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    OO-t-alkyl O-polycaprolactone monoperoxycarbonates
    204.
    发明公开
    OO-t-alkyl O-polycaprolactone monoperoxycarbonates 失效
    OO叔烷基-O-Polycaprolakton-单过碳酸酯。

    公开(公告)号：EP0606096A1

    公开(公告)日：1994-07-13

    申请号：EP94100205.7

    申请日：1994-01-07

    Applicant: ELF ATOCHEM NORTH AMERICA, INC.

    Inventor： Macleay, Ronald E. ,  Kmiec, Jennifer P. ,  Kazmierczak, Robert T.

    IPC: C08G63/91 ,  C08F293/00

    CPC classification number: C08F293/00

    Abstract: Polycaprolactones are capped with OO-t-alkylperoxy carbonate groups useful in the preparation of polycaprolactone block and graft copolymers, processes for their preparation and use and intermediates suitable for use in said processes as well as the use of said copolymers as compatibilizing agents for blends of immiscible polymers are provided.
    The peroxy terminated poly(e-caprolactones) are of formula I:

            (A-X-) m -R-(-X'-B) n    I


    wherein:
       A is

       B is

       m is an integer of 0 to 3,
       n is an integer of 1 to 4
       and m + n is an integer of 1 to 4;
       R¹, R² and R³ can be, e.g., methyl,
       y is an integer and may vary from 0 to 10,000,
       x is an integer and may vary from 4 to 22,000,
       and (y)(m) + (x)(n) is an integer and may vary from 4 to 22,000;
       X and X'can be, e.g., -O- and
       R can be, e.g., an unsubstituted aliphatic radical.

    Abstract translation: 式（A-X）m-R-（X'-B）n（I）的过氧端基聚（ε-己内酯）是新的。 A = H-（O-（CH 2）5 -C（O））y - ; B =（i）; m = 0-3; n = 1-4; （m + n）= 1-4; R1，R2 = 1-4C烷基; R3 = 1-12C烷基或2-12C炔属; y = 0-10000; x = 4-22000; （y）（m）+（x）（n）= 4-22000; X，X'= -O-或-N（R 4） - ; R =选择 substd。 脂族，脂环族，芳族或芳脂族（二，三或四）基; 当n + m = 1时，R = opt。 substd。 选自1-20C脂肪族，5-18C脂环族，6-14C芳族，7-22C芳族脂族和（非）芳族5-12C杂环; 当n + m = 2时，R = opt。 substd。 选自2-20C脂族，4-20C脂族基，被1-3个-O-，-S-或-N（R4）-gps间隔的二价基团。 在链中，条件是多个杂原子是sepd。 彼此之间并且双基链末端至少为2C，5-18C脂环族，6-12C芳族化合物，其中R是具有2个自由价的烃和芳族碳环单元，和7-22C芳脂族; 当n + m = 3时，R = opt。 substd。 选自3-20C脂族，5-18C脂环族，6-14C芳族和7-22C芳脂肪族; 当n + m = 4时，R = opt。 substd。 四价选自4-20C脂族，6-18C脂环族，6-14C芳族和7-22C芳脂肪族; R4 = H或opt。 substd。 1-20C脂肪族，5-18C脂环族，6-14C芳族或7-22C芳脂肪族; 和替代品。 对于R和R 4 = Cl，Br，1-8C烷基，1-12C烷氧基，6-10C芳氧基和/或氰基，以及另外的取代基。 R = 1-4C酰氧基和/或（甲基）丙烯酰氧基。

    Partial esters of epoxy containing compounds and related halogen containing polymer compositions
    209.
    发明公开
    Partial esters of epoxy containing compounds and related halogen containing polymer compositions 失效
    Teilveresterte epoxidierte Verbindungen und entsprechende，Halogen enthaltende Polymerzusammensetzungen。

    公开(公告)号：EP0553400A1

    公开(公告)日：1993-08-04

    申请号：EP92117472.8

    申请日：1992-10-13

    Applicant: ELF ATOCHEM NORTH AMERICA, INC.

    Inventor： Hirshman, Justin Leonard ,  Garcia, Dana Sorina ,  Kazemizadeh, Mohammad Reza

    IPC: C08K5/10 ,  C08K5/15

    CPC classification number: C08K5/1515 ,  C08L57/08

    Abstract: The present invention relates to a partial ester derived from the reaction product of an oxirane containing acid or derivative thereof, and a reactive hydroxyl compound selected from the group consisting of diols, triols, di-diols and 1,4-dihydroxy butane and a halogen containing polymer compositon thereof. The oxirane compound can be derived from the group consisting of epoxidized vegetable oil, epoxidized fish oil, an aliphatic or arylaliphatic containing craboxyl compound having an oxirane group in the aliphatic chain.

    Abstract translation: 本发明涉及衍生自含有环氧乙烷的酸或其衍生物的反应产物的偏酯，以及选自二醇，三醇，二醇和1,4-二羟基丁烷的反应性羟基化合物和卤素 其聚合物组合物。 环氧乙烷化合物可以衍生自环氧化植物油，环氧化鱼油，脂族链中具有环氧乙烷基团的脂族或芳基脂族含有的异戊二烯基化合物。

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