Method of making planographic printing plate and planographic printing plate
    232.
    发明授权
    Method of making planographic printing plate and planographic printing plate 有权
    平版印刷版和平版印刷版的制作方法

    公开(公告)号:US09091926B2

    公开(公告)日:2015-07-28

    申请号:US13756538

    申请日:2013-02-01

    Abstract: A method of making a planographic printing plate includes exposing, to infrared light, a planographic printing plate precursor including a recording layer provided on a substrate, and developing the precursor using an aqueous alkaline solution. The recording layer comprises a copolymer containing a structural unit derived from (meth)acrylonitrile and at structural unit derived from styrene, a water-insoluble and alkali-soluble resin, and an infrared absorbing agent, the solubility of the recording layer in the aqueous alkaline solution being increased by the exposure. The aqueous alkaline solution has a pH of 8.5 to 10.8 and contains a betaine-based amphoteric surfactant and an ammonium salt represented by Formula (I): R1, R2, R3, and R4 each independently represent an alkyl or aryl group; the total number of carbon atoms in R1, R2, R3, and R4 is not more than 20; and X− represents a counter anion.

    Abstract translation: 制造平版印刷版的方法包括将包含设置在基材上的记录层的平版印刷版原版曝光于红外光,并使用碱性水溶液显影前体。 记录层包含含有衍生自(甲基)丙烯腈的结构单元和衍生自苯乙烯的结构单元,水不溶性和碱溶性树脂和红外吸收剂的共聚物,记录层在碱性水溶液中的溶解度 溶液通过曝光增加。 碱性水溶液的pH为8.5〜10.8,含有基于甜菜碱的两性表面活性剂和式(I)表示的铵盐:R1,R2,R3和R4各自独立地表示烷基或芳基; R1,R2,R3和R4中的碳原子总数不超过20; X表示抗衡阴离子。

    Polymeric dyes, overcoat compositions and thermal lithographic printing plates
    237.
    发明授权
    Polymeric dyes, overcoat compositions and thermal lithographic printing plates 有权
    聚合染料,外涂层组合物和热平版印刷版

    公开(公告)号:US08491993B2

    公开(公告)日:2013-07-23

    申请号:US12669805

    申请日:2008-07-24

    Abstract: A thermal lithographic printing plate overcoat composition comprising (a) a water-soluble polymeric dye having an absorption band between about 300 and about 600 nm; and (b) micro-particles or nano-particles is provided. A negative-working thermal lithographic printing plate comprising (a) a hydrophilic substrate; (b) a near infrared imaging layer disposed on the hydrophilic substrate; and (c) an overcoat layer disposed on the imaging layer, said overcoat layer comprising a water-soluble polymeric dye having an absorption band between about 300 and about 600 nm; and micro-particles or nano-particles is also provided. Finally, a water-soluble polymeric dye having an absorption band between about 300 and about 600 nm is provided.

    Abstract translation: 一种热平版印刷版外涂层组合物,其包含(a)具有在约300和约600nm之间的吸收带的水溶性聚合物染料; 和(b)微粒或纳米颗粒。 一种负性热平版印刷版,其包含(a)亲水性基材; (b)设置在亲水基板上的近红外成像层; 和(c)设置在成像层上的外涂层,所述外涂层包含具有在约300和约600nm之间的吸收带的水溶性聚合物染料; 还提供微粒或纳米颗粒。 最后,提供了吸收带在约300和约600nm之间的水溶性聚合物染料。

    Negative-working imaging elements and methods of use
    238.
    发明授权
    Negative-working imaging elements and methods of use 失效
    负面影像元素和使用方法

    公开(公告)号:US08354216B2

    公开(公告)日:2013-01-15

    申请号:US12173220

    申请日:2008-07-15

    Abstract: Negative-working imageable elements such as lithographic printing plate precursors, include a free-radically polymerizable component, an initiator composition that is capable of generating free radicals sufficient to initiate polymerization of the free-radically polymerizable component upon exposure to imaging radiation in the presence of a radiation absorbing compound, a radiation absorbing compound, an aerobic free radical inhibitor, optionally a polymeric binder that is not a free radically polymerizable component, and an anaerobic free radical inhibitor. The molar ratio of the anaerobic free radical inhibitor to the aerobic free radical inhibitor is at least 1:1. This combination of inhibitors provides increased shelf life and good latent image stability particularly when the element includes a polymeric topcoat layer that functions as an oxygen barrier.

    Abstract translation: 负面工作的可成像元件如平版印刷版前体包括可自由基聚合的组分,引发剂组合物,其能够产生足够的自由基,以便在存在可见光辐射的情况下暴露于成像辐射时引发可自由基聚合的组分的聚合 辐射吸收化合物,辐射吸收化合物,需氧自由基抑制剂,任选的不是可自由基自由基组分的聚合物粘合剂和厌氧自由基抑制剂。 厌氧自由基抑制剂与好氧自由基抑制剂的摩尔比至少为1:1。 这种抑制剂的组合提供了增加的保质期和良好的潜影稳定性,特别是当元件包括用作氧阻隔层的聚合物顶涂层时。

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