公开(公告)号：US5710208A

公开(公告)日：1998-01-20

申请号：US542544

申请日：1995-10-13

Applicant: Klaus Bederke ,  Carmen Flosbach ,  Eva Frigge ,  Walter Schubert

Inventor： Klaus Bederke ,  Carmen Flosbach ,  Eva Frigge ,  Walter Schubert

IPC: C09D133/10 ,  C08L33/06 ,  C09D133/04 ,  C09D133/06 ,  C09D167/00 ,  C09D167/02 ,  C09D167/06 ,  C09D171/02 ,  C09D175/04 ,  C09D201/00 ,  C09D201/08 ,  C08J3/00

CPC classification number: C09D171/02 ,  C09D133/064 ,  C09D167/06 ,  C09D201/08 ,  C08L33/068

Abstract: A binder composition, a coating composition containing this binder, a process for its production and use to produce single or multi-layer lacquer coatings, particularly in the automotive sector, are described. The binder composition contains A) 25 to 75 wt. % of one of more resins containing carboxyl groups, which may contain .alpha.,.beta.-unsaturated groups, with a number average molecular weight (Mn) of 500 to 10000 g/mol and an acid value of 15 to 200 mg KOH/g, B) 25 to 75 wt. % of one or more polyethers, polyesters, polyether/polyesters and/or (meth)acrylic copolymers with at least one .alpha.,.beta.-unsaturated group and at least one epoxy group per molecule, wherein the .alpha.,.beta.-unsaturated groups and epoxy groups are present in a numerical ratio of 20:80 to 80:20, with a number average molecular weight (Mn) of up to 10000 g/mol, C) 0 to 60 wt. % of one or more polyols with at least two hydroxyl functional groups per molecule, D.sub.1) 0 to 20 wt. % of one or more melamine resins, D.sub.2) 0 to 40 wt. % of one or more capped polyisocyanates, wherein the sum of the weight percentages of components A), B), C), D.sub.1) and D.sub.2) is 100 wt. %, together with E) 0 to 10 wt. % of one or more catalysts to catalyze the reaction of the carboxyl and epoxy groups, related to the sum of the weights of components A) to D.sub.2), and F) 0.1 to 10 wt. % of one or more thermally or photochemically activated initiators, related to the total weight of components A) and B).

Abstract translation: 描述了粘合剂组合物，含有该粘合剂的涂料组合物，其生产和用于生产单层或多层漆涂料的方法，特别是在汽车领域。 粘合剂组合物含有A）25〜75wt。 可以含有数均分子量（Mn）为500〜10000g / mol，酸值为15〜200mgKOH / g的α，β-不饱和基团的含羧基的树脂中的一种以上的羧基，B值 ）25〜75重量％ ％的一种或多种聚醚，聚酯，聚醚/聚酯和/或具有至少一个α，β-不饱和基团和每分子至少一个环氧基团的（甲基）丙烯酸共聚物，其中α，β-不饱和基团和环氧基团 以20:80至80:20的数值比存在，数均分子量（Mn）高达10000g / mol，C）0至60wt。 ％的一种或多种每分子具有至少两个羟基官能团的多元醇，D1）0-20重量％ ％的一种或多种三聚氰胺树脂，D2）0-40重量％ ％的一种或多种封端的多异氰酸酯，其中组分A），B），C），D1）和D2的重量百分比之和为100重量％。 ％，连同E）0〜10wt。 ％的一种或多种催化剂催化羧基和环氧基的反应，与组分A）至D2的重量之和相关），和F）0.1至10wt。 ％的一种或多种热或光化学活化的引发剂，与组分A）和B）的总重量有关。

公开(公告)号：US5705560A

公开(公告)日：1998-01-06

申请号：US602674

申请日：1996-02-16

Applicant: Kunihide Takarabe ,  Yoshio Tamura ,  Takayuki Sugiyama ,  Tomohiro Shinoda ,  James Keith Bardman

Inventor： Kunihide Takarabe ,  Yoshio Tamura ,  Takayuki Sugiyama ,  Tomohiro Shinoda ,  James Keith Bardman

IPC: C09D5/00 ,  C08L33/06 ,  C09D133/04 ,  C09D133/06 ,  C09D133/10 ,  C09D201/02 ,  C09D201/08 ,  C08K3/10 ,  C08K5/16

CPC classification number: C09D133/062 ,  C09D133/064 ,  C08L33/062 ,  C08L33/064

Abstract: This invention is a new aqueous paint composition, and its object is to provide a quick-drying paint composition that has a low sensitivity to temperature and has a high rubber elasticity. An aqueous paint composition, comprising (1) a latex which is a film-forming latex polymer having anionic property, where the solubility of the monomers to form the polymer, excluding the monomers that show anionic property, is 0.01-1.50 g per 100 g of water, (2) a water-soluble or water dispersible polymer formed from a monomer mixture containing at least 20 weight % of amine functional group-containing monomer, and (3) an amount of volatile base sufficient to raise the pH of the composition to a sufficiently high level to bring essentially all amine functional groups to a nonionic state.

Abstract translation: 本发明是一种新的水性涂料组合物，其目的是提供一种对温度敏感性低，橡胶弹性高的快干漆组合物。 一种水性涂料组合物，其包含（1）胶乳，其是具有阴离子性质的成膜胶乳聚合物，其中除了显示阴离子性质的单体之外，形成聚合物的单体的溶解度为0.01-1.50g / 100g 的水，（2）由含有至少20重量％的含胺官能团的单体的单体混合物形成的水溶性或水分散性聚合物，和（3）足以提高组合物的pH的挥发性碱的量 达到足够高的水平以使基本上所有的胺官能团达到非离子状态。

公开(公告)号：US5658967A

公开(公告)日：1997-08-19

申请号：US443846

申请日：1995-05-18

Applicant: Jan Feijen ,  Johannes G. A. Terlingen ,  Jan Pleun Lens

Inventor： Jan Feijen ,  Johannes G. A. Terlingen ,  Jan Pleun Lens

IPC: B29C71/04 ,  B29C59/14 ,  C08J3/28 ,  C08J7/00 ,  C08J7/12 ,  C08J7/14 ,  C09D201/08

CPC classification number: C08J7/123 ,  C08J7/14

Abstract: The invention relates to a method for providing a surface with carboxyl groups. A compound is applied to the surface with at least one functional group which can be converted into a carboxyl group. Thereafter, this surface is treated with a plasma to immobilize the compound, and then the functional group is converted into a carboxyl group. Also provided is a surface having carboxyl groups which is obtained with this method and a product with such a surface for exposure to blood, typically in vivo blood flows.

Abstract translation: 本发明涉及提供具有羧基的表面的方法。 将化合物施加至具有至少一个能够转化为羧基的官能团的表面。 此后，用等离子体处理该表面以固定化合物，然后将官能团转化为羧基。 还提供了通过该方法获得的具有羧基的表面和具有暴露于血液的这种表面的产物，通常在体内血液流动。

公开(公告)号：US5626958A

公开(公告)日：1997-05-06

申请号：US190748

申请日：1994-02-01

Applicant: Bruno D'Herbecourt ,  Thierry Moulin

Inventor： Bruno D'Herbecourt ,  Thierry Moulin

IPC: C09D177/00 ,  C08G18/40 ,  C08J7/04 ,  C09D175/04 ,  C09D201/00 ,  C09D201/06 ,  C09D201/08 ,  B32B5/16 ,  B32B27/18 ,  B32B27/26 ,  B32B27/30

CPC classification number: C08J7/047 ,  C08G18/4063 ,  C09D175/04 ,  C08J2327/06 ,  C08J2475/00 ,  Y10T428/254 ,  Y10T428/31511 ,  Y10T428/31562 ,  Y10T428/31565 ,  Y10T428/31576 ,  Y10T428/3158 ,  Y10T428/31743 ,  Y10T428/31746 ,  Y10T428/31757 ,  Y10T428/31797 ,  Y10T428/3192 ,  Y10T428/31928

Abstract: The invention relates to a coating composition for PVC sections, based on a polymeric vehicle, a crosslinking agent, and a thermoplastic resin powder. The coating composition is particularly useful for coating PVC sections for windows, shutters, and doors. PVC joinery coated with the composition of the invention has exceptional impact strength and resistance to abrasion, friction, and inclement weather.

Abstract translation: 本发明涉及一种基于聚合物载体，交联剂和热塑性树脂粉末的用于PVC部分的涂料组合物。 涂料组合物特别适用于涂覆窗户，百叶窗和门的PVC部分。 涂有本发明组合物的PVC细木工具有优异的冲击强度和耐磨性，摩擦性和恶劣天气。

公开(公告)号：US5124176A

公开(公告)日：1992-06-23

申请号：US347149

申请日：1989-05-03

Applicant: Alastair R. Marrion

Inventor： Alastair R. Marrion

IPC: C09D5/03 ,  C08G59/58 ,  C09D163/00 ,  C09D167/00 ,  C09D201/08

CPC classification number: C09D167/00 ,  C08G59/58 ,  C09D163/00 ,  C09D201/08 ,  Y10S525/934

Abstract: A powder coating composition comprises a component (A) containing carboxylic acid or anhydride functionality and a component (B) containing hydroxy functionality. The components (A) and (B) are both solids at temperatures up to 50.degree. C. and at least one of them is a synthetic resin having a glass transition temperature in the range 0.degree. to 120.degree. C. The carboxylic acid or anhydride-functional component (A) is a compound or polymer containing at least two cyclic carboxylic anhydride groups per molecule or is a compound containing a moiety of the formula: ##STR1## where X is a hydrogen atom or an alkyl group, or a cyclic anhydride thereof. The hydroxy-functional component (B) contains at least two hydroxy groups per molecule and contains at least one amine group in its molecule to catalyze the reaction of the carboxylic acid or anhydride groups of component (A) with the hydroxy groups of component (B). The composition is prepared by mixing the ingredients, extruding them at a temperature above the glass transition temperature of at least one of the components but below the fusion temperature, and comminuting the extrudate. The composition is applied to substrates and heated to cause fusion and reaction of the ingredients to cure the coating layer formed.

Abstract translation: 粉末涂料组合物包含含有羧酸或酸酐官能团的组分（A）和含有羟基官能团的组分（B）。 组分（A）和（B）在高达50℃的温度下都是固体，并且它们中的至少一种是玻璃化转变温度在0-120℃的合成树脂。羧酸或酸酐 官能组分（A）是每分子含有至少两个环状羧酸酐基团的化合物或聚合物，或者是含有下式的部分的化合物：其中X是氢原子或烷基，或环状酸酐 其中。 羟基官能组分（B）每分子含有至少两个羟基，并在其分子中含有至少一个胺基，以催化组分（A）的羧酸或酸酐基团与组分（B）的羟基反应 ）。 通过混合成分，在高于至少一种组分的玻璃化转变温度但低于熔融温度的温度下挤出组合物并粉碎挤出物来制备组合物。 将组合物施加到基底上并加热，使成分的熔融和反应固化形成的涂层。

公开(公告)号：US4812549A

公开(公告)日：1989-03-14

申请号：US1010

申请日：1987-01-07

Applicant: Hisaichi Muramoto ,  Keizou Ishii ,  Tadafumi Miyazono

Inventor： Hisaichi Muramoto ,  Keizou Ishii ,  Tadafumi Miyazono

IPC: C08F220/26 ,  C08F220/28 ,  C08F246/00 ,  C08F290/00 ,  C08F299/02 ,  C08F299/04 ,  C08L33/04 ,  C08L33/14 ,  C09D133/04 ,  C09D133/14 ,  C09D201/08 ,  C08F20/10

CPC classification number: C08F246/00 ,  C08F220/28

Abstract: A resinous composition comprising an acrylic resin having end carboxyl bearing long pendant groups of the formula: ##STR1## wherein R.sub.2 is a substituted or unsubstituted aliphatic hydrocarbon having 2 to 10 carbon atoms, alicyclic hydrocarbon having 6 to 7 carbon atoms or aromatic hydrocarbon having 6 carbon atoms; A is a repeating unit of ##STR2## R.sub.3 is ethylene or propylene; R.sub.4 is a substituted or unsubstituted alkylene having 2 to 7 carbon atoms; R.sub.5 is a substituted or unsubstituted alkylene having 2 to 5 carbon atoms; m is an integer of 1 to 10; and n is an integer of 2 to 50. The invention also concerns a process for preparing said resinous composition characterizing by polymerizing a monomer mixture containing end carboxyl bearing reactive acryl monomer of the formula: ##STR3##

Abstract translation: 一种树脂组合物，其包含具有末端羧基的具有下式的长侧基的丙烯酸树脂：其中R 2是具有2至10个碳原子的取代或未取代的脂族烃，具有6至7个碳原子的脂环族烃或具有6个 碳原子 A是重复单元，其中R3是乙烯或丙烯; R4是取代或未取代的碳原子数为2〜7的亚烷基; R5是取代或未取代的碳原子数2〜5的亚烷基。 m为1〜10的整数。 本发明还涉及一种制备所述树脂组合物的方法，其特征在于通过聚合含有末端羧基的反应性丙烯酸单体的单体混合物，其结构如下：＆lt; IMAGE＆gt;

公开(公告)号：US4602061A

公开(公告)日：1986-07-22

申请号：US716273

申请日：1985-03-26

Applicant: Jaap M. Akkerman

Inventor： Jaap M. Akkerman

IPC: C08G63/00 ,  C08F283/00 ,  C08G18/04 ,  C08G59/00 ,  C08G59/02 ,  C08G61/12 ,  C08G63/12 ,  C08G63/16 ,  C08G63/91 ,  C08G85/00 ,  C09D4/00 ,  C09D4/02 ,  C09D163/00 ,  C09D165/00 ,  C09D167/02 ,  C09D175/00 ,  C09D175/04 ,  C09D201/08 ,  C08G63/02

CPC classification number: C08G61/128 ,  C08F283/00 ,  C08G63/12 ,  C08G85/00 ,  C09D201/08

Abstract: An ambient temperature curable composition is prepared from a .alpha.,.beta.-ethylenically unsaturated carbonyl compound (such as trimethylol propane triacrylate) and a compound chosen from a particular class of compounds having an activated CH group (such as malonate group-containing oligomeric or polymeric esters). The coatings of the invention cure quickly without heating, and have excellent hardness.

Abstract translation: 由α，β-烯属不饱和羰基化合物（例如三羟甲基丙烷三丙烯酸酯）和选自特定类别的具有活化的CH基团的化合物（例如含丙二酸酯基的低聚或聚合酯）制备环境温度可固化组合物 ）。 本发明的涂层在不加热的情况下快速固化，并具有优异的硬度。

公开(公告)号：US4528318A

公开(公告)日：1985-07-09

申请号：US462235

申请日：1983-01-31

Applicant: Sakuichi Konishi ,  Naohito Shingo ,  Mathuo Shibayama

Inventor： Sakuichi Konishi ,  Naohito Shingo ,  Mathuo Shibayama

IPC: C09D5/00 ,  C09D5/02 ,  C09D201/00 ,  C09D201/02 ,  C09D201/06 ,  C09D201/08 ,  C08L51/00

CPC classification number: C09D201/06

Abstract: An aqueous coating composition which comprises an aqueous resin having a carboxyl group (I) and a water-insoluble resin powder (II), the aqueous resin (I) being the one dispersible or soluble into an aqueous medium by ionization when the carboxyl group is neutralized with a basic substance, and the water-insoluble resin powder (II) being the one of 5 to 100 in acid value obtained by reaction between a carboxyl group-containing resin of 20 to 300 in acid value in a solid state at room temperature and a monoepoxy compound or a monoisocyanate compound.

Abstract translation: 一种水性涂料组合物，其包含具有羧基（I）和水不溶性树脂粉末（II）的水性树脂，所述水性树脂（I）是当所述羧基为羧基时，通过离子化可分散或溶解于水性介质中的水性树脂 用碱性物质中和，水溶性树脂粉末（II）为酸值的5〜100的酸值，通过在室温下的固体状态的酸值为20〜300的羧基树脂反应而得到 和单环氧化合物或单异氰酸酯化合物。

公开(公告)号：US4373072A

公开(公告)日：1983-02-08

申请号：US183041

申请日：1980-09-02

Applicant: Hans-Peter Patzschke ,  Armin Gobel

Inventor： Hans-Peter Patzschke ,  Armin Gobel

IPC: C09D5/02 ,  C09D5/44 ,  C09D201/02 ,  C09D201/08 ,  C08L67/04

CPC classification number: C09D5/4419

Abstract: The invention relates to a self-cross-linking, thermosetting, aqueous lacquer coating material, which comprises synthetic resins having a mean molecular weight (M.sub.n) of about 500 to 15,000 and containing primary and/or secondary--and if appropriate also tertiary--amino groups as well as terminal esterified carboxyl groups, having an amine number of about 20 to 180 and an ester number of about 20 to 350, and which becomes dilutable with water through protonization with acids.The invention moreover concerns the utilization of this lacquer coating material for the purposes of cathodic deposition upon electrically conducting surfaces.

Abstract translation: 本发明涉及自交联，热固性水性漆涂料，其包含平均分子量（Mn）为约500至15,000并含有伯和/或仲 - 以及如果合适的叔氨基 基团以及末端酯化羧基，其胺值为约20至180，酯数为约20至350，并且通过用酸质子化而与水稀释。 本发明还涉及这种漆涂料在导电表面上用于阴极沉积的目的。

公开(公告)号：US4373059A

公开(公告)日：1983-02-08

申请号：US183040

申请日：1980-09-02

Applicant: Hans-Peter Patzschke ,  Armin Gobel

Inventor： Hans-Peter Patzschke ,  Armin Gobel

IPC: C09D5/44 ,  C09D201/02 ,  C09D201/08 ,  C08L63/02 ,  C08L67/02 ,  C08L77/06

CPC classification number: C09D5/4419 ,  Y10S524/901

Abstract: The invention concerns a pre-condensed, thermosetting aqueous lacquer coating material containing a pre-condensation product that becomes water-dilutable after protonization with acids and has a mean molecular weight [M.sub.n ] of 800 to 15,000, obtainable by heating of 55 to 95% by weight, based on the total quantity of the binding agent, of an organic synthetic-resin binder containing primary and/or secondary amino groups which has an amine number of 30 to 150 and 5 to 45% by weight of a crosslinking agent possessing esterified terminal carboxyl groups.The invention moreover concerns the application of this lacquer coating material for cathodic deposition upon electrically conducting surfaces.

Abstract translation: 本发明涉及一种预冷凝的热固性水性漆涂料，其含有预先缩合的产物，其在用酸质子化后变成水可稀释的，并且具有800至15,000的平均分子量[Mn]，其通过加热55至95％ 基于粘合剂的总量的含有伯胺和/或仲氨基的有机合成树脂粘合剂，其具有30至150的胺值和5至45重量％的具有酯化的交联剂 末端羧基。 此外，本发明涉及这种漆涂料在导电表面上的阴极沉积的应用。