公开(公告)号：EP0361620A2

公开(公告)日：1990-04-04

申请号：EP89202443.1

申请日：1989-09-29

Applicant: UNION CARBIDE CHEMICALS AND PLASTICS COMPANY INC. (a New York corporation)

Inventor： King, Stephen Wayne

IPC: C07C43/11 ,  C07C41/03 ,  B01J31/12 ,  C11D1/72

CPC classification number: C07C41/03 ,  B01J31/223 ,  B01J2531/37 ,  C07C43/11 ,  C07C43/13

Abstract: This invention relates to modified Group IIIB metal-containing bimetallic or polymetallic catalysts and the use thereof in the preparation of alkoxylation products, i.e., condensation reaction products of alkylene oxides and organic compounds having at least one active hydrogen. In another aspect of this invention, processes are provided for preparing the modified Group IIIB metal-containing bimetallic or polymetallic catalysts for alkoxylation using a Group IIIB metal or a Group IIIB metal-containing compound as sources for the catalytically-active group IIIB metal. In a further aspect of this invention, processes are provided for preparing alkoxylation products that have beneficial, narrow molecular weight ranges using the modified Group IIIB metal-containing bimetallic or polymetallic catalysts.

Abstract translation: 本发明涉及经修饰的含IIIB族金属的双金属或多金属催化剂及其在制备烷氧基化产物中的用途，即环氧烷烃与具有至少一个活性氢的有机化合物的缩合反应产物。 在本发明的另一方面，提供了使用IIIB族金属或IIIB族金属化合物作为催化活性IIIB族金属的来源来制备用于烷氧基化的改性的含IIIB族金属的双金属或多金属催化剂的方法。 在本发明的另一方面，提供了使用改性的含IIIB族金属的双金属或多金属催化剂制备具有有益的窄分子量范围的烷氧基化产物的方法。

公开(公告)号：EP0361617A2

公开(公告)日：1990-04-04

申请号：EP89202440.7

申请日：1989-09-29

Applicant: UNION CARBIDE CHEMICALS AND PLASTICS COMPANY INC. (a New York corporation)

Inventor： King, Stephen Wayne

IPC: C07C43/11 ,  C07C41/03 ,  B01J31/12 ,  C11D1/72

CPC classification number: C08G65/269 ,  B01J31/223 ,  B01J2531/23 ,  C07C41/03 ,  C08G65/2651 ,  C07C43/11

Abstract: This invention relates to modified calcium-containing bimetallic or polymetallic catalysts and the use thereof in the preparation of alkoxylation products, i.e., condensation reaction products of alkylene oxides and organic compounds having at least one active hydrogen. In another aspect of this invention, processes are provided for preparing modified calcium-containing bimetallic or polymetallic catalysts for alkoxylation using calcium metal or a calcium-containing compound as sources for the catalytically-active calcium. In a further aspect of this invention, processes are provided for preparing alkoxylation products that have beneficial, narrow molecular weight ranges using the modified calcium-containing bimetallic or polymetallic catalysts.

Abstract translation: 本发明涉及改性含钙双金属或多金属催化剂及其在制备烷氧基化产物中的用途，即环氧烷烃与具有至少一个活性氢的有机化合物的缩合反应产物。 在本发明的另一方面，提供了使用钙金属或含钙化合物作为催化活性钙的来源制备用于烷氧基化的改性含钙双金属或多金属催化剂的方法。 在本发明的另一方面，提供了使用改性的含钙双金属或多金属催化剂制备具有有益的窄分子量范围的烷氧基化产物的方法。

公开(公告)号：EP0355837A2

公开(公告)日：1990-02-28

申请号：EP89115647.3

申请日：1989-08-24

Applicant: UNION CARBIDE CHEMICALS AND PLASTICS COMPANY INC. (a New York corporation)

Inventor： Abatjoglou, Anthony George ,  Bryant, David Robert

IPC: C22B3/00 ,  C01G55/00 ,  B01J39/12 ,  B01J31/40

CPC classification number: B01J31/24 ,  B01J31/185 ,  B01J31/20 ,  B01J31/2234 ,  B01J31/2404 ,  B01J31/2409 ,  B01J31/4023 ,  B01J31/4046 ,  B01J31/4053 ,  B01J39/12 ,  B01J2231/321 ,  B01J2531/02 ,  B01J2531/0211 ,  B01J2531/80 ,  B01J2531/822 ,  B01J2531/985 ,  B01J2540/12 ,  B01J2540/32 ,  B01J2540/42 ,  B01J2540/525 ,  B01J2540/68 ,  C01G55/001 ,  C07C45/50 ,  C07C45/79 ,  C22B3/42 ,  Y02P10/234 ,  Y02P20/584 ,  C07C47/02

Abstract: A method for recovering a transition metal such as rhodium from a polar or non-polar liquid by contacting said transition metal-­containing liquid with an ion-exchange resin having bonded ionically thereto an organophosphorus ligand; the transition metal can be eluted from the bed using a liquid containing a sufficient concentra­tion of organophosphorus ligand.

Abstract translation: 通过使所述含过渡金属的液体与离子交换树脂离子交联的有机磷配体接触从极性或非极性液体中回收诸如铑的过渡金属的方法; 可以使用含有足够浓度的有机磷配体的液体从床上洗脱过渡金属。

公开(公告)号：EP0353722A2

公开(公告)日：1990-02-07

申请号：EP89114222.6

申请日：1989-08-01

Applicant: UNION CARBIDE CHEMICALS AND PLASTICS COMPANY INC. (a New York corporation)

Inventor： Wegman, Richard William

IPC: C07C67/36 ,  C07C67/37 ,  C07C69/14

CPC classification number: B01J27/188 ,  B01J23/30 ,  B01J23/6527 ,  B01J27/185 ,  B01J27/186 ,  C07C51/12 ,  C07C67/36 ,  C07C67/37 ,  C07C69/14

Abstract: A process and novel catalyst for the carbonylation of one or more of alcohols, ethers and ether alcohols to esters and, optionally, to carboxylic acids. The reaction is effected in the vapor state over a solid catalyst comprising a polyoxometalate anion in which the metal is at least one taken from Group V and VI of the Periodic Chart of the Elements complexed with a cation from a member of Group VIIIA of the Periodic Chart of the Elements. Preferably, the catalyst is deposited on a support that is inert to the reaction. The preferred support is silica.

Abstract translation: 用于将一种或多种醇，醚和醚醇羰基化成酯和任选地作为羧酸的方法和新型催化剂。 该反应在蒸气状态下在包含多金属氧酸盐阴离子的固体催化剂下进行，其中金属为元素周期表第V和VI族中的至少一种元素，该元素与元素周期表第VIIIA族成员的阳离子络合 元素图表。 优选地，催化剂沉积在对反应呈惰性的载体上。 优选的载体是二氧化硅。

公开(公告)号：EP1817370A1

公开(公告)日：2007-08-15

申请号：EP05813823.1

申请日：2005-10-26

Applicant: UNION CARBIDE CHEMICALS AND PLASTICS COMPANY, INC.

Inventor： LIN, Thomas, S. ,  COGEN, Jeffrey, M.

IPC: C08K5/20 ,  C08K5/30 ,  H01B3/44 ,  C08K5/00

CPC classification number: C08K5/005 ,  C08K5/20 ,  C08K5/25 ,  C08L23/02

Abstract: Compositions including a polymer, a primary antioxidant, a secondary antioxidant, and a metal deactivator selected from at least one of 2,2'-oxamido bis[ethyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate] and oxalyl bis(benzylidenehydrazide), are disclosed. The compositions can also include a light stabilizer. The compositions can be used to manufacture insulations for wire and cable. The compositions have improved long-term heat aging and also retain their color when exposed to heat. A method of making an insulation for a conductor, such as a wire or a cable, made from a composition is also provided.

公开(公告)号：EP1065220A1

公开(公告)日：2001-01-03

申请号：EP00305422.8

申请日：2000-06-28

Applicant: UNION CARBIDE CHEMICALS AND PLASTICS COMPANY, INC.

Inventor： Wang, Weidong ,  Cann, Kevin Joseph

IPC: C08F2/34 ,  C08F2/44 ,  C08F36/06 ,  C09C1/56

CPC classification number: C09C1/565 ,  C01P2006/19 ,  C07C327/00 ,  C08F36/04 ,  C08F210/18 ,  C08K9/02 ,  C09C1/56 ,  Y10S526/901 ,  C08F2/34 ,  C08F2/44 ,  C08L21/00

Abstract: There is provided a polymerization of a sticky polymer in the presence of a catalyst under polymerization conditions using carbon black as the inert particulate material, the improvement comprises conducting said polymerization in the presence of a carbon black that has been treated with a sulfur donor and/or an oxidizing agent.

Abstract translation: 在使用炭黑作为惰性颗粒材料的聚合条件下，在催化剂存在下提供粘性聚合物的聚合，改进包括在已经用硫供体处理的炭黑存在下进行所述聚合和/ 或氧化剂。

公开(公告)号：EP0907655A1

公开(公告)日：1999-04-14

申请号：EP97932600.0

申请日：1997-06-25

Applicant: UNION CARBIDE CHEMICALS AND PLASTICS COMPANY, INC.

Inventor： REICHLE, Walter, Thomas ,  KAROL, Frederick, John

IPC: C07F7 ,  C08F4 ,  C08F10

CPC classification number: C08F10/00 ,  C07F7/006 ,  C08F210/16 ,  Y10S526/901 ,  C08F4/64189 ,  C08F4/6028 ,  C08F4/64048 ,  C08F210/14

Abstract: A catalyst composition for the polymerization of olefins is provided, comprising a bis(hydroxy aromatic nitrogen ligand) transition metal catalyst precursor and an activating cocatalyst.

公开(公告)号：EP0478075B1

公开(公告)日：1998-11-11

申请号：EP91202425.4

申请日：1991-09-19

Applicant: UNION CARBIDE CHEMICALS AND PLASTICS COMPANY, INC.

Inventor： King, Stephen Wayne ,  Olson, Kurt Damar ,  Ream, Bernard Claude

IPC: C07B37/06

CPC classification number: C07D295/023 ,  B01J21/02 ,  B01J21/10 ,  B01J23/00 ,  C07B37/06 ,  C07C41/01 ,  C07C41/16 ,  C07C213/08 ,  C07D295/088 ,  C07D305/06 ,  Y02P20/582 ,  C07C43/04 ,  C07C43/18 ,  C07C43/11

公开(公告)号：EP0856531A2

公开(公告)日：1998-08-05

申请号：EP98105783.9

申请日：1995-08-02

Applicant: UNION CARBIDE CHEMICALS AND PLASTICS COMPANY, INC.

Inventor： The designation of the inventor has not yet been filed

IPC: C08F36/00

CPC classification number: C07D405/12 ,  B01J8/1827 ,  B01J8/1872 ,  B01J8/24 ,  B01J23/10 ,  C07D311/58 ,  C07D405/14 ,  C07D409/14 ,  C07D417/12 ,  C07D493/04 ,  C08F10/14 ,  C08F36/04 ,  C08F36/06 ,  C08F210/16 ,  C08F210/18 ,  C08K3/04 ,  C08K3/34 ,  Y10S526/901 ,  C08F2/34 ,  C08L21/00 ,  C08F2/44

Abstract: Granular particles of polybutadiene or polyisoprene which contain residues of a rare earth metal and from 0.3 to 80 wt % of an inert particulate material which is carbon black, silica, clay, talc or a mixture thereof

公开(公告)号：EP0476780B1

公开(公告)日：1998-05-06

申请号：EP91202423.9

申请日：1991-09-19

Applicant: UNION CARBIDE CHEMICALS AND PLASTICS COMPANY, INC.

Inventor： King, Stephen Wayne

IPC: C07D487/08

CPC classification number: C07D295/088 ,  B01J21/10 ,  B01J23/00 ,  C07D471/08 ,  Y02P20/582