Pervaporation process for separating a lower alcohol compound from a mixture of a lower alcohol compound and an ether compound

    公开(公告)号:GB2242429A

    公开(公告)日:1991-10-02

    申请号:GB9106535

    申请日:1991-03-27

    Applicant: UBE INDUSTRIES

    Abstract: A C1-4 alcohol is separated from a mixture of a C1-4 alcohol and an ether by a pervaporation method comprising the steps of: bringing a feed comprising an ether compound and a C1-4 alcohol compound into direct contact with a feed face of a specific asymmetric separating membrane comprising an aromatic imide polymer which preferably has 70 to 100 molar% of recurring units selected from those of the formulae (I) and (II> wherein R = divalent aromatic group having two or more benzene rings and X = -S-, -SO2-, -CO-, -O-, -C(CH3)2-, -CH2- and -C(CF3)2-; exposing a delivery face opposite to the feed face of the membrane to a pressure-reduced atmosphere to cause the C1-4 alcohol compound to selectively permeate through the membrane and to be then vaporized at the delivery face side, and collecting the C1-4 alcohol compound at the delivery face side of the membrane.

    Water-repellent breathable cover and transducer with water-repellent breathable cover
    16.
    发明专利
    Water-repellent breathable cover and transducer with water-repellent breathable cover 审中-公开
    防水防水罩和透水罩

    公开(公告)号:JP2011004097A

    公开(公告)日:2011-01-06

    申请号:JP2009144729

    申请日:2009-06-17

    Abstract: PROBLEM TO BE SOLVED: To provide a protection cover which is available in a transducer of a microphone, a speaker or the like and is superior in breathability and waterproofness.SOLUTION: A polyimide porous film includes an aromatic polyimide obtained from: a tetracarboxylic acid component containing a component selected from biphenyl tetracarboxylic acid components and pyromellitic acid components; and an aromatic diamine compound containing an aromatic diamine selected from among benzene diamine components, diamino diphenyl ether components, and bis(amino phenoxy) phenyl components.

    Abstract translation: 要解决的问题:提供一种在麦克风,扬声器等的换能器中可用的保护罩,并且具有优异的透气性和防水性。解决方案:聚酰亚胺多孔膜包括芳族聚酰亚胺,其由四羧酸组分 含有选自联苯四羧酸组分和均苯四酸酸组分的组分; 和含有选自苯二胺组分,二氨基二苯醚组分和双(氨基苯氧基)苯基组分的芳族二胺的芳族二胺化合物。

    METHOD FOR PRODUCING (1R,1'S,3R,3'S,4S,4'R)-DICYCLOHEXYL-3,3',4,4'- TETRACARBOXYDIIMIDE DERIVATIVE

    公开(公告)号:JP2002088064A

    公开(公告)日:2002-03-27

    申请号:JP2000281417

    申请日:2000-09-18

    Applicant: UBE INDUSTRIES

    Abstract: PROBLEM TO BE SOLVED: To obtain a novel (1R,1'S,3R,3'S,4S,4'R)-dicyclohexyl-3,3',4,41- tetracarboxydiimide derivative capable of being suitably used as a monomer or the like for producing a high polymer having a dicyclohexyl isomer structure and useful as a model compound for analyzing the structure, physical characteristics, functionality and the like of a high polymer and the like having the aforesaid isomer. SOLUTION: This method for producing a (1R,1'S,3R,3'S,4S,4'R)- dicyclohexyl-3,3',4,4'-tetracarboxydiimide derivative is to react a (1R,1'S,3R,3'S,4 S,4'R)-dicyclohexyl-3,3',4,4'-tetracarboxylic dianhydride with a monoamino compound in a solvent and subsequently and/or simultaneously bring the amido acid to an imide derivative thermally and/or chemically.

    SEPARATION OF LOWER ALCOHOL
    19.
    发明专利

    公开(公告)号:JPH0416213A

    公开(公告)日:1992-01-21

    申请号:JP11688590

    申请日:1990-05-08

    Applicant: UBE INDUSTRIES

    Abstract: PURPOSE:To permeate a lower alcohol selectively and separate it from vapor of a mixture containing the lower alcohol such as ethanol and an organic compound by using a gas separating membrane of a heat-resistant polymer having a specific gas diffusible function. CONSTITUTION:A gas separation membrane to be used is a gas separation membrane of a heat-resistant polymer having 2.0-400 separation degree at 25 deg.C [the ratio of diffusing speed of helium gas to that of sulfur hexafluoride gas (PHe/PSF6)] and permeation speed of methanol at 80 deg.C (PCH3OH) of at least 1.0X10 cm /cm .sec.cmHg. Vapor of a mixture containing 1-2C lower alcohol (including methanol, etc.) and an organic compound is brought into contact with one side (a supplying side) of the gas separation membrane at 60 deg.C and the lower alcohol is selectively permeated to the other side (a permeating side) of the gas separation membrane, so that a lower alcohol such as methanol, etc., is separated.

    SEPARATION OF LOWER ALCOHOL
    20.
    发明专利

    公开(公告)号:JPH03284334A

    公开(公告)日:1991-12-16

    申请号:JP8299590

    申请日:1990-03-31

    Applicant: UBE INDUSTRIES

    Abstract: PURPOSE:To effectively separate lower alcohol as vapor from a liq. mixture of the alcohol with an org. ether by bringing the mixture into direct contact with one side of a heat resistant asymmetric separating membrane of an arom. polyamide. CONSTITUTION:A liq. org. compd. mixture of 1-4C lower alcohol with an org. ether is fed into a separating membrane module and brought into direct contact with an asymmetric separating membrane of an arom. polyamide built in the module. The permeation side of the membrane is kept under reduced pressure as required and the lower alcohol is allowed to selectively permeate the membrane, vaporized and separated. The highly concd. org. ether is finally taken out and recovered from the feed side of the membrane and vapor contg. a highly concd. lower alcohol from the permeation side. By this method, the lower alcohol is industrially and stably separated and recovered over a long time.

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