公开(公告)号：EP3242925A2

公开(公告)日：2017-11-15

申请号：EP15830955.9

申请日：2015-12-29

Applicant: Stepan Company

Inventor： HOLLAND, Brian ,  BERNHARDT, Randal ,  SAJIC, Branko

IPC: C11D1/14 ,  C11D1/22 ,  C11D1/29 ,  C11D1/34 ,  C11D1/62 ,  C11D1/72 ,  C11D1/75 ,  C11D1/825 ,  C11D1/90 ,  C11D1/92 ,  C11D1/83 ,  C11D3/386 ,  C11D11/00

CPC classification number: C11D1/37 ,  C11D1/143 ,  C11D1/146 ,  C11D1/22 ,  C11D1/29 ,  C11D1/345 ,  C11D1/62 ,  C11D1/72 ,  C11D1/75 ,  C11D1/83 ,  C11D1/90 ,  C11D1/92 ,  C11D3/38627 ,  C11D11/0017

Abstract: Laundry detergents and their use for cold-water cleaning are disclosed. The detergents comprise a lipase and a mid-chain headgroup surfactant or an alkylene-bridged surfactant. The mid-chain headgroup surfactants have a C14-C30 alkyl chain and a polar group bonded to a central zone carbon of the C14-C30 alkyl chain. The alkylene-bridged surfactants comprise a C12-C18 alkyl chain, a polar group, and a C1-C2 alkylene group bonded to the polar group and a central zone carbon of the C12-C18 alkyl chain. Surprisingly, when combined with lipases, detergents formulated with the mid-chain headgroup or alkylene-bridged surfactants effectively liquefy greasy soils at low temperature and provide outstanding cold-water performance in removing greasy stains such as bacon grease, butter, cooked beef fat, or beef tallow from soiled articles.

公开(公告)号：EP2632256A1

公开(公告)日：2013-09-04

申请号：EP11838499.9

申请日：2011-10-25

Applicant: Stepan Company

Inventor： ALLEN, Dave R. ,  ALONSO, Marcos ,  BERNHARDT, Randal J. ,  BROWN, Aaron ,  BUCHEK, Kelly ,  GANGULY-MINK, Sangeeta ,  HOLLAND, Brian ,  LUEBKE, Gary ,  LUKA, Renee ,  MALEC, Andrew D. ,  MASTERS, Ronald A. ,  MURPHY, Dennis S. ,  SHAPIRO, Irene ,  SKELTON, Patti ,  SOOK, Brian ,  TERRY, Michael R. ,  WALLACE, Gregory ,  WHITLOCK, Laura Lee ,  WIESTER, Michael ,  WOLFE, Patrick, Shane ,  TITIEVSKY, Lena

IPC: A01N37/00 ,  A61K31/20

CPC classification number: C07C233/09 ,  A01N25/02 ,  A01N25/04 ,  A01N25/30 ,  A01N33/12 ,  A01N37/18 ,  A01N37/44 ,  A01N41/04 ,  A61K8/416 ,  A61K8/42 ,  A61K8/44 ,  A61K8/466 ,  A61K8/92 ,  A61Q5/02 ,  A61Q5/12 ,  A61Q17/005 ,  A61Q19/10 ,  A62D1/0071 ,  B01F17/0028 ,  B01F17/0057 ,  C07C69/533 ,  C07C69/593 ,  C07C209/12 ,  C07C211/21 ,  C07C219/08 ,  C07C231/12 ,  C07C233/20 ,  C07C233/38 ,  C07C237/16 ,  C07C303/18 ,  C07C309/15 ,  C07C309/70 ,  C07D233/24 ,  C08G65/2615 ,  C08K5/01 ,  C08K5/20 ,  C08K5/42 ,  C09D7/45 ,  C09D7/63 ,  C09K8/00 ,  C09K8/524 ,  C09K8/54 ,  C09K15/28 ,  C11C3/00 ,  C11C3/08 ,  C11D1/002 ,  C11D1/04 ,  C11D1/28 ,  C11D1/62 ,  C11D1/652 ,  C11D1/66 ,  C11D1/74 ,  C11D1/83 ,  C11D1/90 ,  C11D1/92 ,  C11D1/94 ,  C11D3/48 ,  C11D11/0017 ,  C07C211/63 ,  C07C211/64 ,  C07C309/14 ,  A01N33/18 ,  A01N39/04 ,  A01N43/653 ,  A01N51/00 ,  A01N57/20 ,  A01N43/40 ,  A01N43/56 ,  A01N53/00

Abstract: Fatty amide compositions and their derivatives are disclosed. The fatty amides comprise a reaction product of a metathesis-derived C10-C17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives with a primary or secondary amine. Derivatives made by reducing, quaternizing, sulfonating, alkoxylating, sulfating, and sulfitating the fatty amide are also included. The amine reactant can be diethylenetriamine or (2-aminoethyl)ethanolamine, which provide imidazoline amides or esters, respectively. In one aspect, the ester derivative of the C10-C17 monounsaturated acid or octadecene-1,18-dioic acid is a lower alkyl ester. In other aspects, the ester derivative is a modified triglyceride made by self-metathesis of a natural oil or an unsaturated triglyceride made by cross-metathesis of a natural oil with an olefin. The compositions are valuable for cleaners, fabric treatment, hair conditioning, personal care, antimicrobial compositions, agricultural uses, and oil field applications.

Abstract translation: 公开了脂肪酰胺组合物及其衍生物。 脂肪酰胺包含由复分解衍生的C10-C17单不饱和酸，十八碳烯-1,18-二酸或其酯衍生物与伯胺或仲胺的反应产物。 还包括通过还原，季铵化，磺化，烷氧基化，硫酸化和硫酸化而制得的衍生物。 胺反应物可以是二亚乙基三胺或（2-氨基乙基）乙醇胺，其分别提供咪唑啉酰胺或酯。 一方面，C10-C17单不饱和酸或十八碳烯-1,18-二酸的酯衍生物是低级烷基酯。 在其它方面，酯衍生物是通过天然油或通过天然油与烯烃的交叉复分解制备的不饱和甘油三酯的自分解制备的改性甘油三酯。 组合物对于清洁剂，织物处理，头发调理，个人护理，抗微生物组合物，农业用途和油田应用是有价值的。

公开(公告)号：EP3152286B1

公开(公告)日：2020-01-22

申请号：EP15730027.8

申请日：2015-06-08

Applicant: Stepan Company

Inventor： HOLLAND, Brian ,  BERNHARDT, Randal, J. ,  SAJIC, Branko ,  TABOR, Rick

IPC: C11D1/14 ,  C11D1/22 ,  C11D1/29 ,  C11D1/34 ,  C11D1/62 ,  C11D1/72 ,  C11D1/75 ,  C11D1/825 ,  C11D1/90 ,  C11D1/92 ,  C11D1/83

公开(公告)号：EP3152286A2

公开(公告)日：2017-04-12

申请号：EP15730027.8

申请日：2015-06-08

Applicant: Stepan Company

Inventor： HOLLAND, Brian ,  BERNHARDT, Randal, J. ,  SAJIC, Branko ,  TABOR, Rick

IPC: C11D1/14 ,  C11D1/22 ,  C11D1/29 ,  C11D1/34 ,  C11D1/62 ,  C11D1/72 ,  C11D1/75 ,  C11D1/825 ,  C11D1/90 ,  C11D1/92 ,  C11D1/83

Abstract: Detergents useful for cold-water cleaning and mid-chain headgroup and alkylene-bridged surfactants useful therein are disclosed. The mid-chain headgroup surfactant has a C14-C30 alkyl chain and a polar group bonded to a central zone carbon of the alkyl chain. The alkylene-bridged surfactant has a C12-C18 alkyl chain, a polar group, and a C1-C2 alkylene group bonded to the polar group and a central zone carbon of the C12-C18 alkyl chain. Preferred surfactants in these classes are alcohol sulfates, alcohol ethoxylates, ether sulfates, sulfonates, arylsulfonates, alcohol phosphates, amine oxides, quaterniums, betaines, and sulfobetaines. Surprisingly, detergents formulated with the surfactants provide outstanding cold-water performance in removing greasy stains such as bacon grease, butter, cooked beef fat, or beef tallow from soiled articles.

Abstract translation: 公开了可用于冷水清洗的洗涤剂和可用于其中的中链头团和亚烷基桥接表面活性剂。 中链头团表面活性剂具有C 14 -C 30烷基链和与烷基链的中心区碳键合的极性基团。 亚烷基桥连表面活性剂具有C12-C18烷基链，极性基团和与极性基团键合的C1-C2亚烷基和C12-C18烷基链的中心区碳。 这些类别中优选的表面活性剂是醇硫酸盐，醇乙氧基化物，醚硫酸盐，磺酸盐，芳基磺酸盐，醇磷酸盐，氧化胺，季铵盐，甜菜碱和磺基甜菜碱。 令人惊讶的是，用表面活性剂配制的洗涤剂提供出色的冷水性能，从去污的物品中除去培养油脂，黄油，熟牛肉或牛脂等油污。

公开(公告)号：EP2633008B1

公开(公告)日：2019-03-20

申请号：EP11838497.3

申请日：2011-10-25

Applicant: Stepan Company

Inventor： ALLEN, Dave, R. ,  ALONSO, Marcos ,  BERNHARDT, Randal, J. ,  BROWN, Aaron ,  BUCHEK, Kelly ,  GANGULY-MINK, Sangeeta ,  HOLLAND, Brian ,  MALEC, Andrew, D. ,  MASTERS, Ronald, A. ,  MURPHY, Dennis, S. ,  SKELTON, Patti ,  SOOK, Brian ,  WIESTER, Michael ,  WOLFE, Patrick, Shane

IPC: C07C211/00

公开(公告)号：EP2633008A1

公开(公告)日：2013-09-04

申请号：EP11838497.3

申请日：2011-10-25

Applicant: Stepan Company

Inventor： ALLEN, Dave, R. ,  ALONSO, Marcos ,  BERNHARDT, Randal, J. ,  BROWN, Aaron ,  BUCHEK, Kelly ,  GANGULY-MINK, Sangeeta ,  HOLLAND, Brian ,  MALEC, Andrew, D. ,  MASTERS, Ronald, A. ,  MURPHY, Dennis, S. ,  SKELTON, Patti ,  SOOK, Brian ,  WIESTER, Michael ,  WOLFE, Patrick, Shane

IPC: C10L1/18

CPC classification number: C11C3/04 ,  A01N25/02 ,  A01N25/04 ,  A01N25/30 ,  A01N33/12 ,  A01N37/18 ,  A01N37/44 ,  A01N41/04 ,  A61K8/39 ,  A61K8/416 ,  A61K8/42 ,  A61K8/44 ,  A61K8/466 ,  A61K8/86 ,  A61K8/92 ,  A61Q5/12 ,  A61Q17/005 ,  A61Q19/10 ,  A62D1/0071 ,  B01F17/0028 ,  B01F17/0057 ,  C07C6/04 ,  C07C41/03 ,  C07C43/11 ,  C07C67/02 ,  C07C67/26 ,  C07C69/533 ,  C07C69/593 ,  C07C209/12 ,  C07C211/21 ,  C07C219/08 ,  C07C231/12 ,  C07C237/16 ,  C07C303/18 ,  C08G65/2615 ,  C08K5/01 ,  C08K5/20 ,  C09K8/00 ,  C09K15/28 ,  C11C3/00 ,  C11C3/08 ,  C11D1/002 ,  C11D1/04 ,  C11D1/28 ,  C11D1/62 ,  C11D1/652 ,  C11D1/74 ,  C11D1/83 ,  C11D1/90 ,  C11D1/92 ,  C11D1/94 ,  C11D3/48 ,  C07C211/63 ,  C07C211/64 ,  C07C233/38 ,  C07C309/14 ,  A01N33/18 ,  A01N39/04 ,  A01N43/653 ,  A01N51/00 ,  A01N57/20 ,  A01N43/40 ,  A01N43/56 ,  A01N53/00

Abstract: Alkoxylated fatty ester compositions are disclosed. In one aspect, the compositions comprise a reaction product of a metathesis-derived C
10 -C
17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives with one or more alkylene oxides in the presence of an insertion catalyst to give an alkoxylated fatty ester. In another aspect, the metathesis-derived C
10 -C
17 monounsaturated acid, octadecene-1,18-dioic acid, or its ester derivative is reacted with a glycol ether or a glycol ether alkoxylate, to give an alkoxylated fatty ester. In yet another aspect, the metathesis-derived C
10 -C
17 monounsaturated acid or octadecene-1,18-dioic acid is reacted with one or more alkylene oxides to give a fatty acid alkoxylate, followed by etherification of the fatty acid alkoxylate.

公开(公告)号：EP2632893A1

公开(公告)日：2013-09-04

申请号：EP11838498.1

申请日：2011-10-25

Applicant: Stepan Company

Inventor： ALLEN, Dave R. ,  BERNHARDT, Randal J. ,  BROWN, Aaron ,  DAMESHEK, Anatoliy A. ,  HOLLAND, Brian ,  MALEC, Andrew, D. ,  MASTERS, Ronald, A. ,  NEPRAS, Marshall, J. ,  SKELTON, Patti ,  WHITLOCK, Laura Lee ,  WOLFE, Patrick Shane

IPC: C07C229/00

CPC classification number: C07C219/08 ,  A01N25/02 ,  A01N25/04 ,  A01N25/30 ,  A01N33/12 ,  A01N37/18 ,  A01N37/44 ,  A01N41/04 ,  A61K8/416 ,  A61K8/42 ,  A61K8/44 ,  A61K8/466 ,  A61K8/92 ,  A61K8/922 ,  A61K2800/805 ,  A61Q5/02 ,  A61Q5/12 ,  A61Q19/10 ,  A62D1/0071 ,  B01F17/0028 ,  B01F17/0057 ,  C07C6/04 ,  C07C41/03 ,  C07C43/11 ,  C07C67/26 ,  C07C69/533 ,  C07C69/593 ,  C07C209/12 ,  C07C211/21 ,  C07C231/12 ,  C07C237/16 ,  C07C237/18 ,  C07C303/18 ,  C08G65/2615 ,  C08K5/01 ,  C08K5/20 ,  C09K8/00 ,  C09K15/28 ,  C11C3/00 ,  C11C3/08 ,  C11D1/002 ,  C11D1/04 ,  C11D1/28 ,  C11D1/62 ,  C11D1/652 ,  C11D1/74 ,  C11D1/83 ,  C11D1/90 ,  C11D1/92 ,  C11D1/94 ,  C11D3/48 ,  C07C211/63 ,  C07C211/64 ,  C07C233/38 ,  C07C309/14 ,  A01N33/18 ,  A01N39/04 ,  A01N43/653 ,  A01N51/00 ,  A01N57/20 ,  A01N43/40 ,  A01N43/56 ,  A01N53/00

Abstract: Esteramine compositions and their derivatives are disclosed. The esteramines comprise a reaction product of a metathesis-derived C
10 -C
17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives with a tertiary alkanolamine. Derivatives made by quaternizing, sulfonating, alkoxylating, sulfating, and/or sulfitating the esteramines are also disclosed. In one aspect, the ester derivative of the C
10 -C
17 monounsaturated acid or octadecene-1,18-dioic acid is a lower alkyl ester. In other aspects, the ester derivative is a modified triglyceride made by self-metathesis of a natural oil or an unsaturated triglyceride made by cross-metathesis of a natural oil with an olefin. The esteramines and derivatives are valuable for a wide variety of end uses, including cleaners, fabric treatment, hair conditioning, personal care (liquid cleansing products, conditioning bars, oral care products), antimicrobial compositions, agricultural uses, and oil field applications.