DISTRIBUTION OF ELECTROLYTES IN A FLOW BATTERY
    13.
    发明公开
    DISTRIBUTION OF ELECTROLYTES IN A FLOW BATTERY 有权
    VERTEILUNG VON ELEKTROLYTEN IN EINER FLUSSBATTERIE

    公开(公告)号:EP3087628A4

    公开(公告)日:2017-09-13

    申请号:EP13900022

    申请日:2013-12-23

    Abstract: A method of determining a distribution of electrolytes in a flow battery includes providing a flow battery with a fixed amount of fluid electrolyte having a common electrochemically active specie, a portion of the fluid electrolyte serving as an anolyte and a remainder of the fluid electrolyte serving as a catholyte. An average oxidation state of the common electrochemically active specie is determined in the anolyte and the catholyte and, responsive to the determined average oxidation state, a molar ratio of the common electrochemically active specie between the anolyte and the catholyte is adjusted to increase an energy discharge capacity of the flow battery for the determined average oxidation state.

    Abstract translation: 确定液流电池中电解质分布的方法包括:为液流电池提供固定量的具有共同的电化学活性物质的液体电解质,一部分液体电解质用作阳极电解液,并且液体电解质的剩余部分用作 阴极电解液。 在阳极电解液和阴极电解液中确定普通电化学活性物质的平均氧化态,并且响应于确定的平均氧化态,调节阳极电解液和阴极电解液之间的普通电化学活性物质的摩尔比以增加能量放电 用于确定的平均氧化态的液流电池的容量。

    REGENERATION OF FLOW BATTERY ELECTRODE
    14.
    发明公开
    REGENERATION OF FLOW BATTERY ELECTRODE 审中-公开
    REGENERIERUNG EINER FLUSSBATTERIEELEKTRODE

    公开(公告)号:EP3195393A4

    公开(公告)日:2017-07-26

    申请号:EP14902061

    申请日:2014-09-15

    Abstract: A method is disclosed for regenerating an electrode of a flow battery. The method can be executed during shutdown of the flow battery from an active charge/discharge mode to an inactive, shut-down mode in which neither a negative electrolyte nor a positive electrolyte are circulated through at least one cell of the flow battery. The method includes driving voltage of the least one cell of the flow battery toward zero by converting, in-situ, the negative electrolyte in the at least one cell to a higher oxidation state. The negative electrolyte is in contact with an electrode of the at least one cell. The higher oxidation state negative electrolyte is used to regenerate, in-situ, catalytically active surfaces of the electrode of the at least one cell.

    Abstract translation: 公开了一种用于再生液流电池的电极的方法。 该方法可以在液流电池从有源充电/放电模式关闭到关闭不活动模式期间执行,其中负电解液和正电解液都不流过液流电池的至少一个电池。 该方法包括通过原位将至少一个电池中的负电解质转化为更高的氧化态来将液流电池的至少一个电池单元的电压驱动到零。 负电解质与至少一个电池的电极接触。 较高氧化态的负电解质用于原位再生至少一个电池的电极的催化活性表面。

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