3/00 ,  C10G9/14 ,  C10G9/16

Abstract: The rate of formation of carbon on the surfaces of thermal cracking tubes and the production of carbon monoxide during thermal cracking of hydrocarbons are inhibited by the use of cracking tubes treated with an antifoulant, including tin compound, silicon compound and sulfur compounds in the presence of a reducing gas such as hydrogen. Additionally, the concentration of carbon monoxide in a pyrolytic cracking process product stream is reduced by the treatment of the thermal cracking tubes of such process with a reducing gas having a concentration of a sulfur compound.

公开(公告)号：AU4805696A

公开(公告)日：1996-10-03

申请号：AU4805696

申请日：1996-03-13

Applicant: PHILLIPS PETROLEUM CO

Inventor： BROWN RONALD E ,  REED LARRY E ,  GREENWOOD GIL J ,  HARPER TIMOTHY P ,  SCHARRE MARK D

IPC: C09K3/00 ,  C10G9/14 ,  C10G9/16

Abstract: The rate of formation of carbon on the surfaces of thermal cracking tubes and the production of carbon monoxide during thermal cracking of hydrocarbons are inhibited by the use of cracking tubes treated with an antifoulant, including tin compound, silicon compound and sulfur compounds in the presence of a reducing gas such as hydrogen. Additionally, the concentration of carbon monoxide in a pyrolytic cracking process product stream is reduced by the treatment of the thermal cracking tubes of such process with a reducing gas having a concentration of a sulfur compound.

公开(公告)号：CA2170425A1

公开(公告)日：1996-09-24

申请号：CA2170425

申请日：1996-02-27

Applicant: PHILLIPS PETROLEUM CO

Inventor： BROWN RONALD E ,  REED LARRY E ,  GREENWOOD GIL J ,  HARPER TIMOTHY P ,  SCHARRE MARK D

IPC: C09K3/00 ,  C10G9/14 ,  C10G9/16 ,  C23F14/02 ,  C07C4/04

Abstract: The rate of formation of carbon on the surfaces of thermal cracking tubes and the production of carbon monoxide during thermal cracking of hydrocarbons are inhibited by the use of cracking tubes treated with an antifoulant, including tin compound, silicon compound and sulfur compounds in the presence of a reducing gas such as hydrogen. Additionally, the concentration of carbon monoxide in a pyrolytic cracking process product stream is reduced by the treatment of the thermal cracking tubes of such process with a reducing gas having a concentration of a sulfur compound.

公开(公告)号：SG32453A1

公开(公告)日：1996-08-13

申请号：SG1995001132

申请日：1995-08-17

Applicant: PHILLIPS PETROLEUM CO

Inventor： REED LARRY E ,  DEGRAFFENRIED JAMES P ,  MURTHA TIMOTHY P ,  BROWN RONALD E ,  GREENWOOD GIL J ,  HARPER TIMOTHY P ,  SCHARRE MARK D

IPC: C10G75/04

公开(公告)号：BR9503786A

公开(公告)日：1996-04-16

申请号：BR9503786

申请日：1995-08-24

Applicant: PHILLIPS PETROLEUM CO

Inventor： REED LARRY E ,  BROWN RONALD E ,  MURTHA TIMOTHY P ,  HARPER TIMOTHY P ,  DEGRAFFENRIED JAMES P ,  SCHARRE MARK D ,  GREENWOOD GIL J

IPC: C01B33/02 ,  C10G9/16 ,  C23C18/12 ,  C23C16/24

Abstract: For a given percentage decomposition, the decomposition temperature of an organosilicon compound is reduced by admixing with the organosilicon compound a decomposition promoting organotin compound. The amount of decomposition promoting organotin compound admixed with the organosilicon compound is sufficient to effectively lower the decomposition temperature of the organosilicon required for a given percentage decomposition.

公开(公告)号：AU2856995A

公开(公告)日：1996-03-07

申请号：AU2856995

申请日：1995-08-17

Applicant: PHILLIPS PETROLEUM CO

Inventor： REED LARRY E ,  BROWN RONALD E ,  DEGRAFFENRIED JAMES P ,  MURTHA TIMOTHY P ,  GREENWOOD GIL J ,  HARPER TIMOTHY P ,  SCHARRE MARK D

IPC: C10G9/20 ,  C10G9/16 ,  C10G9/34 ,  C10G9/40 ,  C10G9/14

Abstract: The energy required to achieve a given conversion in the thermal cracking of hydrocarbons is reduced by contacting or treating the tubes of a thermal cracking furnace with a composition comprising tin and silicon.

公开(公告)号：CA2152336A1

公开(公告)日：1996-02-26

申请号：CA2152336

申请日：1995-06-21

Applicant: PHILLIPS PETROLEUM CO

Inventor： REED LARRY E ,  BROWN RONALD E ,  DEGRAFFENRIED JAMES P ,  MURTHA TIMOTHY P ,  GREENWOOD GIL J ,  HARPER TIMOTHY P ,  SCHARRE MARK D

IPC: C10G9/20 ,  C10G9/16 ,  C10G9/34 ,  C10G9/40 ,  C07C4/04 ,  C10G75/04

Abstract: The energy required to achieve a given conversion in the thermal cracking of hydrocarbons is reduced by contacting or treating the tubes of a thermal cracking furnace with a composition comprising tin and silicon.