Abstract:
Multi-layered golf balls containing a dual-core structure are provided. The core structure includes an inner core (center) comprising a thermoplastic composition, preferably including: a) ethylene acid copolymer, b) plasticizer, and c) cation source. Preferably, a fatty acid ester such as ethyl oleate is used as the plasticizer. The outer core layer is preferably formed from a thermoset composition such as polybutadiene rubber. The core layers have different hardness levels. For example, the inner core can have a positive, zero, or negative hardness gradient. The core assembly preferably has a positive hardness gradient extending across the entire assembly. The core structure and resulting ball have relatively good resiliency at given compressions.
Abstract:
The present invention is directed to multi-layer golf balls including a layer formed from a relatively soft or low modulus HNP composition and a layer formed from a relatively hard or high modulus HNP composition. Optionally, the soft (or low modulus) HNP composition and/or the hard (or high modulus) HNP composition is plasticized or is replaced with a different plasticized acid copolymer composition.
Abstract:
Golf ball comprising at least one layer LS comprising material LM formed from a polymeric composition and a plurality of liquid droplets that are formed throughout the polymeric composition by combining the polymeric composition and a liquid that is immiscible in the polymeric composition. The polymeric composition has a modulus MS1 and material LM has a modulus MS2 wherein (MS2/MS1)>1. The polymeric composition may comprise at least one polyurethane, polyurea, ionomer, polyamide, polyester, polyolefin, and/or silicone. The liquid may be, for example, at least one of ionic liquids, alcohols, glycols, glycerol, silicone oils, hydrocarbon oils, or liquid fatty acids. Liquid droplet diameter may be up to about 100 nm or up to about 100 μm, and a droplet may be spherical or aspherical, and sometimes be oblate or prolate. An aspherical droplet may be ovoid or ellipsoid. MS2 may be from about 1,000-80,000 psi.; or 70,000-500,000 psi or greater.
Abstract:
A golf ball including an inner core having a first outer surface and a geometric center and being formed from a first substantially homogenous composition such that the inner core has a hardness of about 60 Shore C to about 90 Shore C; an outer core layer disposed about the inner core having a second outer surface and being formed from a second substantially homogenous composition such that the outer core layer has a hardness of about 60 Shore C to about 95 Shore C; and a cover layer disposed about the outer core layer. The geometric center and first and second outer surfaces each have a hardness, the hardness of the second outer surface being lower than the hardness of the geometric center to define a negative hardness gradient.
Abstract:
A golf ball comprising a core and a cover layer, wherein at least one of the core or cover layer comprises a plasticized polyurethane composition comprising at least one polyurethane and at least one plasticizer.
Abstract:
Multi-layered golf balls containing a dual-core structure are provided. The core structure includes an inner core (center) comprising a foam composition, preferably foamed polyurethane. The outer core layer is preferably formed from a non-foamed composition selected from thermoset compositions and thermoplastic compositions. The core layers have different hardness and specific gravity levels. The specific gravity (density) of the foam inner core is preferably less than the density of the outer core layer.
Abstract:
Multi-piece golf balls having a solid core of at least one layer and cover of at least one layer are provided. At least one of the layers is formed from a thermoplastic polyamide composition, comprising a blend of polyamide, ethylene acid copolymer ionomer, fatty acid amide, and plasticizer. A polyamide having a transparent optical nature is preferably used in the composition. A fatty acid ester such as dipropylene glycol dibenzoate and propylene carbonate is preferably used as the plasticizer. The ball may contain an inner core and surrounding outer core layer. A rubber composition is preferably used to form the inner core and the polyamide-based composition is preferably used to form the outer core layer.
Abstract:
Golf ball incorporating an HNP composition consisting of a mixture of: at least one ethylene acid copolymer; sufficient amount of cation source to neutralize greater than about 100% of all acid groups present; and a highly diverse mixture of at least four organic acids having different characteristics such as relating to: carbon chain lengths, number of double bonds on carbon chains, positioning of double bonds on carbon chains, number of branches, types of branches, positioning of branches on carbon chains, positioning of acid groups on carbon chains, configurations(cis/trans), functional groups on carbon chains, being saturated/unsaturated, being conjugated/non-conjugated; presence/absence of functional group(s) on carbon chain; being aliphatic/aromatic, or combinations thereof. No organic acid is present in highly diverse mixture in a concentration greater than 80%, or, in some embodiments, greater than 60%, or greater than 40%. HNP composition may be relatively soft/relatively low modulus, relatively hard/relatively high modulus, or blends thereof.
Abstract:
The present invention is directed to golf balls consisting of a multi-layer core and a cover. The multi-layer core includes at least one layer formed from a relatively soft or low modulus HNP composition and at least one layer formed from a relatively hard or high modulus HNP composition.
Abstract:
Multi-piece golf balls having a solid core of at least one layer and cover of at least one layer are provided. At least one of the layers is formed from a thermoplastic polyamide composition, comprising a blend of about 40 to about 99% by weight polyamide and about 1 to about 60% by weight fatty acid amide. Preferably, the ball has a dual core construction. A rubber composition is preferably used to form the outer core layer and the polyamide composition is preferably used to form the inner core. The flex modulus of the polyamide composition is preferably at least 15% greater than the flex modulus of the rubber composition.