Abstract:
A binder for a coating composition is a combination of(a) polymers containing intramolecular carboxylic anhydride groups and having an average molecular weight of from 500 to 25,000 and(b) organic compounds containing 4,5-dihydrooxazole groups in a quantity corresponding to an equivalent ratio of carboxylic anhydride groups to 4,5-dihydrooxazole groups of from 0.5:1 to 2:1, and contains from 0.005 to 5% by weight, based on the weight of components (a) and (b), of ammonia, a primary amine or secondary amine.
Abstract:
A composition useful in coatings, binders, adhesives, and the like comprises a stable blend of a carboxylic acid copolymer emulsion and a halohydroxy propyl ammonium copolymer solution. The blend is curable, after activation by base, to a crosslinked insoluble alloy polymer.
Abstract:
A paint composition comprising a powder paint uniformly dispersed in an aqueous solution of a water soluble carboxylated resin. Use is made of a powder paint having a mean particle size of 1-100 microns and preferably comprising a thermosetting resin as the vehicle. This paint composition contains no surfactant but, nevertheless, features high stability of the dispersion phase and can provide paint films of excellent resistance to water. This paint composition may utilize recovered waste powder paint, i.e. a mixture of differently colored powder paints, preferably with the addition of a black pigment such as carbon black.
Abstract:
A powder lacquer binder composition which comprises a homogeneous crosslinkable mixture comprising: (A) a polymer containing more than one carboxyl group and having a melting and softening point of from 20.degree. to 150.degree. C. (as determined by differential thermoanalysis) and an acid number of from 10 to 150 mg of KOH/g; and (B) a 1,2-polyepoxide which is N,N',N"-triglycidyl triazolidine-3,5-dione having an epoxide value of from 0.6 to 1.13; the mixture containing from 0.5 to 1.5 1,2-epoxide group per carboxyl group; and a process for the preparation thereof.
Abstract:
A water-based coating composition which emits very little pollutants on curing to a water-resistant coating comprises a synthetic resin containing free carboxyl groups held in solution or stable dispersion in water by an amine. The amine is a tertiary carbinamine containing at least two hydroxymethyl groups bonded to the carbon atom carrying the amine group. The coating compositions react with formaldehyde to produce stable fluid emulsion coating compositions having similar properties on curing. The coating compositions are used to coat substrates.
Abstract:
Vinyl resins containing carboxyl or sulfonic acid functionalities can be formulated as stable, aqueous, colloidal dispersions suitable for preparing coatings by converting them to ionomers in a mixture of an organic solvent water-soluble organic polymer and water, followed by stripping off solvent.
Abstract:
Monoethylenic monomers, including from about 1 to about 30% by weight of monoethylenic carboxylic acid, are placed in solution in a liquid mixture preferably containing a low molecular weight polyhydric alcohol and an anionic surfactant and this liquid mixture is dispersed in water containing a C.sub.3 -C.sub.4 alkanol and polymerized in the presence of an organic peroxide free radical polymerization catalyst at an elevated temperature, while agitating the dispersion. The dispersion of polymer particles is then at least partially neutralized, preferably with ammonia or an amine, to form an aqueous dispersion which is stable and which is useful in electrocoating.
Abstract:
Water-based paints having improved properties are disclosed. Improvements in resistance to crater formation and dirt pick-up is achieved by incorporation of crosslinked latex into a water-based paint comprising (a) an amino resin crosslinking agent, (b) a mixture of at least two copolymers of acrylic monomers, (c) an amine and (d) water or water and an organic solvent.
Abstract:
Coated electrical steel sheets having excellent punchability, weldability and insulation resistance are produced by applying an electrical steel sheet with a treating dispersion obtained by compounding the particle separating resin emulsion and the compatible resin to an aqueous solution containing chromic acid in the particularly defined amount and baking the thus applied steel sheets. To the treating dispersion may be added saccharides or polyhydric alcohols as a reducing agent or boric acid or phosphoric acid.
Abstract:
A novel complexer for use in aqueous coating compositions formed from acidic resins, as well as the coating compositions, are described. The complexer is formed from a metal having a coordination value in excess of its valence and a polyalkylene polyamine along with, optionally, organic acids and cometals. The acidic resin, partially neutralized with ammonia, is added to the formed complexer to form the coating composition, a coordinate, which, upon drying, provides films which are water resistant and have excellent wet rub resistance. The coating compositions are particularly useful for inks, including gravure and flexographic inks.