-
公开(公告)号:HUT66566A
公开(公告)日:1994-12-28
申请号:HU9301074
申请日:1993-04-13
Applicant: ROHM & HAAS
Inventor: BORS DANIEL ARTHUR , SNYDER BARRY SAMUEL
IPC: C08L101/02 , C08F8/30 , C08L101/00 , C09J133/00 , C09J133/06 , C09J157/12 , C09J201/00 , C09J201/06 , C09J133/10 , C09J133/12
Abstract: A pressure-sensitive adhesive having improved shear strength obtained by virtue of the formation of the enamine of a pendant acetoacetate is described. These materials contain acetoacetate functional monomer in a low Tg emulsion polymer. Shear strength is improved without compromise of either peel strength or tack.
-
公开(公告)号:ES2062003T3
公开(公告)日:1994-12-16
申请号:ES89307193
申请日:1989-07-14
Applicant: ROHM & HAAS
Inventor: SPADA LON T , WILCZYNSKI JOSEPH J
IPC: C08F220/12 , C08K5/092 , C08K5/17 , C08K5/5317 , C09J7/02 , C09J157/04 , C09J201/06 , C09J11/06
Abstract: There are disclosed normally tacky, pressure-sensitive adhesive compositions comprising one or more normally tacky polymers having a Tg of about 0 DEG C. or less and containing pendant functional groups attached to the backbone and having the formula: - R1 - @ - CH2 - X in which R1 is a divalent organic radical at least 3 atoms in length, and X is organoacyl or cyano, the polymers preferably also being normally tacky when cured. Such polymers have markedly improved cohesive strength (shear holding value) with little or no detriment to adhesive tack or adhesion (peel resistance), and these improvements are realized without the necessity of incorporating cross-linking monomers such as N-methylolamides or other cross-linking agents. Pressure-sensitive adhesive, water-based emulsions containing such polymers and pressure-sensitive adhesive articles comprising a substrate having at least a portion of one surface thereof coated with the adhesive compositions are also disclosed. In a preferred embodiment, the adhesive compositions further include a polyacid component for further improving cohesive strength, particularly at acidic pH.
-
公开(公告)号:SG28194G
公开(公告)日:1994-10-28
申请号:SG28194
申请日:1994-02-22
Applicant: ROHM & HAAS
Inventor: SPADA LON T , WILCZYNSKI JOSEPH J
IPC: C08F220/12 , C08K5/092 , C08K5/17 , C08K5/5317 , C09J7/02 , C09J157/04 , C09J201/06 , C09J11/06
Abstract: There are disclosed normally tacky, pressure-sensitive adhesive compositions comprising one or more normally tacky polymers having a Tg of about 0 DEG C. or less and containing pendant functional groups attached to the backbone and having the formula: - R1 - @ - CH2 - X in which R1 is a divalent organic radical at least 3 atoms in length, and X is organoacyl or cyano, the polymers preferably also being normally tacky when cured. Such polymers have markedly improved cohesive strength (shear holding value) with little or no detriment to adhesive tack or adhesion (peel resistance), and these improvements are realized without the necessity of incorporating cross-linking monomers such as N-methylolamides or other cross-linking agents. Pressure-sensitive adhesive, water-based emulsions containing such polymers and pressure-sensitive adhesive articles comprising a substrate having at least a portion of one surface thereof coated with the adhesive compositions are also disclosed. In a preferred embodiment, the adhesive compositions further include a polyacid component for further improving cohesive strength, particularly at acidic pH.
-
公开(公告)号:HK83894A
公开(公告)日:1994-08-26
申请号:HK83894
申请日:1994-08-18
Applicant: ROHM & HAAS
Inventor: SPADA LON T , WILCZYNSKI JOSEPH J
IPC: C08F220/12 , C08K5/092 , C08K5/17 , C08K5/5317 , C09J7/02 , C09J157/04 , C09J201/06 , C09J11/06
Abstract: There are disclosed normally tacky, pressure-sensitive adhesive compositions comprising one or more normally tacky polymers having a Tg of about 0 DEG C. or less and containing pendant functional groups attached to the backbone and having the formula: - R1 - @ - CH2 - X in which R1 is a divalent organic radical at least 3 atoms in length, and X is organoacyl or cyano, the polymers preferably also being normally tacky when cured. Such polymers have markedly improved cohesive strength (shear holding value) with little or no detriment to adhesive tack or adhesion (peel resistance), and these improvements are realized without the necessity of incorporating cross-linking monomers such as N-methylolamides or other cross-linking agents. Pressure-sensitive adhesive, water-based emulsions containing such polymers and pressure-sensitive adhesive articles comprising a substrate having at least a portion of one surface thereof coated with the adhesive compositions are also disclosed. In a preferred embodiment, the adhesive compositions further include a polyacid component for further improving cohesive strength, particularly at acidic pH.
-
公开(公告)号:AU5870794A
公开(公告)日:1994-07-04
申请号:AU5870794
申请日:1993-12-09
Applicant: MINNESOTA MINING & MFG
Inventor: DELGADO JOAQUIN , GOETZ RICHARD J , SILVER SPENCER F
IPC: C08F290/00 , C08F290/06 , C09J7/00 , C09J7/02 , C09J11/08 , C09J133/04 , C09J133/06 , C09J133/08 , C09J201/00 , C09J201/06
Abstract: The invention provides inherently tacky, polymeric, organic, solvent-insoluble, solvent dispersible, elastomeric, pressure sensitive adhesive microspheres having pendant hydrophilic polymeric or oligomeric moieties having a degree of polymerization greater than or equal to 2. The microspheres which are sterically stabilized can offer enhanced stability against coagulation caused by alkali, alkali salts, polyelectrolytes and repeated freeze/thaw cycles. The present invention also provides pressure-sensitive adhesives comprising these microspheres including aerosol spray PSAs, coated sheet materials prepared therefrom, and method of making the microspheres.
-
公开(公告)号:CZ9300661A3
公开(公告)日:1994-02-16
申请号:CZ66193
申请日:1993-04-16
Applicant: ROHM & HAAS
Inventor: SNYDER BARRY SAMUEL , BORS DANIEL ARTHUR
IPC: C08L101/02 , C08F8/30 , C08L101/00 , C09J133/00 , C09J133/06 , C09J157/12 , C09J201/00 , C09J201/06
CPC classification number: C09J157/12 , C08F8/32 , C09J133/062 , C09J2201/606 , Y10S526/931 , Y10T428/2852 , Y10T428/31942 , C08F2220/1825 , C08F2220/1858
-
公开(公告)号:CZ66193A3
公开(公告)日:1994-02-16
申请号:CZ66193
申请日:1993-04-16
Applicant: ROHM & HAAS
Inventor: SNYDER BARRY SAMUEL , BORS DANIEL ARTHUR
IPC: C08L101/02 , C08F8/30 , C08L101/00 , C09J133/00 , C09J133/06 , C09J157/12 , C09J201/00 , C09J201/06
Abstract: A pressure-sensitive adhesive having improved shear strength obtained by virtue of the formation of the enamine of a pendant acetoacetate is described. These materials contain acetoacetate functional monomer in a low Tg emulsion polymer. Shear strength is improved without compromise of either peel strength or tack.
-
公开(公告)号:SK37893A3
公开(公告)日:1994-01-12
申请号:SK37893
申请日:1993-04-22
Applicant: ROHM & HAAS
Inventor: SNYDER BARRY S , BORS DANIEL A
IPC: C08L101/02 , C08F8/30 , C08L101/00 , C09J133/00 , C09J133/06 , C09J157/12 , C09J201/00 , C09J201/06 , C09J133/04 , C08F20/26 , C08K3/28
Abstract: A pressure-sensitive adhesive having improved shear strength obtained by virtue of the formation of the enamine of a pendant acetoacetate is described. These materials contain acetoacetate functional monomer in a low Tg emulsion polymer. Shear strength is improved without compromise of either peel strength or tack.
-
公开(公告)号:IL105376D0
公开(公告)日:1993-08-18
申请号:IL10537693
申请日:1993-04-14
Applicant: ROHM & HAAS
IPC: C08L101/02 , C08F8/30 , C08L101/00 , C09J133/00 , C09J133/06 , C09J157/12 , C09J201/00 , C09J201/06 , C09J
Abstract: A pressure-sensitive adhesive having improved shear strength obtained by virtue of the formation of the enamine of a pendant acetoacetate is described. These materials contain acetoacetate functional monomer in a low Tg emulsion polymer. Shear strength is improved without compromise of either peel strength or tack.
-
公开(公告)号:DE58904705D1
公开(公告)日:1993-07-22
申请号:DE58904705
申请日:1989-07-28
Applicant: HENKEL KGAA
Inventor: LANOYE THIERRY , GARNAULT ANNE-MARIE
IPC: C09J121/00 , B32B15/06 , C08J3/24 , C08L19/00 , C08L101/06 , C09J5/00 , C09J5/06 , C09J113/00 , C09J115/00 , C09J167/00 , C09J177/00 , C09J201/06
Abstract: A liquid or spreadable, vulcanisable rubber mixture based on a plurality of polymers, of which at least one is olefinically unsaturated, are prepared in such a manner that they can be cured by two different chemical reaction mechanisms which can be activated successively and can be catalysed at least substantially independently of one another. This is achieved by preparing a rubber mixture from - 30-70 parts by weight of a polymer A containing an average of at least 2 hydroxyl groups per macromolecule, - 70-30 parts by weight of a polymer B which is compatible with A and contains an average of at least 2 carboxylic acid and/or carboxylic anhydride groups or at least one carboxylic acid and one carboxylic anhydride group per molecule, - 10-120 parts by weight of vulcanisation assistants and if desired fillers and/or auxiliaries and - if desired 0.01-5 parts by weight of esterification catalysts, at least one of the polymers A and B being vulcanisable via its olefinic double bonds under conventional reaction conditions at elevated temperatures.
-
-
-
-
-
-
-
-
-