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    High-solids thermoset binders formed using hyperbranched polyols as reactive intermediates, coating compositions formed therewith, and methods of making and using same
    202.
    发明申请
    High-solids thermoset binders formed using hyperbranched polyols as reactive intermediates, coating compositions formed therewith, and methods of making and using same 有权
    使用超支化多元醇作为反应性中间体形成的高固体热固性粘合剂，由其形成的涂料组合物，以及制备和使用它们的方法

    公开(公告)号：US20020026015A1

    公开(公告)日：2002-02-28

    申请号：US09952732

    申请日：2001-09-14

    Inventor： Swaminathan Ramesh

    IPC: C08F020/00

    CPC classification number: C08G83/005 ,  C08G63/123 ,  C08G63/60 ,  C08G63/91 ,  C09D167/00 ,  C09D201/005 ,  Y10S977/754 ,  C08L2666/36 ,  C08L61/04

    Abstract: A binder for a coating composition is formed using a principal resin polyol, in combination with a hyper-branched polyol as a reactive intermediate, and at least one crosslinker. The principal resin polyol is at least one of a polyester polyol, a polyether polyol, and a polyacrylate. Hyper-branched polyester polyols may be used as reactive diluents, which will cross-link with isocyanates, isocyanurates, epoxides, anhydrides or their corresponding polyacids and/or aminoplasts to form a binder having particular properties, to help control the rheology of a coating system. The hyperbranched polyol, the principal resin polyol, or both may, optionally, include a carbamate functional group in the structure thereof. Coating compositions may be made using the binders together with additional components.

    Abstract translation: 使用主要树脂多元醇与作为反应性中间体的超支化多元醇和至少一种交联剂组合形成涂料组合物用粘合剂。 主要树脂多元醇是聚酯多元醇，聚醚多元醇和聚丙烯酸酯中的至少一种。 超支化聚酯多元醇可用作反应性稀释剂，其将与异氰酸酯，异氰脲酸酯，环氧化物，酸酐或其相应的多酸和/或氨基塑料交联以形成具有特定性质的粘合剂，以帮助控制涂料体系的流变性 。 超支化多元醇，主要树脂多元醇或两者可以任选地包括其结构中的氨基甲酸酯官能团。 涂料组合物可以使用粘合剂和附加组分一起制备。

    Vinyl-group-containing dendrimer and curable composition
    204.
    发明授权
    Vinyl-group-containing dendrimer and curable composition 失效
    含乙烯基的树枝状聚合物和可固化组合物

    公开(公告)号：US06187897B1

    公开(公告)日：2001-02-13

    申请号：US09121868

    申请日：1998-07-24

    Applicant: Miki Kawashima ,  Minoru Nakamura ,  Hiroaki Tanaka

    Inventor： Miki Kawashima ,  Minoru Nakamura ,  Hiroaki Tanaka

    IPC: C08G6300

    CPC classification number: C08G83/003 ,  C08G18/3278 ,  C08G18/8116 ,  C08G18/8175 ,  C08L101/005 ,  C09D201/005 ,  Y10S424/16

    Abstract: A vinyl-group-containing dendrimer useful in coating and printing and is curable by any one of conventional triggers such as heating, ultraviolet light, infrared light, electron beams and &ggr; rays, the composition comprising a vinyl-group-containing dendrimer (A) comprising a core portion, branching portions, branches and at least 4 terminal portions and having a vinyl group as a terminal portion and a long-chain group and a curable unsaturated-group-containing compound (B), and the composition comprising a vinyl-group-containing dendrimer (A) obtained by reacting a polyfunctional compound (a) having at least three active-hydrogen-containing groups in a terminal per molecule and having at least five active hydrogen atoms per molecule with a long-chain-group-containing compound (b) having a functional group reactive with an active hydrogen atom so as to leave part of the active hydrogen atoms, thereby obtaining a long-chain-group-containing multi-branched compound (X), and reacting the long-chain-containing multi-branched compound (X) with a vinyl-group-containing compound (c) having a functional group reactive with an active hydrogen atom and a curable unsaturated-group-containing compound (B).

    Abstract translation: 可用于涂布和印刷的含乙烯基的树枝状聚合物并且可通过任何常规触发剂如加热，紫外光，红外光，电子束和γ射线固化，所述组合物包含含乙烯基的树枝状聚合物（A） 包含芯部分，支链部分，分支和至少4个末端部分，并且具有乙烯基作为末端部分，长链基团和含固化不饱和基团的化合物（B），并且所述组合物包含乙烯基 - 通过使具有至少三个含有活性氢的基团的多官能化合物（a）在每个分子的末端与每个分子具有至少五个活性氢原子的长链基团反应获得的含基团的树枝状大分子（A） 具有与活性氢原子反应的官能团的化合物（b），以留下部分活性氢原子，从而得到含有长链基团的多支化化合物（X），并使 具有含活性氢原子的具有官能团的含乙烯基的化合物（c）的长链多支化合物（X）和含有可固化不饱和基团的化合物（B）。

    Dendritic macomolecule and a process for the preparation thereof
    207.
    发明授权
    Dendritic macomolecule and a process for the preparation thereof 失效
    树枝状大分子及其制备方法

    公开(公告)号：US5698662A

    公开(公告)日：1997-12-16

    申请号：US686948

    申请日：1996-07-26

    Applicant: Christiaan J. C. Stoelwinder ,  Ellen M. M. de Brabander-van den Berg ,  Atze J. Nijenhuis

    Inventor： Christiaan J. C. Stoelwinder ,  Ellen M. M. de Brabander-van den Berg ,  Atze J. Nijenhuis

    IPC: C08G73/00 ,  C08G73/02 ,  C08G73/06 ,  C08G83/00 ,  C08L101/00 ,  C09D201/00 ,  C08G63/44

    CPC classification number: C08G83/003 ,  C08G73/0213 ,  C08G73/065 ,  C08L101/005 ,  C09D201/005

    Abstract: The invention relates to a dendritic macromolecule with branches prepared from halogen cyanide units composed of a monohalogenated hydrocarbon compound comprising 3-50 carbon atoms and at least one cyanide group, the halogen and the cyanide group being separated from one another by at least 3 carbon atoms. The invention also relates to a process for the preparation of a dendritic macromolecule, comprising a core and at least one branch emanating from the core, characterized in that the process comprises the steps a) through c): a) substantially every functional group of the core molecule is reacted with monomeric halogen cyanide units b) substantially every incorporated cyanide group is reduced to an amine c) substantially every amine group is reacted with monomeric halogen cyanide units, steps b) and c) being conducted alternately.

    Abstract translation: 本发明涉及一种具有由卤素氰化物单元制备的分枝的树枝状高分子，所述卤素氰化物单元由包含3-50个碳原子和至少一个氰化物基团的单卤代烃化合物组成，所述卤素和所述氰化物基彼此分开至少3个碳原子 。 本发明还涉及一种制备树突状高分子的方法，该方法包括核心和从核心发出的至少一个分支，其特征在于该方法包括步骤a）至c）：a）基本上每个功能基团 核心分子与单体卤素氰化物单元反应b）基本上每个引入的氰基都被还原成胺c）基本上每个胺基与单体卤素氰化物单元反应，步骤b）和c）交替进行。

    Bridged dense star polymers
    209.
    发明授权
    Bridged dense star polymers 失效
    桥接致密星状聚合物

    公开(公告)号：US4737550A

    公开(公告)日：1988-04-12

    申请号：US938686

    申请日：1986-12-08

    Applicant: Donald A. Tomalia

    Inventor： Donald A. Tomalia

    IPC: A61K47/48 ,  B01D17/04 ,  C08G69/44 ,  C08G69/48 ,  C08G73/02 ,  C08G83/00 ,  C09D7/00 ,  C09D201/00 ,  C10G33/04

    CPC classification number: C08G83/003 ,  A61K47/48192 ,  A61K47/482 ,  A61K47/48207 ,  B01D17/047 ,  C08G69/44 ,  C08G69/48 ,  C08G73/028 ,  C09D201/005 ,  C09D7/002 ,  C10G33/04 ,  C08L101/005

    Abstract: Bridged dense star polymers having terminal group densities greater than conventional extended star polymers exhibit greater and more uniform reactivity than their corresponding conventional star polymers. For example, a third generation, hydroxy-terminated polyether dense star polymer can be prepared from pentaerythrityltetrabromide and 4-hydroxymethyl-2,6,7-trioxabicyclo[2.2.2]-octane which has a molecular volume less than 80 percent of the volume of a conventional extended star polymer made from similar materials. This dense star polymer can then be bridged by reacting it with a suitable difunctional reactant such as toluene diisocyanate. Such polymers of dense star polymers are useful as demulsifiers for oil/water emulsions, wet strength agents in the manufacture of paper, proton scavengers, calibration standards for electron microscopy, and agents for modifying viscosity in aqueous formulations such as paints.

    Abstract translation: 具有大于常规延伸的星形聚合物的端基密度的桥连稠密星形聚合物表现出比其相应的常规星形聚合物更大且更均匀的反应性。 例如，第三代羟基封端的聚醚致密星形聚合物可以由季戊四醇四溴化物和4-羟甲基-2,6,7-三氧杂双环[2.2.2] - 辛烷制备，其分子量小于体积的80％ 由类似材料制成的常规的扩展星形聚合物。 然后可以通过使其与合适的二官能反应物如甲苯二异氰酸酯反应来将该致密的星形聚合物桥连。 致密星形聚合物的这种聚合物可用作油/水乳液的破乳剂，纸张制造中的湿强剂，质子清除剂，电子显微镜的校准标准品和用于改进水性配方如油漆中的粘度的试剂。

    Dense star polymer
    210.
    发明授权
    Dense star polymer 失效
    密集聚合物

    公开(公告)号：US4558120A

    公开(公告)日：1985-12-10

    申请号：US565686

    申请日：1983-12-27

    Applicant: Donald A. Tomalia ,  James R. Dewald

    Inventor： Donald A. Tomalia ,  James R. Dewald

    IPC: A61K47/48 ,  B01D17/04 ,  C08G69/44 ,  C08G69/48 ,  C08G73/02 ,  C08G83/00 ,  C09D7/00 ,  C09D201/00 ,  C10G33/04 ,  C08G69/00

    CPC classification number: C08G83/003 ,  A61K47/48192 ,  A61K47/482 ,  A61K47/48207 ,  B01D17/047 ,  C08G69/44 ,  C08G69/48 ,  C08G73/028 ,  C09D201/005 ,  C09D7/002 ,  C10G33/04 ,  C08L101/005 ,  Y10S424/16

    Abstract: Dense star polymers having terminal group densities greater than conventional star polymers exhibit greater and more uniform reactivity than their corresponding conventional star polymers. For example, a third generation, amine-terminated polyamidoamine dense star polymer prepared from ammonia, methyl acrylate and ethylenediamine has 1.24.times.10.sup.-4 amine moieties per unit volume (cubic Angstrom units) in contrast to the 1.58.times.10.sup.-6 amine moieties per unit volume contained by a conventional star polymer. Such dense star polymers are useful as demulsifiers for oil/water emulsions, wet strength agents in the manufacture of paper, and agents for modifying viscosity in aqueous formulations such as paints.

    Abstract translation: 具有大于常规星形聚合物的端基密度的密集聚合物表现出比其相应的常规星形聚合物更大且更均匀的反应性。 例如，由氨，丙烯酸甲酯和乙二胺制备的第三代胺封端的聚酰胺胺致密星形聚合物与每单位体积的1.58x10-6胺部分相比，每单位体积（立方单位）具有1.24×10-4胺部分 由常规的星形聚合物包含。 这种致密的星形聚合物可用作油/水乳液的破乳剂，纸张制造中的湿强力剂和用于改进水性配方如油漆中的粘度的试剂。

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