Abstract:
An object of the present invention is to provide a sulfide solid electrolyte glass producing a tiny amount of hydrogen sulfide. The present invention attains the above-mentioned object by providing a sulfide solid electrolyte glass including Li3PS4, characterized in that Li4P2S7 is not detected by 31P NMR measurement and the content of Li2S as determined by XPS measurement is 3% by mol or less.
Abstract translation:本发明的目的是提供一种产生微量硫化氢的硫化物固体电解质玻璃。 本发明通过提供一种含有Li 3 PO 4的硫化物固体电解质玻璃来实现上述目的,其特征在于,通过31P NMR测量未检测到Li 4 P 2 S 7,并且通过XPS测量测定的Li 2 S含量为3摩尔%以下。
Abstract:
Optical devices and a method for manufacturing these devices. One optical device includes a core region having a first medium of a first refractive index n1, and includes a cladding region exterior to the core region. The cladding region includes a second medium having a second refractive index n2 higher than the first refractive index n1. The cladding region further includes a third medium having a third refractive index n3 lower than the first refractive index n1. The third medium is dispersed in the second medium to form a plurality of microstructures in the cladding region. Another optical device includes a plurality of core regions including at least one core having a doped first medium, and includes a cladding region exterior to the plurality of core regions. The core regions and the cladding region include a phosphate glass.
Abstract:
The present invention is generally directed to a method of making chalcogenide glasses including holding the melt in a vertical furnace to promote homogenization and mixing; slow cooling the melt at less than 10° C. per minute; and sequentially quenching the melt from the top down in a controlled manner. Additionally, the present invention provides for the materials produced by such method. The present invention is also directed to a process for removing oxygen and hydrogen impurities from chalcogenide glass components using dynamic distillation.
Abstract:
Various embodiments of optical fiber designs and fabrication processes for ultra small core fibers (USCF) are disclosed. In some embodiments, the USCF includes a core that is at least partially surrounded by a region comprising first features. The USCF further includes a second region at least partially surrounding the first region. The second region includes second features. In an embodiment, the first features are smaller than the second features, and the second features have a filling fraction greater than about 90 percent. The first features and/or the second features may include air holes. Embodiments of the USCF may provide dispersion tailoring. Embodiments of the USCF may be used with nonlinear optical devices configured to provide, for example, a frequency comb or a supercontinuum.
Abstract:
A method and apparatus for making a substantially void-free preform for a microstructured optical fiber using a one-step process is provided. A preform is prepared from specialty glasses using a direct extrusion method. A die for use with the direct extrusion method is also provided, and a method for drawing the preform into a HC-PBG fiber for use in transmitting infra-red wavelength light is also provided. The preform comprises an outer jacket made of solid glass, a cladding having a plurality of air holes arranged in a desired pattern within the jacket, and a core which is hollow.
Abstract:
Various embodiments of optical fiber designs and fabrication processes for ultra small core fibers (USCF) are disclosed. In some embodiments, the USCF includes a core that is at least partially surrounded by a region comprising first features. The USCF further includes a second region at least partially surrounding the first region. The second region includes second features. In an embodiment, the first features are smaller than the second features, and the second features have a filling fraction greater than about 90 percent. The first features and/or the second features may include air holes. Embodiments of the USCF may provide dispersion tailoring. Embodiments of the USCF may be used with nonlinear optical devices configured to provide, for example, a frequency comb or a supercontinuum.
Abstract:
An optical fiber, which has a zero-material dispersion wavelength equal to or greater than 2 μm, and a high nonlinear susceptibility χ3 equal to or greater than 1×10−12 esu, and uses tellurite glass having sufficient thermal stability for processing into a low loss fiber, employs a PCF structure or HF structure having strong confinement into a core region. This enables light to propagate at a low loss. The size and geometry of air holes formed in the core region, and the spacing between adjacent air holes make it possible to control the zero dispersion wavelength within an optical telecommunication window (1.2-1.7 μm), and to achieve large nonlinearity with a nonlinear coefficient γ equal to or greater than 500 W−1 km−1.
Abstract:
A thermally stable chalcogenide glass, a process for making the same, and an optical fiber drawn therefrom are provided. A chalcogenide glass having the composition Ge(5−y)As(32−x)Se(59+x)Te(4+y) (0≦y≦1 and 0≦x≦2) is substantially free from crystallization when it is heated past the glass transition temperature Tg or drawn into optical fibers. A process for making the thermally stable chalcogenide glass includes purifying the components to remove oxides and scattering centers, batching the components in a preprocessed distillation ampoule, gettering oxygen impurities from the mixture, and heating the components to form a glass melt. An optical fiber formed from the chalcogenide glass is substantially free from crystallization and exhibits low signal loss in the near-infrared region, particularly at wavelengths of about 1.55 μm.
Abstract:
In general, in one aspect, the invention features a method that includes exposing a surface to a first gas composition under conditions sufficient to deposit a layer of a first chalcogenide glass on the surface, and exposing the layer of the first chalcogenide glass to a second gas composition under conditions sufficient to deposit a layer of a second glass on the layer of the first chalcogenide glass, wherein the second glass is different from the first chalcogenide glass.