Apparatus and methods for application of coatings with supercritical fluids as diluents by spraying from an orifice
    192.
    发明公开
    Apparatus and methods for application of coatings with supercritical fluids as diluents by spraying from an orifice 失效
    装置和使用超临界流体作为稀释剂从小孔通过Zustäuben施加涂层材料的方法。

    公开(公告)号:EP0476705A2

    公开(公告)日:1992-03-25

    申请号:EP91116068.7

    申请日:1991-09-20

    CPC classification number: B05D1/025 B01F5/0619 B05B1/306 B05B7/168 B05D2401/90

    Abstract: This invention is directed to improved spraying apparatus for coating substrates with a coating material and supercritical fluid which apparatus is provided with various features, either alone or in combination, to prevent undesirable premature cooling of the coating mixture which might detrimentally affect the final coating on the substrate; to prevent undesirable depressurization of supercritical fluid contained in the coating mixture which remains in the spray gun after spraying has been stopped; and/or to desirably provide the ability to mix the components of the coating mixture directly in the spray gun. Methods for utilizing these features in the spraying apparatus of the present invention are also disclosed.

    Abstract translation: 本发明涉及改善的喷射装置用于与该设备被提供有各种特征的涂层材料和超临界流体涂覆基材,无论是单独或组合,以防止涂层混合物的不期望的过早冷却可能不利地影响在最终涂料 基板; 为了防止包含在涂层混合物,其保持在喷雾已经停止之后喷枪超临界流体的不期望的减压; 和/或优选提供直接在喷枪的涂布混合物的各组分混合的能力。 对于在本发明的喷射装置利用合成器功能方法因此游离缺失盘。

    Process for the preparation of random copolymers
    193.
    发明公开
    Process for the preparation of random copolymers 失效
    制备无规共聚物的方法

    公开(公告)号:EP0426139A3

    公开(公告)日:1992-03-25

    申请号:EP90120846.2

    申请日:1990-10-30

    Abstract: A process for the copolymerization of a mixture of monomers comprising propylene and 1-butene which comprises contacting the monomers and hydrogen in the gas phase in a single stage reaction zone, under polymerization conditions, with a catalyst system comprising (i) a solid catalyst precursor, which includes magnesium; titanium; a halogen which is chlorine, bromine, or iodine, or a mixture thereof; and a polycarboxylic acid ester containing two coplanar ester groups attached to adjacent carbon atoms; (ii) a hydrocarbyl aluminum cocatalyst; and (iii) a silicon compound containing at least one silicon-oxygen-carbon group, a temperature of from about 50°C to about 90°C, wherein:
    (a) the atomic ratio of aluminum to titanium is in the range of about 10 to about 300; (b) the molar ratio of aluminum to silicon compound is in the range of about 0.5 to about 10; (c) the propylene partial pressure is in the range of about 50 to about 450 psi; (d) the 1-butene partial pressure is in the range of about 10 to about 50 psi; (e) the hydrogen partial pressure is in the range of about 0.1 psi to about 80 psi; (f) the superficial gas velocity is in the range of about 1 to about 3 feet per second; and (g) the molar ratio of 1-butene to propylene is in the range of about 0.01:1 to about 0.4:1.

    Abstract translation: 一种使包含丙烯和1-丁烯的单体混合物共聚的方法,该方法包括在聚合条件下在单级反应区中使单体和氢在气相中与催化剂体系接触,所述催化剂体系包含(i)固体催化剂前体 ,其中包括镁; 钛; 卤素,其是氯,溴或碘,或其混合物; 和含有两个与相邻碳原子连接的共平面酯基的多元羧酸酯; (ii)烃基铝助催化剂; 和(iii)含有至少一个硅 - 氧 - 碳基团的硅化合物,其温度为约50℃至约90℃,其中:(a)铝与钛的原子比在约 10至约300; (b)铝与硅化合物的摩尔比在约0.5至约10的范围内; (c)丙烯分压在约50至约450psi的范围内; (d)1-丁烯分压在约10至约50psi的范围内; (e)氢分压在约0.1psi至约80psi的范围内; (f)表观气体速度在约1至约3英尺每秒的范围内; 和(g)1-丁烯与丙烯的摩尔比在约0.01:1至约0.4:1的范围内。

    Catalysts and processes useful in producing 1,3-diols and/or 3-hydroxyaldehydes
    198.
    发明公开
    Catalysts and processes useful in producing 1,3-diols and/or 3-hydroxyaldehydes 失效
    催化剂和方法,用于生产1,3-二醇和/或3-羟基醛。

    公开(公告)号:EP0455261A1

    公开(公告)日:1991-11-06

    申请号:EP91107226.2

    申请日:1991-05-03

    Abstract: A process for producing a 1,3-diol, e.g., 1,3-propanediol, and/or a 3-hydroxyaldehyde, e.g., 3-hydroxypropionaldehyde is disclosed which comprises contacting a combination of an epoxide, carbon monoxide and hydrogen in the presence of a rhodium-containing catalyst composition effective to promote the hydroformylation of the epoxide at conditions effective to form at least one of a 1,3-diol and a 3-hydroxyaldehyde. The rhodium-containing catalyst composition comprises an anionic rhodium-containing complex. A promoter component is preferably provided to enhance at least one of the rate and selectivity of the epoxide hydroformylation reaction. Rhodium-containing compositions and a processes for producing rhodium-containing compositions are also disclosed.

    Abstract translation: 一种制备1,3-二醇,例如,1,3-丙二醇,和/或3-羟基醛,例如过程,3-羟基丙醛是游离缺失盘其包括使在存在环氧化物,一氧化碳和氢气的组合 的含铑催化剂组合物可有效促进环氧化物的羰基化在有效形成1,3-二醇中的至少一种和3-羟基醛的条件。 含铑催化剂组合物包括含铑阴离子配合物。 包括助催化剂成分优选地设置,以提高环氧化物羰基化反应的速率和选择性中的至少一种。 因此组合物和方法用于生产含铑组合物的含铑是游离缺失盘。

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