公开(公告)号：US5232888A

公开(公告)日：1993-08-03

申请号：US774340

申请日：1991-10-10

Applicant: Tetsuro Kamo

Inventor： Tetsuro Kamo

IPC: B01J31/22 ,  B01J21/04 ,  B01J23/85 ,  B01J23/882 ,  B01J31/02 ,  B01J37/02 ,  B01J37/04 ,  C10G45/08 ,  C10G49/04

CPC classification number: B01J31/223 ,  B01J23/85 ,  B01J23/882 ,  B01J31/1616 ,  B01J37/0203 ,  B01J37/04 ,  C10G45/08 ,  B01J21/04 ,  B01J2231/641 ,  B01J2531/64 ,  B01J2531/66 ,  B01J2531/845 ,  B01J2531/847 ,  B01J31/0201 ,  B01J37/0236

Abstract: Disclosed is a method of preparing a catalyst for hydrogenation of a hydrocarbon oil, in which a hydroxycarboxylic acid is added to a catalyst carrying a metal of the Group VI of the Periodic Table and a metal of the Group VIII of the same, optionally along with phosphoric acid, on a carrier, in an amount of from 0.3 to 5 molar times of the total metal molar number of the metal of the Group VI and the metal of Group VIII, and thereafter the resulting catalyst is dried at a temperature not higher than 200.degree. C. The catalyst has a high catalyst activity and is used for hydrogenation of a hydrocarbon oil, especially satisfying the requirement of reducing the sulfur content in a light oil.

公开(公告)号：US5200381A

公开(公告)日：1993-04-06

申请号：US774339

申请日：1991-10-10

Applicant: Tetsuro Kamo

Inventor： Tetsuro Kamo

IPC: B01J31/22 ,  B01J23/85 ,  B01J27/188 ,  B01J31/02 ,  B01J31/04 ,  B01J37/00 ,  B01J37/02 ,  B01J37/04 ,  C10G45/08 ,  C10G49/04

CPC classification number: C10G45/08 ,  B01J23/85 ,  B01J27/188 ,  B01J31/1616 ,  B01J31/223 ,  B01J37/0009 ,  B01J2231/641 ,  B01J2531/0272 ,  B01J2531/64 ,  B01J2531/66 ,  B01J2531/845 ,  B01J2531/847 ,  B01J31/0201 ,  B01J37/0236

Abstract: A method of preparing a catalyst for hydrogenation of a hydrocarbon oil, wherein an aqueous solution containing a metal of Group VI of the Periodic Table and a metal of Group VIII of the same, along with a hydroxycarboxylic acid and optionally phosphoric acid is added to a carrier substance consisting essentially of at least one of an inorganic oxide and an inorganic hydrate, and the resulting blend is kneaded, shaped and thereafter dried at a temperature not higher than 200.degree. C. The catalyst has a high catalyst activity and is used for hydrogenation of a hydrocarbon oil, especially satisfying the requirement of reducing the sulfur content in a light oil.

公开(公告)号：US5095162A

公开(公告)日：1992-03-10

申请号：US732001

申请日：1991-07-18

Applicant: Yves Chauvin ,  Dominique Commereuc ,  Alain Forestiere ,  Gerard Leger

Inventor： Yves Chauvin ,  Dominique Commereuc ,  Alain Forestiere ,  Gerard Leger

IPC: B01J31/02 ,  B01J31/04 ,  B01J31/14 ,  B01J31/16 ,  B01J31/22 ,  C07B61/00 ,  C07C2/26 ,  C07C2/30 ,  C07C2/32 ,  C07C11/02 ,  C08F4/607

CPC classification number: C07C2/32 ,  B01J31/0201 ,  B01J31/04 ,  B01J31/143 ,  B01J31/2234 ,  C07C2/30 ,  B01J2231/20 ,  B01J2531/847 ,  C07C2531/02 ,  C07C2531/04 ,  C07C2531/14 ,  C07C2531/22

Abstract: The invention concerns a catalytic composition resulting from placing at least one divalent nickel compound into contact with at least one hydrocarbylaluminum halide and at least one epoxy compound, in any order. It also concerns the use of the catalytic composition in a process of oligomerizing monoolefins.

公开(公告)号：US4935550A

公开(公告)日：1990-06-19

申请号：US231508

申请日：1988-08-12

Applicant: David J. Miller ,  David R. Bryant

Inventor： David J. Miller ,  David R. Bryant

IPC: B01D11/04 ,  B01J31/40 ,  B01J38/00 ,  C01G55/00 ,  C07B61/00 ,  C07C45/50 ,  C07C47/02

CPC classification number: B01J31/24 ,  B01J31/2404 ,  B01J31/2409 ,  B01J31/2414 ,  B01J31/4046 ,  C07C45/50 ,  B01J2231/321 ,  B01J2531/80 ,  B01J2531/822 ,  B01J2531/96 ,  B01J31/0201 ,  Y02P20/584

Abstract: A method for recovering a transition metal, e.g., rhodium, from a non-polar organic solution containing non-polar organic solvent-soluble and polar solvent-insoluble coordination complex of the transition metal and a non-polar organic solvent-soluble and polar solvent-insoluble ligand, e.g., an organophosphorus ligand, by contacting the non-polar organic solution with a polar solution of an ionic organophosphine ligand, the transition metal then can be transferred back into a non-polar solution for reuse. In one embodiment rhodium is rendered amenable for back-extraction by treating the polar solution with a suitable conditioning reagent.

公开(公告)号：US4861918A

公开(公告)日：1989-08-29

申请号：US231510

申请日：1988-08-12

Applicant: David J. Miller ,  David R. Bryant ,  Ernst Billig ,  Bernard L. Shaw

Inventor： David J. Miller ,  David R. Bryant ,  Ernst Billig ,  Bernard L. Shaw

IPC: B01J31/40 ,  C07B61/00 ,  C07C29/16 ,  C07C31/02 ,  C07C45/50 ,  C07C47/02

CPC classification number: B01J31/4046 ,  B01J31/24 ,  B01J31/2404 ,  C07C45/50 ,  B01J2231/321 ,  B01J2531/822 ,  B01J31/0201 ,  B01J31/0215 ,  B01J31/0231 ,  B01J31/0255 ,  B01J31/04 ,  Y02P20/582 ,  Y02P20/584

Abstract: A process for improving the catalytic activity of a partially deactivated solubilized rhodium - tertiary organophosphine complex hydroformylation catalyst.

公开(公告)号：US4557760A

公开(公告)日：1985-12-10

申请号：US614480

申请日：1984-05-29

Applicant: Heinz Erpenbach ,  Klaus Gehrmann ,  Winfried Lork ,  Peter Prinz

Inventor： Heinz Erpenbach ,  Klaus Gehrmann ,  Winfried Lork ,  Peter Prinz

IPC: C07C27/00 ,  B01J31/40 ,  C01G55/00 ,  C07C21/00 ,  C07C51/12 ,  C07C51/42 ,  C07C51/54 ,  C07C67/00 ,  C22B3/16 ,  C22B3/26 ,  C22B5/20 ,  C22B11/00

CPC classification number: B01J31/4046 ,  B01J31/0239 ,  B01J31/0268 ,  B01J31/04 ,  B01J31/20 ,  B01J31/26 ,  B01J31/4038 ,  C22B11/04 ,  C22B3/0018 ,  C22B5/20 ,  B01J2231/34 ,  B01J2531/82 ,  B01J2531/822 ,  B01J31/0201 ,  Y02P10/234

Abstract: In this process for recovering noble metals of group VIII from a contaminated catalyst solution originating from the carbonylation of methyl acetate and/or dimethylether (the catalyst solution containing carbonyl complexes of these noble metals, organic or inorganic promoters, undistillable organic contaminants as well as volatiles) the volatiles are distillatively removed from the catalyst solution and the remaining distillation residue is water-treated, whereby the noble metal/carbonyl-complex is precipitated together with the organic contaminants and is separated from the aqueous phase, while the promotor is dissolved and recovered in conventional manner. The noble metals are then set free in elemental form by subjecting the noble metal/carbonyl-complex separated and contaminated with organic polymers at temperatures of 150.degree. to 300.degree. C. to treatment with an ethyleneglycoldialkylether solvent of the formula R(--OCH.sub.2 --CH.sub.2).sub.n --OR, in which n stands for a number of from 1 to 4 and R stands for identical or different alkyl groups having from 1 to 6 carbon atoms. The noble metal can then be recovered by filtration, and the solvent can be freed of organic contaminants by distillation.

Abstract translation: 在用于从源自乙酸甲酯和/或二甲醚的羰基化的污染的催化剂溶液（含有这些贵金属的羰基络合物的催化剂溶液，有机或无机促进剂，不可挥发的有机污染物以及挥发物）中回收第VIII族的贵金属的方法中 ）将挥发物从催化剂溶液中蒸馏除去，剩余的蒸馏残余物进行水处理，由此贵金属/羰基络合物与有机污染物一起沉淀并与水相分离，同时促进剂被溶解和回收 以常规方式。 然后通过使贵金属/羰基络合物在150℃至300℃的温度下用有机聚合物分离和污染来将贵金属自由化，以用式R（-OCH 2 -CH 2）的乙二醇缩酮基醚溶剂 ）n-OR，其中n表示1至4的数，R表示具有1至6个碳原子的相同或不同的烷基。 然后可以通过过滤回收贵金属，并且溶剂可以通过蒸馏而除去有机污染物。

公开(公告)号：US3222294A

公开(公告)日：1965-12-07

申请号：US24634262

申请日：1962-12-21

Applicant: ELEKTROCHEM WERKE MUENCHEN AG

Inventor： MEYER HEINZ W

IPC: B01J31/02 ,  B21D22/14 ,  B21H1/04 ,  C01B15/023 ,  C01B15/037 ,  C08F2/02 ,  C08F2/04 ,  C08F4/28 ,  C08F4/30 ,  C08F4/34 ,  C08F283/01 ,  C08K5/10 ,  C08L67/06

CPC classification number: B21D22/14 ,  B01J31/0201 ,  B01J31/0202 ,  B01J31/0204 ,  B01J31/0209 ,  B01J31/0258 ,  B21H1/04 ,  C01B15/023 ,  C01B15/037 ,  C08F4/28 ,  C08F283/01 ,  C08K5/10 ,  C08L67/06 ,  Y10S260/28 ,  C08F4/00

公开(公告)号：US2815332A

公开(公告)日：1957-12-03

申请号：US2815332D

IPC: C08G65/28

CPC classification number: B01J31/0201

公开(公告)号：US2324248A

公开(公告)日：1943-07-13

申请号：US45695842

申请日：1942-09-01

Applicant: SHELL DEV

Inventor： VAUGHAN WILLIAM E ,  RUST FREDERICK F

IPC: B01J31/02 ,  C07C17/10

CPC classification number: B01J31/006 ,  B01J31/0201 ,  B01J2231/40 ,  C07C17/10

公开(公告)号：US20240300878A1

公开(公告)日：2024-09-12

申请号：US18444075

申请日：2024-02-16

Applicant: WISys Technology Foundation, Inc.

Inventor： Ian Andrew MacKenzie ,  Mark Elliot Levenstein

IPC: C07C37/18 ,  B01J31/02 ,  B01J35/39 ,  C07D233/64 ,  C07D249/08 ,  C07D307/94 ,  C07F7/12

CPC classification number: C07C37/18 ,  B01J31/0201 ,  B01J31/0244 ,  B01J35/39 ,  C07D233/64 ,  C07D249/08 ,  C07D307/94 ,  C07F7/127 ,  B01J2231/4288

Abstract: Various embodiments disclosed relate to a method of preparing aryl fluorinated ether compounds. The method involves contacting an aryl halide with a fluorinated alcohol in the presence of a photocatalyst, a base, and irradiation with electromagnetic radiation comprising a wavelength between about 200 nm and about 800 nm. The present invention also provides a method of late-stage photochemical modification of a biologically active compound, such as drugs or agrochemicals. Fluorinated derivatives of griseofulvin, clofibrate, and 2,4-D methyl ester are described herein.