Abstract:
An arc extinguishing resin processed article having excellent flame retardancy is disclosed, in which the contribution to rise in inner pressure is small, a pyrolysis gas that can efficiently extinguish an arc generated upon the interruption of a circuit can be generated, and heat resistance withstanding the rise in temperature generated in such a case and pressure resistance withstanding the rise in inner pressure are provided, and a circuit breaker using the arc extinguishing resin processed article are disclosed. The arc extinguishing resin processed article comprises a resin composition comprising (A) a polyolefin resin containing a hydroxyl group in an amount of from 0.2 to 0.7 mol per mol of a methylene group, a part of hydrogen atoms in a methylene chain being substituted with a hydroxyl group, (B) microcapsules containing water as a core material, and (C) a reactive organophosphorus flame retardant having a terminal unsaturated bond, the resin composition being molded and then subjected to radiation crosslinking.
Abstract:
To provide a flame-retardant resin composition exhibiting high flame retardance, and excellent char (shell) formation, moldability and mechanical properties, stably without variation.A flame-retardant resin composition comprising an olefin-type resin (A), a modified copolymer (B) obtained by modifying at least partially a copolymer comprising a C4 olefin and an α,β-unsaturated dicarboxylic anhydride or a derivative thereof, by at least one method of the following (b-1) and (b-2), and an inorganic flame retardant (C):(b-1); modification with a compound having a hydroxyl group and/or a compound having an ether group; and (b-2); partial ionomerization with metal ions. Preferred embodiment of the copolymer comprising a C4 olefin and an α,β-unsaturated dicarboxylic anhydride or a derivative thereof is an alternating copolymer composed of the C4 olefin and the α,β-unsaturated dicarboxylic anhydride or the derivative thereof
Abstract:
The present invention relates to polycarbonate compositions comprising A) from 10 to 99 parts by weight, in each ease based on the sum of components A+B+C, of aromatic polycarbonate and/or aromatic polyester carbonate, B) from 1 to 35 parts by weight, in each case based on the sum of components A+B+C, of rubber-modified graft polymer of B.1 from 5 to 95 wt. % of at least one vinyl monomer on B.2 from 95 to 5 wt. % of one or more graft bases having a glass transition temperature
Abstract:
A flame retardant poly(arylene ether) composition is described. In addition to the poly(arylene ether), the composition includes a polyolefin component, and a flame retardant composition that includes a metal dialkyl phosphinate but excludes melamine phosphate, melamine pyrophosphate, and melamine polyphosphate. The polyolefin component can be a polyolefin polymer and/or the polyolefin block of a poly(alkenyl aromatic)-polyolefin block copolymer. The composition is particularly suitable as a replacement for poly(vinyl chloride) in insulation for wire and cable.
Abstract:
The present invention relates to a polycarbonate resin composition having an excellent weld strength. The polycarbonate resin composition comprises:100 parts by weight of a mixture comprising (a) 60 to 95 parts by weight of an aromatic polycarbonate resin, (b) 4 to 39 parts by weight of a styrene/(meth)acrylonitrile-based copolymer produced by polymerizing at least a styrene-based monomer and a (meth)acrylonitrile-based monomer with each other in the presence of a rubber, and (b′) 1 to 36 parts by weight of a styrene/(meth)acrylonitrile-based copolymer produced by polymerizing at least a styrene-based monomer and a (meth)acrylonitrile-based monomer with each other in the absence of the rubber;0 to 40 parts by weight of a phosphorus-based flame retardant (c);0 to 5 parts by weight of a fluorinated polyolefin (d) and0 to 50 parts by weight of an inorganic filler (e), which (c), (d) and (e) are blended to the 100 parts by weight of the mixture in respective amount,the polycarbonate resin composition satisfying the following relational formula (1): Sg/(Sd/B2/3)≧0.5 (1) wherein B is a weight ratio (% by weight) of a sum of the components (b) and (b′) to a sum of the components (a), (b) and (b′) ((b+b′)/(a+b+b′)); Sd is an average occupation area (μm2) of a styrene/(meth)acrylonitrile-based copolymer domain (hereinafter referred to merely as an “AS domain”) dispersed in a polycarbonate resin matrix; and Sg is an average occupation area (μm2) of rubber particles dispersed in the AS domain in which Sd and Sg are values measured by subjecting an electron micrograph of the composition to image processing.
Abstract:
Soft flame retardant thermoplastic compositions that are preferably halogen free and include a styrenic block copolymer having a low modulus, one or more of a polyolefin polymer or copolymer and an acrylate containing polymer or copolymer, one or more of a softener and plasticizer, an inorganic phosphorous-containing flame retardant, and optionally but preferably, a platelet filler such as a nanoclay or an organic modified clay. In a preferred embodiment, the phosphorous-containing flame retardant has a surface coating thereon which reduces sensitivity of the flame retardant to water, and thus reduces the amount of the flame retardant that can leach out in the presence of water, thereby enabling the compositions of the present invention to be utilized outdoors or other environments where exposure to water or high humidity is possible. The hardness of the compositions according to the invention preferably ranges from about Shore A 40 to about Shore A 90. The compositions exhibit high char formation upon burning and also desirable vertical burn characteristics.
Abstract translation:软阻燃热塑性组合物优选无卤素,并且包括具有低模量的苯乙烯嵌段共聚物,聚烯烃聚合物或共聚物中的一种或多种,含丙烯酸酯的聚合物或共聚物,软化剂和增塑剂中的一种或多种,无机磷 含有阻燃剂,以及任选但优选为片状填料,例如纳米粘土或有机改性粘土。 在优选的实施方案中,含磷阻燃剂在其上具有表面涂层,其降低了阻燃剂对水的敏感性,从而减少了在水存在下可以浸出的阻燃剂的量,从而使得 本发明要在户外或其他暴露于水或高湿度的环境中使用。 根据本发明的组合物的硬度优选在约Shore A 40至约Shore A 90的范围内。该组合物在燃烧时表现出高的焦炭形成性,并且还具有期望的垂直燃烧特性。
Abstract:
Disclosed is a polypropylene resin composition with flame retardance and abrasion resistance. The polypropylene resin composition according to the present invention includes 20 to 200 parts by weight of an inorganic flame retardant; and 0.1 to 10 parts by weight of at least one additive, based on 100 parts by weight of a base resin comprising 30 to 90% by weight of polypropylene copolymer resin and 10 to 70% by weight of polyolefin alpha copolymer resin. The polypropylene resin composition according to the present invention can be used for industrial cables with potent endurance since it includes an inorganic flame retardant to show flame retardance and it can remove or reduce a whitening phenomenon and show a significantly improved abrasion resistance without deteriorating moldability or mechanical property even when the contents of the composition are varied to enhance abrasion resistance.
Abstract:
The present invention provides flame retardant thermoplastic moulding compositions comprising: A) from 65% to 99.5% by weight (with respect of the total weight of the final composition) of a polyolefinic polymer particularly selected among polypropylene polymers; B) from 0.1% to 30% by weight (with respect of the total weight of the final composition) of a synergic mixture of an hypophosphorous acid metal salt and halogenated organic compounds; C) from 0.5% to 10% by weight (with respect of the total weight of the final composition) of a plurality of selected additives consisting of processing aids, heat and process stabilisers, UV stabilisers, antidripping agents (PTFE—Polytetrafluoroethylene), pigments, mould releasing agents, nucleating agents; D) from 0% to 50% by weight (with respect of the total weight of the final composition) of an inorganic filler. The total of the percentages by weight of components A to D is 100%.
Abstract:
A halogen-free, flame-resistant wrapping foil, characterized in that the wrapping foil is composed of polyolefin and contains more than 120 phr of metal hydroxide, preferably aluminum hydroxide and more preferably magnesium hydroxide.
Abstract:
A flame retardant, halogen-free polymer composition that is a blend of: (1) a polyolefin selected from (a) EVA containing 25-90% by weight ethylene and 10-75% by weight vinyl acetate, (b) LLDPE, (c) LDPE, (d) VLDPE, (e) HDPE, or mixtures thereof; (2) a coupling agent made from (f) about 10 to about 50% by weight of a copolymer of ethylene and about 1% by weight to about 15% by weight functional comonomer and (g) about 50% by weight to about 90% by weight of an ethylene-based polymer; and (3) an inorganic flame retardant filler.