Abstract:
The present invention relates to compounds of the general formula (I) and to the salts thereof, wherein the substituents and the n index have the following values: Q represents -C(=CHCH3)-COOCH3, -C(=CHOCH3)-COOCH3, -C(=NOCH3)-COOCH3 or -C(=NOCH3)-CONH(CH3); R represents hydrogen, halogen, C1-C4 alkyl, C1-C2 halogenalkyl, C1-C4 alkoxy or C1-C2 halogenalkoxy; R represents halogen, C1-C4 alkyl, C1-C2 halogenalkyl or C1-C4 alkoxy; n is 0, 1 or 2, wherein the R substituents can be different when n = 2; and R represents phenyl, pyridyle or pyrimidyle. This invention also relates to agents containing these compounds as well as to the use of said compounds (I) and agents against noxious fungi and animal parasites.
Abstract translation:通式(I)和它们的盐,其中取代基和指数n具有以下含义的化合物:Q是-C(= CHCH 3)-COOCH 3,-C(= CHOCH 3)-COOCH 3,C(= NOCH 3) - COOCH 3或-C(= NOCH 3)-CONH(CH 3); R 1是氢,卤素,C 1 -C 4烷基,C 1 -C 2卤代烷基,C 1 -C 4烷氧基或C 1 -C 2卤代烷氧基; R 2是卤素,C 1 -C 4烷基,C 1 -C 2卤代烷基,C 1 -C 4烷氧基; n是0,1或2,其中当n = 2时取代基R 2可以不同; R 3苯基,吡啶基或嘧啶基,含有它们的试剂以及化合物(I)和防治有害真菌和动物害虫的试剂的用途。
Abstract:
The invention concerns diphenylethers of formula (I) and their salts and N-oxides, the substituents and indices in the formula having the following meanings: Q is C(CO2CH3)=CHCH3, C(CO2CH3)=CHOCH3, C(CONH2)=CHOCH3, C(CO2CH3)=NOCH3, C(CONHCH3)=NOCH3 or N(OCH3)-CO2CH3; n is 0 or 1; R is hydrogen or an organic group bonded via a carbon atom; R is hydrogen, cyano, halogen or an organic group bonded via a carbon, oxygen, sulphur or nitrogen atom; or, if n stands for 1, an organic group bonded via a carbon atom; x is 0, 1 or 2; R is cyano, nitro, halogen, or an organic group bonded via a carbon, oxygen, sulphur or nitrogen atom; y is 0, 1, 2 or 3; and R is cyano, halogen, C1-C4 alkyl, C1-C4 alkyl halide or C1-C4 alkoxy. The invention further concerns a process and intermediate products for preparing these substance, and their use.
Abstract:
The invention concerns phenylcarbamates of formula (I) in which the substituents and the index have the following meanings: R = cyano, nitro, trifluoromethyl, halogen, alkyl or alkoxy; m = 0, 1 or 2; R = alkyl, alkenyl, alkinyl, cycloalkyl or cycloalkenyl and, if X stands for NR , additionally hydrogen; X is a direct bond, O or NR ; R = hydrogen, alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkenyl; R = hydrogen, optionally substituted alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkenyl, cycloalkinyl, alkylcarbonyl or alkoxycarbonyl; R and R , independently of each other, stand for hydrogen, cyano, nitro, hydroxy, amino, halogen, optionally substituted alkyl, alkoxy, alkylthio, alkylamino, dialkylamino, alkenyl, alkenyloxy, alkenylthio, alkenylamino, N-alkenyl-N-alkylamino, alkinyl, alkinyloxy, alkinylthio, alkinylamino, N-alkinyl-N-alkylamino, cycloalkyl, cycloalkyloxy, cycloalkylthio, cycloalkylamino, N-cycloalkyl-N-alkylamino, cycloalkenyl, cycloalkenyloxy, cycloalkenylthio, cycloalkenylamino, N-cycloalkenyl-N-alkylamino, heterocyclyl, heterocyclyloxy, heterocyclylthio, heterocyclylamino, N-heterocyclyl-N-alkylamino, aryl, aryloxy, arylthio, arylamino, N-aryl-N-alkylamino, hetaryl, hetaryloxy, hetarylthio, hetarylamino or N-heteraryl-N-alkylamino; and R is one of the groups mentioned under R or a CR =NOR group. The invention further concerns processes and intermediate products for preparing these substances and their use as pesticides and fungicides.
Abstract:
Compounds of general formula (I), in which R is C(CO2CH3)=CHOCH3, C(CO2CH3)=NOCH3, N(OCH3)CO2CH3 and C(CONHCH3)=NOCH3; R is cyano, halogen, C1-C4 alkyl and C1-C4 alkoxy; m is 0 or 1; R is cyano, halogen, C1-C4 alkyl, C1-C4 alkyl halide and C1-C4 alkoxy; n is 0, 1, 2 or 3, where the constituents R may be different if n is 2 or 3; R is hydrogen, C1-C4 alkyl, C1-C4 alkyl halide, C3-C6 cycloalkyl and phenyl; X, Y are C1-C6 alkoxy, C1-C6 alkylthio, C1-C6 alkyl amino, di-C1-C6 alkyl amino or a C1-C4 alkylene chain which is bonded to the C atom directly or via an oxygen, sulphur and/or nitrogen atom and may bear one or two of the constituents oxo (=O), cyano, C1-C4 alkyl, C3-C6 cycloalkyl, C1-C4 alkoxy carbonyl, aryl and heteroaryl; process for their production and their use as pesticide or fungicide.
Abstract:
The disclosure concerns oxyamino oxime ethers of formula (I), wherein: X is NOCH3, CHOCH3, CHCH3; Y is O or NZ, Z being H or alkyl; R is H or alkyl; R is cyano, nitro, trifluoromethyl, halogen, alkyl or alkoxy, m = 0, 1 or 2 and the groups R can be different if m = 2; R is H, alkyl, alkyl halide or cycloalkyl; R is H or optionally substituted alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkenyl, heterocyclyl, aryl, heteroaryl; R is H or alkylsulphonyl, or optionally substituted alkyl, alkenyl, alkinyl, cycloalkyl; and their salts. Also disclosed are methods and intermediate products for use in producing them and their use for controlling harmful fungi and insect pests.
Abstract translation:式Oxyaminooximether(I)(X = NOCH 3,CHOCH 3,CHCH 3; Y = O,NZ,其中Z = H,烷基; R <1> = H,烷基; R <2>是氰基,硝基,三氟甲基,卤素, 烷基,烷氧基,m为0,1,2,其中基团R <2>可以是不同的,当m = 2; R <3> = H,烷基,卤代烷基,环烷基; R <4> = H,任选 SUBST:烷基,烯基,炔基,环烷基,环烯基,杂环基,芳基,杂芳基; R <5> = H,烷基磺酰基,未取代或取代的:烷基,烯基,炔基,环烷基),和它们的盐,方法和中间体。 其制备方法及其在防治有害真菌和有害昆虫的用途。
Abstract:
The invention concerns phenylacetic acid derivatives of formula (I) in which the substituents and the indices have the following meanings: X denotes NOCH3, CHOCH3 and CHCH3; Y denotes oxygen or NR ; R denotes hydrogen or alkyl; R denotes cyano, nitro, trifluoromethyl, halogen, alkyl and alkoxy; m stands for 0, 1 or 2, wherein the rests R can be different if m is 2; R denotes hydrogen or alkyl; R and R , independently of each other, denote hydrogen, cyano, nitro, hydroxy, amino, halogen, optionally substituted alkyl, alkoxy, alkylthio, alkylamino, dialkylamino, alkenyl, alkenyloxy, alkenylthio, alkenylamino, N-alkenyl-N-alkylamino, alkinyl, alkinyloxy, alkinylthio, alkinylamino, N-alkinyl-N-alkylamino, cycloalkyl, cycloalkyloxy, cycloalkylthio, cycloalkylamino, N-cycloalkyl-N-alkylamino, cycloalkenyl, cycloalkenyloxy, cycloalkenylthio, cycloalkenylamino, N-cycloalkenyl-N-alkylamino, heterocyclyl, heterocyclyloxy, heterocyclylthio, heterocyclylamino, N-heterocyclyl-N-alkylamino, aryl, aryloxy, arylthio, arylamino, N-aryl-N-alkylamino, hetaryl, hetaryloxy, hetarylthio, hetarylamino and N-hetaryl-N-alkylamino; R denotes one of the groups mentioned in the case of R or a CR =NOR group; R denotes one of the groups mentioned in the case of R ; and R denotes hydrogen, optionally substituted alkyl, cycloalkyl, alkenyl, alkinyl, alkylcarbonyl, alkenylcarbonyl, alkinylcarbonyl, alkylsulphonyl, aryl, arylcarbonyl, arylsulphonyl, hetaryl, hetarylcarbonyl or hetarylsulphonyl. The invention also concerns their salts, a process for the preparation of these substances and their use.
Abstract:
A process for preparing substantially isomer-pure E-2-(2-aryloxymethylene phenyl)-crotonic acid methyl esters having formula (Ia), in which R stands for an aromatic residue substitued by the usual groups and R' stands for a C1-C3 alkyl group, is characterised in that a corresponding 2-(2-aryloxymethylene phenyl)- alpha -keto-acetic acid methyl ester having formula (II) with an alkyl metal compound having formula (III), in which M stands for a metal ion equivalent, first yields the corresponding 2-(2-aryloxymethylene phenyl)- alpha -hydroxybutyric acid methyl ester having formula (IV), which is then dehydrated in the presence of an acid into a mixture of E- et Z-2-(2-aryloxymethylene phenyl)-crotonic acid methyl esters having formulas (Ia) and (Ib). This mixture is finally converted into the substantially isomer-pure E-2-(2-aryloxymethylene phenyl)-crotonic acid methyl ester (Ia) in the presence of a base in an inert polar solvent.
Abstract:
Phenyl acetic acid derivatives of formula (I) in which the substituents and index have the following meanings: X is oxygen or sulphur; R is hydrogen and alkyl; R is hydrogen and alkyl; R is cyano, nitro, trifluoromethyl, halogen, alkyl and alkoxy; m is 0, 1 ou 2, in which the radicals R may be different if m is 2; R is hydrogen, cyano, nitro, hydroxy, amino, halogen, alkyl, halogen alkyl, alkoxy, halogen alkoxy, alkylthio, alkylamino or dialkylamino; R is hydrogen, cyano, nitro, hydroxy, amino, halogen, possibly substituted alkyl, alkoxy, alkylthio, alkylamino, dialkylamino, alkenyl, alkenyloxy, alkenylthio, alkenylamino, N-alkenyl-N-alkylamino, alkinyl, alkinyloxy, alkinylthio, alkinylamino, N-alkinyl-N-alkylamino; optionally substituted cycloalkyl, cycloalkyloxy, cycloalkylthio, cycloalkylamino, N-cycloalkyl-N-alkylamino, cycloalkenyl, cycloalkenyloxy, cycloalkenylthio, cycloalkenylamino, N-cycloalkenyl-N-alkylamino, heterocyclyl, heterocyclyloxy, heterocyclylthio, heterocyclylamino, N-heterocylcyl-N-alkylamino, aryl, aryloxy, arylthio, arylamino, n-aryl-n-alkylamino, hetaryl, hetaryloxy, hetarylthio, hetarylamino, N-hetaryl-N-alkylamino; R is hydrogen, optionally substituted alkyl, cycloalkyl, alkenyl, alkinyl, alkylcarbonyl, alkenylcarbonyl, alkinylcarbonyl or alkylsulfonyl; optionally substituted aryl, arylcarbonyl, arylsulfonyl, hetaryl, hetarylcarbonyl or hetarylsulphonyl; and their salts, process and intermediate products for their production, and their use.
Abstract:
The present invention relates to substituted 1-{2-cyclyloxy-2-[2-halo-4-(4-halogen-phenoxy)-phenyl]-ethyl}-1H-[1,2,4]triazole compounds of formula I as defined in the description, and the N-oxides, and salts thereof, processes and intermediates for preparing these compounds and also to compositions comprising at least one such compound. The invention also relates to the use of such compounds and compositions for combating harmful fungi and seed coated with at least one such compound.