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    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS
    221.
    发明申请
    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开
    用于烯烃聚合的催化组分

    公开(公告)号：US20150141594A1

    公开(公告)日：2015-05-21

    申请号：US14406470

    申请日：2013-06-05

    Applicant: Basell Poliolefine Italia S.r.l.

    Inventor： Alessandro Mignogna ,  Simona Guidotti ,  Igor Kashulin ,  Giampiero Morini ,  Ilya Nifant'ev ,  Joachim T.M. Pater

    IPC: C08F4/52 ,  C08F4/16 ,  C08F4/10

    CPC classification number: C08F4/52 ,  C08F4/10 ,  C08F4/16 ,  C08F110/08 ,  C08F4/651 ,  C08F2500/15 ,  C08F2500/17 ,  C08F110/06 ,  C08F2500/12

    Abstract: A catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor compound of the following formula (I) in which the R groups equal to or different from each other, are C1-C15 hydrocarbon groups, the R1-R2 groups, equal to or different from each other, are hydrogen, halogen or C1-C15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, P, S, N and Si, which can be fused together to form one or more cycles; n and m are integer from 0 to 3 with the proviso that at least one of them is different from 0 and that diisobutyl o-phenylenediacetate is excluded.

    Abstract translation: 包含Mg，Ti和其中R基彼此相同或不同的下式（I）的电子给体化合物的烯烃聚合催化剂组分是C 1 -C 15烃基，R 1 -R 2基， 相同或不同的是氢，卤素或C 1 -C 15烃基，任选地含有选自卤素，P，S，N和Si的杂原子，其可以一起稠合形成一个或多个循环; n和m是0-3的整数，条件是它们中的至少一个不同于0，并且排除邻苯二乙酸二异丁酯。

    PROPYLENE BASED TERPOLYMERS
    222.
    发明申请
    PROPYLENE BASED TERPOLYMERS 有权
    基于丙烯的三元共聚物

    公开(公告)号：US20150087770A1

    公开(公告)日：2015-03-26

    申请号：US14402262

    申请日：2013-05-21

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

    Inventor： Roberta Marzolla ,  Monica Galvan ,  Tiziana Caputo

    IPC: C08F210/06 ,  C08J5/18

    CPC classification number: C08F210/06 ,  C08F210/16 ,  C08J5/18 ,  C08J2323/12 ,  C08J2323/14 ,  C08L23/14 ,  C08L23/142 ,  C08F210/08 ,  C08F2500/12 ,  C08F2500/26

    Abstract: A propylene, ethylene, 1-butene terpolymer containing from 0.5 wt % to 2.2 wt % of ethylene derived units and from 6.0 wt % to 20.0 wt % of 1 butene derived units; wherein: i) the ratio C2 wt %/C4 wt % ranges from 0.09 to 0.06; wherein C2 wt % is the weight per cent of ethylene derived units and C4 wt % is the weight per cent of 1-butene derived units; ii) the Melt flow rate ranges from 0.4 to 54 g/10 min; iii) the xylene soluble fraction at 25° C. is lower than 15.0 wt % the minimum value being 5.0 wt %.

    Abstract translation: 含有0.5重量％至2.2重量％的乙烯衍生单元和6.0重量％至20.0重量％的1-丁烯衍生单元的丙烯，乙烯，1-丁烯三元共聚物; 其中：i）C2重量％/ C4重量％的比率范围为0.09至0.06; 其中C2重量％是乙烯衍生单元的重量百分比，C4重量％是1-丁烯衍生单元的重量百分数; ii）熔体流动速率范围为0.4至54g / 10min; iii）25℃下的二甲苯可溶级分低于15.0wt％，最小值为5.0wt％。

    PRE-POLYMERIZED CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS
    224.
    发明申请
    PRE-POLYMERIZED CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 有权
    用于烯烃聚合的预聚合催化剂组分

    公开(公告)号：US20140316083A1

    公开(公告)日：2014-10-23

    申请号：US14365357

    申请日：2012-12-11

    Applicant: Basell Poliolefine Italia S.r.l.

    Inventor： Diego Brita ,  Gianni Collina ,  Giampiero Morini

    IPC: C08F10/02

    CPC classification number: C08F10/02 ,  C08F10/00 ,  C08F4/6492 ,  C08F110/06 ,  C08F4/651

    Abstract: A pre-polymerized catalyst component for the polymerization of olefins endowed with high activity and morphological stability comprises a non-stereospecific solid catalyst component containing Ti, Mg and a halogen, and an amount of an ethylene/alpha-olefin block (co)polymer ranging from 0.1 up to 5 g per g of said solid catalyst component, said prepolymerized catalyst component being characterized by a mercury porosity, due to pores having radius up to 1 μm, ranging from 0.15 to 0.5 cm3/g and by the fact that at least 55% of said porosity is due to pores having pore radius up to 0.2 μm.

    Abstract translation: 用于聚合具有高活性和形态稳定性的烯烃聚合的预聚合催化剂组分包括含有Ti，Mg和卤素的非立体特异性固体催化剂组分和一定量的乙烯/α-烯烃嵌段（共）聚合物范围 0.1至5g / g所述固体催化剂组分，所述预聚催化剂组分的特征在于水银孔隙率，由于孔径半径为1μm，范围为0.15至0.5cm 3 / g，并且至少 所述孔隙率的55％是由于孔半径高达0.2μm的孔。

    POLYMER COMPOSITION FOR BUMPERS AND INTERIORS AND POLYETHYLENE-BASED RESIN PRECURSOR
    225.
    发明申请
    POLYMER COMPOSITION FOR BUMPERS AND INTERIORS AND POLYETHYLENE-BASED RESIN PRECURSOR 有权
    用于缓冲和内部聚合物和聚乙烯基树脂前体的聚合物组合物

    公开(公告)号：US20140303310A1

    公开(公告)日：2014-10-09

    申请号：US14357474

    申请日：2012-10-30

    Applicant: Basell Poliolefine Italia S.r.l.

    Inventor： Fabiana Fantinel ,  Sander Willems ,  Michele Grazzi ,  Giampaolo Pellegatti ,  Jurgen Rohrmann ,  Shahram Mihan

    IPC: C08L23/12 ,  C08F210/16

    CPC classification number: C08F210/16 ,  C08K3/34 ,  C08L23/06 ,  C08L23/08 ,  C08L23/10 ,  C08L23/12 ,  C08L23/16 ,  C08L2205/02 ,  C08L23/0815

    Abstract: Polyolefin compositions suitable for injection moulded items e.g. for impact bumpers and car interiors comprising from 30% to 90% by weight of an heterophasic propylene polymer composition (A); and from 10% to 70% by weight of a multimodal ethylene/C6-C12 alpha olefin copolymer (B); having density from 0.850 to 0.920 g/cm3, total comonomer content from 6% to 30% by weight, Mw/Mn from 4 to 20; intrinsic viscosity in decalin at 135° C. from 1.0 to 4.0 dL/g, and comprising an HDPE fraction (HDPE % wt) up to 30% wt; further comprising up to 50% by weight of a filler (C) and optionally, in amount up to 10% by weight with respect to the overall composition, an impact modifier masterbatch component (D) consisting of a ultra-soft heterophasic copolymer component.

    Abstract translation: 适用于注射成型物品的聚烯烃组合物 用于冲击保险杠和汽车内饰，其包含按重量计30％至90％的异相丙烯聚合物组合物（A）; 和10重量％至70重量％的多峰乙烯/ C 6 -C 12α-烯烃共聚物（B）; 密度为0.850〜0.920g / cm3，总共聚单体含量为6〜30重量％，Mw / Mn为4〜20; 在135℃，萘烷中的特性粘度为1.0-4.0dL / g，并且包含高达30％wt的HDPE级分（HDPE％wt）; 进一步包含至多50重量％的填料（C），并且任选地，相对于整个组合物，其量为至多10重量％，由超软多相共聚物组分组成的抗冲改性剂母料组分（D）。

    MAGNESIUM DICHLORIDE-ETHANOL ADDUCTS AND CATALYST COMPONENTS OBTAINED THEREFROM
    226.
    发明申请
    MAGNESIUM DICHLORIDE-ETHANOL ADDUCTS AND CATALYST COMPONENTS OBTAINED THEREFROM 有权
    二氯二苯醚 - 乙醇添加剂和催化剂组分

    公开(公告)号：US20140171604A1

    公开(公告)日：2014-06-19

    申请号：US14236486

    申请日：2012-08-01

    Applicant: Basell Poliolefine Italia S.r.l.

    Inventor： Daniele Evangelisti ,  Benedetta Gaddi ,  Gianni Collina

    IPC: C08F4/649

    CPC classification number: C08F4/6494 ,  C08F10/00 ,  C08F4/6545 ,  C08F4/651 ,  C08F110/06 ,  C08F2500/17

    Abstract: Solid adducts comprising MgCl2 and an alcohol ROH in which R is a C1-C20 hydrocarbon group, in which the amount of alcohol ranges from higher than 42% to 60% by weight and the porosity determined with Hg method due to pores up to 1 μm and expressed in cm3/g, is such that the value of its ratio with the amount of alcohol in percentage falls above the straight line defined by the equation y=−0.0158x+1.03 in which y is the porosity of the adduct and x is the alcohol percentage by weight.

    Abstract translation: 包含MgCl 2和醇ROH的固体加合物，其中R是C1-C20烃基，其中醇的含量范围高于42％至60％（重量），并且由于孔高达1μm而用Hg法测定的孔隙率 以cm 3 / g表示，其与醇的比例的比值的值落在由等式y = -0.0158x + 1.03定义的直线之上，其中y是加合物的孔隙率，x是 酒精重量百分比。

    Styrene-assisted depolymerization of polyolefins
    229.
    发明授权
    Styrene-assisted depolymerization of polyolefins 有权

    公开(公告)号：US12173124B2

    公开(公告)日：2024-12-24

    申请号：US17450234

    申请日：2021-10-07

    Applicant: Basell Poliolefine Italia S.r.l.

    Inventor： Sandor Nagy ,  Daniel F. White ,  Christopher D. Smith ,  David L Ramage

    IPC: C08J11/20

    Abstract: Methods of depolymerizing polyolefin-based material into useful petrochemical products using styrene oligomers or polymers, and heat are described. The styrene oligomers or polymers improve the depolymerization reaction by decreasing the halftime for the depolymerization, which results in a higher depolymerization rate and a shorter residence time in the depolymerization unit, allowing for a predictable depolymerization reaction, and decreasing the branching or aromatic formations in the product.

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