Abstract:
Multi-layered golf balls containing a dual-core structure are provided. The core structure includes an inner core (center) made from a foam or metal-containing composition, or it has a hollow shell construction, and the outer core layer is made of a thermoplastic composition. Preferably, the thermoplastic composition comprises: a) ethylene acid copolymer, b) plasticizer, and c) cation source. A fatty acid ester such as ethyl oleate is preferably used as the plasticizer. The core assembly preferably may have a positive hardness gradient extending across the entire assembly. The core structure and resulting ball have relatively good resiliency at given compressions.
Abstract:
A golf ball comprising a core and a cover, the core consisting of: a solid inner core layer formed from a first unfoamed thermoplastic composition TP1 and having a diameter of 1.10 inch or less and a center Shore C hardness (Hcenter) of 50 or less, one or more optional intermediate core layers, and an outer core layer formed from a second thermoplastic composition TP2 and having a thickness of 0.200 inches or greater and an outer surface Shore C hardness (Houter surface) of 70 or greater, wherein Houter surface>Hcenter, and Houter surface−Hcenter≧40.
Abstract:
The present invention generally relates to golf balls and more particularly to golf balls having multi-layered cores comprising a thermoset rubber center, a thermoplastic intermediate core layer, and a thermoset rubber outer core layer. A cover layer is disposed about the multi-layered core. At least one of the center, intermediate core layer, and outer core layer comprises a polyalkenamer rubber. The polyalkenamer rubber may be blended with other rubbers such as polybutadiene, polyisoprene, ethylene propylene diene, and styrene-butadiene rubbers. The polyalkenamer rubber composition helps improve resiliency of the core and provides the ball with a comfortable and soft feel.
Abstract:
Multi-piece golf balls containing a dual-core structure are provided. The core structure includes an inner core (center) comprising a foam composition, preferably foamed polyurethane. The outer core layer is preferably formed from a non-foamed thermoset composition such as polybutadiene rubber. Preferably, the specific gravity (density) of the foam inner core is less than the density of the outer core layer. The ball further includes a cover of at least one layer and may include at least one casing layer. The core structure and resulting ball have relatively good resiliency.
Abstract:
Methods for making golf balls having a cover made from polyurea and polyurethane compositions are provided. The methods for making the polyurea and polyurethane composition involve preparing an amine-terminated or hydroxyl-terminated first prepolymer by reacting a first isocyanate compound with a stoichiometric excess of polyamine or polyol (depending on the type of prepolymer desired). The first prepolymer is then reacted with a stoichiometric excess of a second isocyanate compound to form an isocyanate-terminated second prepolymer. The second prepolymer is then reacted with a chain extender.
Abstract:
Multi-layered golf ball core sub-assemblies and the resulting golf balls are provided. The core structure includes an inner core (center) comprising a foam composition, preferably foamed polyurethane. The intermediate core layer is preferably formed from a thermoplastic composition such as an ethylene acid copolymer ionomer resin; and the outer core layer is preferably formed from a thermoset composition such as polybutadiene rubber. The core layers have different hardness and specific gravity levels. The core structure and resulting ball have relatively good resiliency.
Abstract:
Process for making golf ball having multi-layered cover having a very thin outermost cover layer comprising: providing first and second substantially hemispherical half shells comprising a thermoplastic composition; dispensing uncured liquid thermoset composition into a hemispherical cavity of first half shell; inserting first half of a core subassembly into hemispherical cavity and displacing an amount of the uncured liquid thermoset composition such that the uncured liquid thermoset composition forms an inner cover layer; dispensing the uncured liquid thermoset composition into hemispherical cavity of second half shell; inserting second half of core subassembly into hemispherical cavity of second half shell and displacing an amount of the uncured liquid thermoset composition such that the uncured liquid thermoset composition forms an inner cover layer and thereby mating the first and second half shells; curing thermoset inner cover layer; and forming dimples in the outer surfaces of mated first and second half shells.
Abstract:
A golf ball including a core and a cover including a thermoplastic inner cover layer having a material hardness of 60 to 80 Shore D; a thermoset outer cover layer comprising a castable polyurea and having a material hardness of 20 to 60 Shore D; and a thermoset intermediate cover layer disposed between the inner and outer cover layers and having a hardness substantially the same as the inner cover layer hardness and greater than the outer cover layer hardness. The inner cover includes one or more high- or low-acid ionomers and, optionally, a maleic anhydride modified polyolefin. The intermediate layer is formed from a castable liquid polybutadiene rubber.
Abstract:
A golf ball comprising a core and a cover layer having a cover inner surface, a cover outer surface, a treated cover region, and an untreated cover region, the treated cover region extending inward from the cover outer surface a depth DCTr and being treated with and comprising a fatty acid and/or fatty acid salt composition, the untreated cover region disposed between the cover inner surface and the treated cover region and having a depth DCUTr, the untreated cover region comprising n regions of hardness wherein n≧1 and wherein at least one of the n regions of hardness has a hardness H1 such that the hardness α is greater than the hardness H1, and wherein each of said n regions of hardness further comprise a depth DCUTn such that DCTr≦(1/n)(DUT1+DUT2+ . . . +DUTn). In another embodiment, DCTr≦(n)(DCUT1+DCUT2+ . . . +DCUTn). In yet another embodiment, DCTr≦(1/n2)(DCUT1+DCUT2+ . . . +DCUTn).
Abstract:
Multi-piece golf balls containing a dual-core structure are provided. The core structure includes a small, heavy inner core (center) having a relatively high specific gravity and a surrounding outer core layer having a relatively low specific gravity. The core structure may have different hardness gradients. The center of the core comprises a metal material such as copper, steel, brass, tungsten, titanium, aluminum, and alloys thereof. The outer core layer is formed from a thermoset composition, such as polybutadiene rubber, or from a thermoplastic composition, such as an ethylene acid copolymer ionomer resin.