processo para a produção de olefinas, e, processo para a produção de propileno

    公开(公告)号:BR112012024185A2

    公开(公告)日:2016-07-05

    申请号:BR112012024185

    申请日:2011-03-28

    Applicant: UOP LLC

    Abstract: processo para a produção de olefinas, e, processo para a produção de propileno. processos para a conversão, sob condições e com um sistema de catalilsador eficaz para a metáfase de olefinas, de cargas de alimentação de hidrocarbonetos compreendendo uma olefina acíclica simétrica (por exemplo, buteno-2) são descritos. produtos olefínicos de números de carbono menores e maiores (por exempo, propileno e penteno) são formados na presença de um catalisador compreendendo um suporte sólido e um hidreto de tungstênio ligado a uma alumina presente no suporte. isto ocorre apesar do mecanismo de reação de metátese de olefina levar a um resultado degenerativo, sem qualquer produção esperada de produtos de números de carbono diferentes a partir de olefinas acíclicas simétricas.

    AROMATIC TRANSALKYLATION USING UZM-44 ALUMINOSILICATE ZEOLITE

    公开(公告)号:SG11201502366UA

    公开(公告)日:2015-04-29

    申请号:SG11201502366U

    申请日:2013-12-06

    Applicant: UOP LLC

    Abstract: A new family of aluminosilicate zeolites designated UZM-44 has been synthesized. These zeolites are represented by the empirical formula. NanMmk+TtAl1-xExSiyOz where M represents a metal or metals from zine, Group 1, Group 2, Group 3 and or the lanthanide series of the periodic table, “m” is the mole ratio of M to (Al+E), T is the organic structure directing agent or agents, and E is a framework element such as gallium. UZM-44 may be used to catalyze a process for the transalkylation of a feedstream comprising one or more of C7, C9, C10 and C11+ aromatics to obtain a transalkylation product stream having an increased concentration of C8 aromatics relative to that of the feedstream.

    ZEOLITA DE ALUMINOSILICATO UZM-39.
    14.
    发明专利

    公开(公告)号:MX2014007632A

    公开(公告)日:2014-10-01

    申请号:MX2014007632

    申请日:2012-12-13

    Applicant: UOP LLC

    Abstract: La presente invención se refiere a la síntesis de una nueva familia de materiales compuestos coherentemente formados de zeotipos TUN y IMP. Estas zeolitas están representadas por la fórmula empírica NanMmk+TtAl1-xExSiyOz, donde "n" es la proporción molar de Na contra (A1 + E), M representa un metal o metales de entre zinc, del Grupo 1, del Grupo 2, del Grupo 3 y/o la serie de lantánidos de la tabla periódica, "m" es la proporción molar de M contra (A1 + E), "k" es la carga media del metal o metales M, T es el agente o agentes directores de estructura orgánicos, y E es un elemento de estructura como galio. Estas zeolitas son similares a TNU-9 e IM-5, pero se caracterizan por composiciones y procedimientos de síntesis únicos en su tipo, y poseen propiedades catalíticas para realizar diversos procesos de conversión de hidrocarburos, y propiedades de separación para realizar diversas separaciones.

    AROMATIC TRANSFORMATION USING UZM-39 ALUMINOSILICATE ZEOLITE

    公开(公告)号:CA2858726A1

    公开(公告)日:2013-06-27

    申请号:CA2858726

    申请日:2012-12-13

    Applicant: UOP LLC

    Abstract: A new family of coherently grown composites of TUN and IMF zeotypes has been synthesized and shown to be effective catalysts for aromatic transformation reactions. These zeolites are represented by the empirical formula. NanMm k+TtA11-xExSiyOz where "n" is the mole ratio of Na to (Al + E), M represents at least one metal, "m" is the mole ratio of M to (Al + E), "k" is the average charge of the metal or metals M, T is the organic structure directing agent or agents, "t" is the mole ratio of N from the organic structure directing agent or agents to (Al + E), and E is a framework element such as gallium. The process involves contacting at least a first aromatic with the coherently grown composites of TUN and IMF zeotypes to produce at least a second aromatic.

    ORGANO-1-OXA-4-AZONIUM CYCLOHEXANE COMPOUNDS
    17.
    发明申请
    ORGANO-1-OXA-4-AZONIUM CYCLOHEXANE COMPOUNDS 审中-公开
    有机基-1-氧杂-4-氮杂环戊烷化合物

    公开(公告)号:WO2016089758A3

    公开(公告)日:2016-09-01

    申请号:PCT/US2015062971

    申请日:2015-11-30

    Applicant: UOP LLC

    CPC classification number: C07D295/037 C07D295/023 C07D295/027

    Abstract: Novel 1-oxa-4-azonium cyclohexane salts are described. These compounds can be used as structure directing agents, and they overcome many of the typical problems associated with OSDA synthesis and subsequent zeolite synthesis. Methods for synthesis of the 1-oxa-4-azonium cyclohexane salts from a variety of starting materials are also described. A substituted hydrocarbon is added to water to form a mixture, and a 1-oxa-4-azacyclohexane derivative is then added. The reaction mixture stirred until a solution containing the 1-oxa-4-azonium cyclohexane salt is obtained.

    Abstract translation: 描述了新的1-氧杂-4-氮杂环己烷盐。 这些化合物可以用作结构导向剂,并且它们克服了许多与OSDA合成和随后的沸石合成相关的典型问题。 还描述了由各种原料合成1-氧杂-4-氮杂环己烷盐的方法。 将取代的烃加入水中形成混合物,然后加入1-氧杂-4-氮杂环己烷衍生物。 搅拌反应混合物直至得到含有1-氧杂-4-氮环己烷盐的溶液。

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