公开(公告)号：EP2633008B1

公开(公告)日：2019-03-20

申请号：EP11838497.3

申请日：2011-10-25

Applicant: Stepan Company

Inventor： ALLEN, Dave, R. ,  ALONSO, Marcos ,  BERNHARDT, Randal, J. ,  BROWN, Aaron ,  BUCHEK, Kelly ,  GANGULY-MINK, Sangeeta ,  HOLLAND, Brian ,  MALEC, Andrew, D. ,  MASTERS, Ronald, A. ,  MURPHY, Dennis, S. ,  SKELTON, Patti ,  SOOK, Brian ,  WIESTER, Michael ,  WOLFE, Patrick, Shane

IPC: C07C211/00

公开(公告)号：EP2633022B1

公开(公告)日：2019-01-23

申请号：EP11838507.9

申请日：2011-10-25

Applicant: Stepan Company

Inventor： ALLEN, Dave, R. ,  BERNHARDT, Randal, J. ,  BROWN, Aaron ,  MASTERS, Ronald, A. ,  WOLFE, Patrick, Shane ,  TITIEVSKY, Lena

IPC: C07C211/00 ,  C11D1/28 ,  C11D1/62 ,  C11D1/88 ,  C11D1/92 ,  C11D1/94 ,  C11C3/00 ,  C07C211/21 ,  C07C219/08 ,  C07C237/16 ,  C07C209/12 ,  C07C303/18 ,  A61Q19/10 ,  A61K8/44 ,  A61K8/46 ,  B01F17/00 ,  B01F17/08 ,  C11D1/74 ,  A01N25/02 ,  A01N25/30

公开(公告)号：EP2633022A2

公开(公告)日：2013-09-04

申请号：EP11838507.9

申请日：2011-10-25

Applicant: Stepan Company

Inventor： ALLEN, Dave, R. ,  BERNHARDT, Randal, J. ,  BROWN, Aaron ,  MASTERS, Ronald, A. ,  WOLFE, Patrick, Shane ,  TITIEVSKY, Lena

IPC: C11D10/00

CPC classification number: C11C3/08 ,  A01N25/02 ,  A01N25/04 ,  A01N25/30 ,  A01N33/12 ,  A01N37/18 ,  A01N37/44 ,  A01N41/04 ,  A61K8/416 ,  A61K8/42 ,  A61K8/44 ,  A61K8/466 ,  A61K8/92 ,  A61Q5/12 ,  A61Q19/10 ,  A62D1/0071 ,  B01F17/0028 ,  B01F17/0057 ,  C07C6/04 ,  C07C41/03 ,  C07C43/11 ,  C07C67/26 ,  C07C69/533 ,  C07C69/593 ,  C07C209/12 ,  C07C211/21 ,  C07C219/08 ,  C07C231/12 ,  C07C237/16 ,  C07C303/18 ,  C08G65/2615 ,  C08K5/01 ,  C08K5/20 ,  C09K8/00 ,  C09K15/28 ,  C11C3/00 ,  C11D1/002 ,  C11D1/04 ,  C11D1/28 ,  C11D1/62 ,  C11D1/652 ,  C11D1/74 ,  C11D1/83 ,  C11D1/90 ,  C11D1/92 ,  C11D1/94 ,  C11D3/48 ,  C07C211/63 ,  C07C211/64 ,  C07C233/38 ,  C07C309/14 ,  A01N33/18 ,  A01N39/04 ,  A01N43/653 ,  A01N51/00 ,  A01N57/20 ,  A01N43/40 ,  A01N43/56 ,  A01N53/00

Abstract: Aqueous hard surface cleaner compositions derived from metathesized natural oil feedstocks are disclosed. In one aspect, the compositions comprise at least one anionic surfactant derived from a metathesis-derived C
10 -C
17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives. Particular classes of sulfonated materials (e.g., certain amide sulfonates, sulfonated fatty ester alkoxylates, amidoamine sulfonates, amidoamine betaine sulfonates, sulfo-estolides) are identified as having value as the anionic surfactant. In another aspect, aqueous hard surface cleaners comprising at least one nonionic or amphoteric surfactant derived from a metathesis- derived C
10 -C
17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives are disclosed. Particular classes of these surfactants (e.g., certain amides, imidazoline quat sulfonates, fatty ester alkoxylates, and amine oxides, betaines, amidoamine sulfobetaines) are also identified. The aqueous cleaners noted above rival or outperform commercial baselines in a Gardner straight-line washability test. Industrial degreasers comprising a C
10 or C
12 amide solvent and derived from a metathesis-derived C
10 -C
17 monounsaturated acid are superior to commercial standards.

公开(公告)号：EP2633008A1

公开(公告)日：2013-09-04

申请号：EP11838497.3

申请日：2011-10-25

Applicant: Stepan Company

Inventor： ALLEN, Dave, R. ,  ALONSO, Marcos ,  BERNHARDT, Randal, J. ,  BROWN, Aaron ,  BUCHEK, Kelly ,  GANGULY-MINK, Sangeeta ,  HOLLAND, Brian ,  MALEC, Andrew, D. ,  MASTERS, Ronald, A. ,  MURPHY, Dennis, S. ,  SKELTON, Patti ,  SOOK, Brian ,  WIESTER, Michael ,  WOLFE, Patrick, Shane

IPC: C10L1/18

CPC classification number: C11C3/04 ,  A01N25/02 ,  A01N25/04 ,  A01N25/30 ,  A01N33/12 ,  A01N37/18 ,  A01N37/44 ,  A01N41/04 ,  A61K8/39 ,  A61K8/416 ,  A61K8/42 ,  A61K8/44 ,  A61K8/466 ,  A61K8/86 ,  A61K8/92 ,  A61Q5/12 ,  A61Q17/005 ,  A61Q19/10 ,  A62D1/0071 ,  B01F17/0028 ,  B01F17/0057 ,  C07C6/04 ,  C07C41/03 ,  C07C43/11 ,  C07C67/02 ,  C07C67/26 ,  C07C69/533 ,  C07C69/593 ,  C07C209/12 ,  C07C211/21 ,  C07C219/08 ,  C07C231/12 ,  C07C237/16 ,  C07C303/18 ,  C08G65/2615 ,  C08K5/01 ,  C08K5/20 ,  C09K8/00 ,  C09K15/28 ,  C11C3/00 ,  C11C3/08 ,  C11D1/002 ,  C11D1/04 ,  C11D1/28 ,  C11D1/62 ,  C11D1/652 ,  C11D1/74 ,  C11D1/83 ,  C11D1/90 ,  C11D1/92 ,  C11D1/94 ,  C11D3/48 ,  C07C211/63 ,  C07C211/64 ,  C07C233/38 ,  C07C309/14 ,  A01N33/18 ,  A01N39/04 ,  A01N43/653 ,  A01N51/00 ,  A01N57/20 ,  A01N43/40 ,  A01N43/56 ,  A01N53/00

Abstract: Alkoxylated fatty ester compositions are disclosed. In one aspect, the compositions comprise a reaction product of a metathesis-derived C
10 -C
17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives with one or more alkylene oxides in the presence of an insertion catalyst to give an alkoxylated fatty ester. In another aspect, the metathesis-derived C
10 -C
17 monounsaturated acid, octadecene-1,18-dioic acid, or its ester derivative is reacted with a glycol ether or a glycol ether alkoxylate, to give an alkoxylated fatty ester. In yet another aspect, the metathesis-derived C
10 -C
17 monounsaturated acid or octadecene-1,18-dioic acid is reacted with one or more alkylene oxides to give a fatty acid alkoxylate, followed by etherification of the fatty acid alkoxylate.

公开(公告)号：EP2632271B1

公开(公告)日：2018-12-05

申请号：EP11838510.3

申请日：2011-10-25

Applicant: Stepan Company

Inventor： ALLEN, Dave, R. ,  BERNHARDT, Randal, J. ,  MALEC, Andrew, D. ,  WOLFE, Patrick, Shane

IPC: A01N25/30 ,  A01N57/20 ,  A01P13/00 ,  A01N25/02 ,  A62D1/02 ,  B01F17/00 ,  C07C69/593 ,  C07C231/12 ,  C09K8/00 ,  C07C69/533 ,  C07C303/18 ,  C07C209/12 ,  C11D1/28 ,  C11D1/74 ,  C08G65/26

CPC classification number: C11C3/08 ,  A01N25/02 ,  A01N25/04 ,  A01N25/30 ,  A01N33/12 ,  A01N37/18 ,  A01N37/44 ,  A01N41/04 ,  A61K8/416 ,  A61K8/42 ,  A61K8/44 ,  A61K8/466 ,  A61K8/92 ,  A61Q5/12 ,  A61Q19/10 ,  A62D1/0071 ,  B01F17/0028 ,  B01F17/0057 ,  C07C69/533 ,  C07C69/593 ,  C07C209/12 ,  C07C211/21 ,  C07C219/08 ,  C07C231/12 ,  C07C237/16 ,  C07C303/18 ,  C08G65/2615 ,  C08K5/01 ,  C08K5/20 ,  C09K8/00 ,  C09K15/28 ,  C11C3/00 ,  C11D1/002 ,  C11D1/04 ,  C11D1/28 ,  C11D1/62 ,  C11D1/652 ,  C11D1/74 ,  C11D1/83 ,  C11D1/90 ,  C11D1/92 ,  C11D1/94 ,  C11D3/48 ,  C07C211/63 ,  C07C211/64 ,  C07C233/38 ,  C07C309/14 ,  A01N33/18 ,  A01N39/04 ,  A01N43/653 ,  A01N51/00 ,  A01N57/20 ,  A01N43/40 ,  A01N43/56 ,  A01N53/00

Abstract: Aqueous glyphosate formulations comprising a surfactant derived from metathesized natural oil feedstocks are disclosed. The formulations comprise a glyphosate salt, water, and a surfactant derived from a metathesis-derived C10-C17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives. The surfactant is selected from C10 or C12 amine oxides, C10 or C12 quats, C10, C12, or C16 amidoamines, C10 or C12 amidoamine oxides, C10 imidazoline quats, C10 or C12 amidoamine quats, C10, C12, or C16 betaines, C16 amidoamine betaines, C18 diamidoamines, C18 diamidoamine oxides, C18 diamidoamine diquats, C18 diamidoamine oxide quats, C18 diamidoamine oxide betaines, Cis diamidoamine monobetaines, C18 diamidoamine monobetaine quats, C18 ester amidoamine quats, and amidoamines and their oxidized or quaternized derivatives made from self- or cross-metathesized palm or soybean oil. The surfactants noted above impart substantial stability to highly concentrated glyphosate formulations at, above, and below room temperature and perform as well or better than commercial alternatives.

公开(公告)号：EP3164004A1

公开(公告)日：2017-05-10

申请号：EP15730032.8

申请日：2015-06-09

Applicant: Stepan Company

Inventor： ALLEN, Dave, R. ,  MALEC, Andrew, D.

IPC: A01N25/30 ,  A01P13/00 ,  A01N57/20

Abstract: Agricultural compositions having reduced aquatic toxicity are disclosed. The compositions comprise an agricultural active, a monounsaturated C10-C12 fatty amine ethoxylate, and optionally water. The compositions may further comprise an auxiliary surfactant, a solvent, or both. In certain preferred aspects, the agricultural active is a glyphosate salt. Agricultural compositions comprising a monounsaturated C10-C12 fatty amine ethoxylate have good herbicidal efficacy. Unexpectedly, the monounsaturated C10-C12 fatty amine ethoxylates have reduced aquatic toxicity when compared with their saturated analogs.

Abstract translation: 公开了具有降低的水生毒性的农业组合物。 该组合物包含农用活性成分，单不饱和C10-C12脂肪胺乙氧基化物和任选的水。 该组合物可以进一步包含辅助表面活性剂，溶剂或两者。 在某些优选的方面，农业活性成分是草甘膦盐。 包含单不饱和C10-C12脂肪胺乙氧基化物的农业组合物具有良好的除草效力。 出乎意料的是，与其饱和类似物相比，单不饱和C10-C12脂肪胺乙氧基化物具有降低的水生毒性。

公开(公告)号：EP2632890B8

公开(公告)日：2017-04-12

申请号：EP11838500.4

申请日：2011-10-25

Applicant: Stepan Company

Inventor： ALLEN, Dave, R. ,  ALONSO, Marcos ,  BERNHARDT, Randal, J. ,  BROWN, Aaron ,  BUCHEK, Kelly ,  LUEBKE, Gary ,  LUKA, Renee ,  MALEC, Andrew, D. ,  MASTERS, Ronald, A. ,  MUNIE, Lawrence, A. ,  MURPHY, Dennis, S. ,  SHAPIRO, Irene ,  SKELTON, Patti ,  SOOK, Brian ,  TERRY, Michael, R. ,  WHITLOCK, Laura, Lee ,  WIESTER, Michael ,  WOLFE, Patrick, Shane

IPC: C07C69/533 ,  C07C69/593 ,  C11D1/28 ,  C11D1/74 ,  B01F17/00

CPC classification number: C11D1/66 ,  A01N25/02 ,  A01N25/04 ,  A01N25/30 ,  A01N33/12 ,  A01N37/18 ,  A01N37/44 ,  A01N41/04 ,  A01N57/20 ,  A61K8/41 ,  A61K8/416 ,  A61K8/42 ,  A61K8/44 ,  A61K8/466 ,  A61K8/92 ,  A61Q5/12 ,  A61Q19/10 ,  A62D1/0071 ,  B01F17/0028 ,  B01F17/0057 ,  C04B24/121 ,  C04B24/124 ,  C04B24/16 ,  C04B28/02 ,  C04B28/14 ,  C04B38/10 ,  C07C6/04 ,  C07C41/03 ,  C07C43/11 ,  C07C67/26 ,  C07C69/533 ,  C07C69/593 ,  C07C209/12 ,  C07C211/21 ,  C07C219/08 ,  C07C231/12 ,  C07C237/16 ,  C07C303/18 ,  C07C309/69 ,  C08G65/2615 ,  C08K5/01 ,  C08K5/17 ,  C08K5/20 ,  C08K5/32 ,  C08K5/42 ,  C09D5/00 ,  C09D7/63 ,  C09K8/00 ,  C09K8/54 ,  C09K8/584 ,  C09K15/28 ,  C09K2208/32 ,  C11C3/00 ,  C11C3/08 ,  C11D1/002 ,  C11D1/04 ,  C11D1/28 ,  C11D1/62 ,  C11D1/652 ,  C11D1/74 ,  C11D1/75 ,  C11D1/83 ,  C11D1/90 ,  C11D1/92 ,  C11D1/94 ,  C11D3/48 ,  C07C211/63 ,  C07C211/64 ,  C07C233/38 ,  C07C309/14 ,  A01N33/18 ,  A01N39/04 ,  A01N43/653 ,  A01N51/00 ,  A01N43/40 ,  A01N43/56 ,  A01N53/00 ,  C07C11/02

Abstract: Fatty amine compositions made from a metathesis-derived C10-C17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives are disclosed. In another aspect, fatty amidoamines made by reacting a metathesis-derived C10-C17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives with an aminoalkyl-substituted tertiary amine are disclosed. The fatty amines or amidoamines are advantageously sulfonated, sulfitated, oxidized, or reduced. In other aspects, the ester derivative is a modified triglyceride made by self-metathesis of a natural oil or an unsaturated triglyceride made by cross-metathesis of a natural oil with an olefin.

Abstract translation: 公开了由复分解衍生的C10-C17单不饱和酸，十八碳烯-1,18-二酸或其酯衍生物制成的脂肪胺组合物。 在另一方面，公开了通过使由复分解衍生的C10-C17单不饱和酸，十八碳烯-1,18-二酸或其酯衍生物与氨基烷基取代的叔胺反应制得的脂肪酰氨基胺。 脂肪胺或酰胺胺有利地被磺化，硫酸化，氧化或还原。 在其它方面，酯衍生物是通过天然油或通过天然油与烯烃的交叉复分解制备的不饱和甘油三酯的自分解制备的改性甘油三酯。

公开(公告)号：EP2632890B1

公开(公告)日：2017-01-11

申请号：EP11838500.4

申请日：2011-10-25

Applicant: Stepan Company

Inventor： ALLEN, Dave, R. ,  ALONSO, Marcos ,  BERNHARDT, Randal, J. ,  BROWN, Aaron ,  BUCHEK, Kelly ,  LUEBKE, Gary ,  LUKA, Renee ,  MALEC, Andrew, D. ,  MASTERS, Ronald, A. ,  MUNIE, Lawrence, A. ,  MURPHY, Dennis, S. ,  SHAPIRO, Irene ,  SKELTON, Patti ,  SOOK, Brian ,  TERRY, Michael, R. ,  WHITLOCK, Laura, Lee ,  WIESTER, Michael ,  WOLFE, Patrick, Shane

IPC: C07C69/533 ,  C07C69/593 ,  C11D1/28 ,  C11D1/74 ,  B01F17/00

CPC classification number: C11D1/66 ,  A01N25/02 ,  A01N25/04 ,  A01N25/30 ,  A01N33/12 ,  A01N37/18 ,  A01N37/44 ,  A01N41/04 ,  A01N57/20 ,  A61K8/41 ,  A61K8/416 ,  A61K8/42 ,  A61K8/44 ,  A61K8/466 ,  A61K8/92 ,  A61Q5/12 ,  A61Q19/10 ,  A62D1/0071 ,  B01F17/0028 ,  B01F17/0057 ,  C04B24/121 ,  C04B24/124 ,  C04B24/16 ,  C04B28/02 ,  C04B28/14 ,  C04B38/10 ,  C07C6/04 ,  C07C41/03 ,  C07C43/11 ,  C07C67/26 ,  C07C69/533 ,  C07C69/593 ,  C07C209/12 ,  C07C211/21 ,  C07C219/08 ,  C07C231/12 ,  C07C237/16 ,  C07C303/18 ,  C07C309/69 ,  C08G65/2615 ,  C08K5/01 ,  C08K5/17 ,  C08K5/20 ,  C08K5/32 ,  C08K5/42 ,  C09D5/00 ,  C09D7/63 ,  C09K8/00 ,  C09K8/54 ,  C09K8/584 ,  C09K15/28 ,  C09K2208/32 ,  C11C3/00 ,  C11C3/08 ,  C11D1/002 ,  C11D1/04 ,  C11D1/28 ,  C11D1/62 ,  C11D1/652 ,  C11D1/74 ,  C11D1/75 ,  C11D1/83 ,  C11D1/90 ,  C11D1/92 ,  C11D1/94 ,  C11D3/48 ,  C07C211/63 ,  C07C211/64 ,  C07C233/38 ,  C07C309/14 ,  A01N33/18 ,  A01N39/04 ,  A01N43/653 ,  A01N51/00 ,  A01N43/40 ,  A01N43/56 ,  A01N53/00 ,  C07C11/02

Abstract: Fatty amine compositions made from a metathesis-derived C10-C17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives are disclosed. In another aspect, fatty amidoamines made by reacting a metathesis-derived C10-C17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives with an aminoalkyl-substituted tertiary amine are disclosed. The fatty amines or amidoamines are advantageously sulfonated, sulfitated, oxidized, or reduced. In other aspects, the ester derivative is a modified triglyceride made by self-metathesis of a natural oil or an unsaturated triglyceride made by cross-metathesis of a natural oil with an olefin.

公开(公告)号：EP2633020A1

公开(公告)日：2013-09-04

申请号：EP11838511.1

申请日：2011-10-25

Applicant: Stepan Company

Inventor： ALLEN, Dave, R. ,  ALONSO, Marcos ,  BERNHARDT, Randal, J. ,  MURPHY, Dennis, S. ,  WOLFE, Patrick, Shane ,  BROWN, Aaron

IPC: C11D3/32

CPC classification number: C11D1/92 ,  A01N25/02 ,  A01N25/04 ,  A01N25/30 ,  A01N33/12 ,  A01N37/18 ,  A01N37/44 ,  A01N41/04 ,  A61K8/416 ,  A61K8/42 ,  A61K8/44 ,  A61K8/466 ,  A61K8/92 ,  A61Q5/12 ,  A61Q19/10 ,  A62D1/0071 ,  B01F17/0028 ,  B01F17/0057 ,  C07C69/533 ,  C07C69/593 ,  C07C209/12 ,  C07C211/21 ,  C07C219/08 ,  C07C231/12 ,  C07C237/16 ,  C07C303/18 ,  C08G65/2615 ,  C08K5/01 ,  C08K5/20 ,  C09K8/00 ,  C09K15/28 ,  C11C3/00 ,  C11C3/08 ,  C11D1/002 ,  C11D1/04 ,  C11D1/28 ,  C11D1/29 ,  C11D1/62 ,  C11D1/652 ,  C11D1/72 ,  C11D1/74 ,  C11D1/75 ,  C11D1/83 ,  C11D1/86 ,  C11D1/88 ,  C11D1/90 ,  C11D1/94 ,  C11D3/30 ,  C11D3/32 ,  C11D3/48 ,  C07C211/63 ,  C07C211/64 ,  C07C233/38 ,  C07C309/14 ,  A01N33/18 ,  A01N39/04 ,  A01N43/653 ,  A01N51/00 ,  A01N57/20 ,  A01N43/40 ,  A01N43/56 ,  A01N53/00 ,  C07C209/14

Abstract: Laundry detergents useful for cold-water cleaning and boosted bargain detergents are disclosed. The detergents include a surfactant composition derived from a metathesis-derived C10-C17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives. For fatty alkyl ester sulfonate-containing detergents, the composition is selected from C10 betaines, C12 or C16 amidoamines, C12 ethanolamine amides, C16 amidoamine sulfonates, C18 diamidoamine dioxides, quaternized C18 diamidoamine betaines, sulfonated C18 low-EO fatty ester alkoxylates, C18 amidoamine carboxylates, and amidoamine oxides and sulfobetaines derived from cross-metathesis of palm or soybean oil. The bargain detergents include a performance booster selected from C12 low-EO fatty ester alkoxylate sulfonates, C18 amidoamine oxide esters, C18 amidoamine oxide carboxylates, and amidoamine sulfobetaines made from self metathesized palm or soybean oil.

公开(公告)号：EP2633020B1

公开(公告)日：2019-06-12

申请号：EP11838511.1

申请日：2011-10-25

Applicant: Stepan Company

Inventor： ALLEN, Dave, R. ,  ALONSO, Marcos ,  BERNHARDT, Randal, J. ,  MURPHY, Dennis, S. ,  WOLFE, Patrick, Shane ,  BROWN, Aaron

IPC: C11D3/32