Abstract:
A compound of formula (I): (Core)n – (X)m wherein Core is a core group; n is 0 and m is 1, or n is 1 and m is at least 1; and X is a group of formula (II): wherein: R 1 , R 3 and R 5 are each independently H or a substituent; R 2 and R 4 are each a substituent; one of R 1 -R 5 is a direct bond or divalent linking group linking the group of formula (II) to Core in the case where n is 1; x and y are 0, 1, 2, 3 or 4; and the compound of formula (I) is substituted with at least one ionic substituent. The compound may be used as an n-dopant to dope an organic semiconductor.
Abstract:
Light-Emitting Compound A composition comprising a light-emitting compound having a peak wavelength of at least 650 nm and a material comprising a group of formula (I): wherein Ar 1 , Ar 2 and Ar 3 in each occurrence are independently selected from a C 6-20 aromatic group and a 6-20 membered heteroaromatic group of C and N ring atoms and at least one of Ar 1 , Ar 2 and Ar 3 is a 6-20 membered heteroaromatic group of C and N ring atoms; x, y and z are each independently at least 1; n, m and p are each independently 0 or a positive integer; and R 1 , R 2 and R 3 in each occurrence is independently a substituent or a single bond to a polymer chain, wherein the group of formula (I) has no more than 3 single bonds to a polymer chain. The composition may be used in the light-emitting layer of an infrared organic light-emitting device.
Abstract:
Anthrathiophene derivatives are disclosed, which comprise transverse solubilising groups at transversal positions relative to the longitudinal axis of the anthracene core. These compounds enable preferential molecular stacking and a high field effect mobility and at the same time show improved solubility as compared to known benzothiophene based materials. In addition, organic thin films comprising these derivatives, their use in electronic devices and components, such as organic thin film transistors, and methods of manufacturing the same are disclosed.
Abstract:
Charge Transfer Salt, Electronic Device and Method of Forming the Same A charge-transfer salt formed from a material comprising a unit of formula (I) and an n-dopant: wherein Ar 1 is an arylene group; R 1 is a substituent comprising at least one cyano group; n is at least 1; R 2 is a substituent; and m is 0 or a positive integer. The material may be a polymer. The charge-transfer salt may be used as a layer of an organic electronic device.
Abstract:
A method of fabricating an organic light emitting device comprises patterning a first electrode layer to form a grid comprising a mesh of electrically conductive metal tracks, depositing a layer of hole injection material from a solution comprising less than 10% solids by weight in a solvent, the thickness of the wet layer of solution before the solvent is evaporated to dry the film being greater than the track spacing, evaporating the solvent to provide a dry film having an average thickness in the spacing between the tracks which is less than 10% of the wet thickness of the wet layer of solution and an average thickness in the spacing between the tracks which is greater than 25% of the track thickness to provide a more planar top surface than the surface of the metal tracks before the layer of hole injection material was deposited, depositing one or more further layers from solution to provide a light emitting layer and one or more optional charge transporting layers, and depositing a second electrode layer. The grid can comprise sets of tracks having different widths and spacings.
Abstract:
Compound, Composition and Organic Light-Emitting Device A compound of formula (I) (Formula (I)) wherein X is O, S, NR 8 , CR 8 2 or SiR 8 2 wherein R 8 in each occurrence is independently a substituent; R 1 , R 5 and R 6 are independently in each occurrence a substituent; x independently in each occurrence is 0, 1, 2, 3 or 4; and y independently in each occurrence is 0, 1 or 2. The compound may be provided as a sidechain, end group or backbone group of a polymer. The compound may be used as a host for a phosphorescent light-emitting material in an organic light-emitting device.
Abstract:
Organic Light-Emitting Device An organic light-emitting device (100) comprising an anode (103); a cathode (109); a light-emitting layer (107) between the anode and the cathode; and a hole-transporting layer (105) between the anode and the cathode, wherein the light-emitting layer comprises a light-emitting compound of formula (I) and the hole-transporting layer comprises a hole-transporting material having a HOMO level that is no more than 5.1 e V from vacuum level: N N ML x R 2 (R ) m (R ) n y (I) wherein: R in each occurrence is independently a substituent; R 2 is H or a substituent; m is 0, 1 or 2; n is 0, 1, 2, 3 or 4; M is a transition metal; L is a ligand; y is at least 1; and x is 0 or a positive integer. (FIGURE 1)
Abstract translation:有机发光器件包括阳极(103)的有机发光器件(100) 阴极(109); 阳极和阴极之间的发光层(107); 和在阳极和阴极之间的空穴传输层(105),其中发光层包含式(I)的发光化合物,空穴传输层包含具有HOMO能级的空穴传输材料, 从真空度不超过5.1e V:NN ML x R 2(R)m(R)ny(I)其中:R在每次出现时独立地为取代基; R 2是H或取代基; m为0,1或2; n为0,1,2,3或4; M是过渡金属; L是配体; y至少为1; x为0或正整数。 (图1)
Abstract:
A polymer comprising a repeat unit of formula (I): wherein R 1 in each occurrence is independently H or a substituent; R 2 in each occurrence is independently a substituent; and x is 0, 1, 2 or 3. The polymer may be used as a light- emitting polymer in an organic light-emitting device.
Abstract:
An organic light-emitting device (100) comprising an anode (103); a cathode (109); a light-emitting layer (107) between the anode and the cathode; a first hole-transporting layer (105A) comprising a first conjugated hole-transporting polymer between the anode and the light-emitting layer; and a second hole-transporting layer (105B) comprising a second conjugated hole-transporting polymer between the first hole-transporting layer and the light-emitting layer, wherein a lowest excited state energy level of the first hole- transporting polymer is lower than the lowest excited state energy of the second hole- transporting polymer.
Abstract:
A phosphorescent metal complex comprising at least one ligand substituted with a group of formula (IIIa), (IIIb) or (IIIc): : wherein Y is selected from O, S, a substituted carbon atom; and a substituted silicon atom; Z in each occurrence is independently selected from N and P; R 4 independently in each occurrence is a substituent; R 5 independently in each occurrence is H or a substituent; x independently in each occurrence is 0, 1, 2 or 3; y and z in each occurrence are independently 0, 1, 2, 3 or 4. The group of formula (IlIa), (Mb) or (IIIc) may be directly bound to the ligand or spaced apart therefrom by a spacer group. The phosphorescent metal complex may be used as a light-emitting material in an organic light-emitting device.