BENZYLIDENE PYRAZOLONES, PRODUCTION AND USE THEREOF
    21.
    发明申请
    BENZYLIDENE PYRAZOLONES, PRODUCTION AND USE THEREOF 审中-公开
    BENZYLIDENPYRAZOLONE,生产和使用

    公开(公告)号:WO9926930A2

    公开(公告)日:1999-06-03

    申请号:PCT/EP9807099

    申请日:1998-11-06

    Abstract: The invention relates to benzylidene pyrazolones of formula (I), wherein the substituents and index n have the following meanings: R = optionally substituted C1-C6 alkyl; R = optionally substituted C1-C6 alkyl, optionally substituted C1-C6 alkoxy, halogen, nitro, cyano; R = hydrogen, halogen, nitro, cyano, a group NR R , OCOR , NR COR ,CO2R , -COSR , -CONR R , C1-C4-alkoxyiminoalkyl, C1-C6 alkoxycarbonyl, optionally substituted C1-C6 alkyl, optionally substituted C1-C6 alkoxy, optionally substituted C1-C6 alkylthio, optionally substituted C2-C6 alkenyl, optionally substituted phenyl, optionally substituted phenoxy, an optionally substituted 5- or 6-membered saturated or unsaturated heterocycle which can contain up to 4 nitrogen atoms and/or up to 2 oxygen or sulphur atoms as ring members; R = C1-C6 alkyl, C1-C4 halogen alkyl; or R and R = an optionally substituted saturated or unsaturated 2- or 3-membered bridge which can contain one sulphur atom which can be oxidized into sulfoxide or sulfone, R = hydrogen or optionally substituted C1-C6 alkyl; R = hydrogen, C1-C6 alkyl or C1-C4 halogenalkyl; n = 0, 1 or 2; X = hydrogen, chlorine or bromine. The compounds to which claim is laid are available in both a trans and a cis form or can be a mixture of these isomers.

    Abstract translation: 式(I)的Benzylidenpyrazolone其中取代基和指数n具有以下含义:R t <1>是未取代的或取代的。 C1-C6烷基; [R <2>是未取代的或取代的。 C1-C6烷基,未取代或取代的。 C1-C6烷氧基,卤素,硝基,氰基; [R <3>是氢,卤素,硝基,氰基,基团NR <5> - [R <6>,OCOR <5>,NR <5> COR <6>,CO 2 <5>,-COSR <5>,-CONR <5> - [R <6>,C1-C4-alkoxyiminoalkyl,C1-C6烷基羰基,未取代的或取代的。 C1-C6烷基,未取代或取代的。 C1-C6烷氧基,未取代的或取代的。 C1-C6烷硫基,未取代或取代的。 C2-C6链烯基,未取代的或取代的。 C2-C6炔基,未取代的或取代的。 苯基,未取代的或取代的。 苯氧基,未取代的或取代的。 5-或6-元饱和或可含有至多4个氮原子和/或至多2个氧或硫原子作为环成员的不饱和的杂环; [R <4> C1-C6-烷基,C1-C4卤代烷基; 或R <3>,R <4>为可以含有可被氧化为亚砜或砜硫原子的任选取代的饱和或不饱和2-或3-元桥; [R <5>为氢或未取代或取代的。 C1-C6烷基; [R <6>是未取代的或取代的。 C1-C6烷基; [R <7>是氢,C1-C6烷基或C1-C4卤代烷基; n为0.1或2; X是氢,氯或溴; 其中要求保护的化合物在跨及在所述顺式 - 形式两者呈现,或者可以是这些异构体的混合物。

    3-AMINOCARBONYL/3-AMINOTHIOCARBONYL-SUBSTITUTED 2-BENZOYL- CYCLOHEXAN-1,3-DIONES WITH HERBICIDAL EFFECT
    22.
    发明申请
    3-AMINOCARBONYL/3-AMINOTHIOCARBONYL-SUBSTITUTED 2-BENZOYL- CYCLOHEXAN-1,3-DIONES WITH HERBICIDAL EFFECT 审中-公开
    3-氨基羰基/ 3-氨基硫代 - 取代的2-苯甲酰基环己烷-1,3-二酮与除草活性

    公开(公告)号:WO1998029383A1

    公开(公告)日:1998-07-09

    申请号:PCT/EP1997007211

    申请日:1997-12-19

    Abstract: The invention concerns 2-benzoyl-cyclohexan-1,3-diones of formula (I), in which R , R stand for hydrogen, nitro, halogen, cyano, rhodano, alkyl, halogen alkyl, alkoxyalkyl, alkenyl, alkinyl, -OR , -OCOR , -OSO2R , -SH, -S(O)nR , -SO2OR , -SO2NR R , -NR SO2R or -NR COR ; R stands for hydrogen, alkyl, halogen alkyl or alkinyl; R stands for hydrogen, optionally substituted alkyl, cycloalkyl, alkenyl, cycloalkenyl, alkinyl, -COR , -CO2R , -COSR or -CONR R ; X stands for oxygen or sulphur; m equals 0 or 1; n equals 0, 1 or 2; R stands for hydrogen, alkyl, halogen alkyl, alkoxyalkyl, alkenyl or alkinyl; R stands for alkyl or halogen alkyl; R stands for alkyl, halogen alkyl, alkoxyalkyl, alkenyl or alkinyl; R stands for hydrogen or alkyl; R stands for alkyl, alkenyl, alkinyl, phenyl or benzyl; R stands for alkyl, halogen alkyl, alkenyl or alkinyl; Q stands for optionally substituted cyclohexan-1,3-dione ring linked in position 2, whereas m equals 1 when R stands for hydrogen. Also disclosed are the salts of these compounds useful in agriculture; processes and intermediate products for preparing the compounds of formula (I), agents containing the same and the use of these derivatives or agents containing the same for controlling undesirable plants.

    Abstract translation: 本发明涉及式(I)的,其中R <1>,R <2> 2-苯甲酰基环己烷-1,3-二酮是氢,硝基,卤素,氰基,氰硫基,烷基,卤代烷基,烷氧基烷基,烯基,炔基, - 或<5>,-OCOR <6>,-OSO 2 R <6>,-SH,-S(O)NR <7>,-SO 2 OR <5>,-SO 2 <5> - [R <8>,-NR <8 > SO 2 <6>或NR <8> COR <6>; [R <3>是氢,烷基,卤代烷基,链烯基或Alkinly; [R <4>为氢,任选取代的烷基,环烷基,烯基,环烯基,炔基,-COR <9>,-CO 2 R <9>,-COSR <9>或-CONR <8> - [R <9>; X是氧或硫; Z为氧或NR <8>; m是0或1; n为0,1或2; [R <5>是氢,烷基,卤代烷基,烷氧基烷基,链烯基或炔基; [R <6>是烷基或卤代烷基; [R <7>是烷基,卤代烷基,烷氧基烷基,烯基或炔基; [R <8>是氢或烷基; [R <9>是烷基,烯基,炔基,苯基或苄基; [R <10>为烷基,卤代烷基,链烯基或炔基; Q在2位上任选取代的联环己烷-1,3-二酮环; 其中m表示1,当R <3>是氢; 及其可农用盐; 的方法和中间体用于制备式(I)的化合物; 含有这些组合物; 和使用这些衍生物或组合物的包含它们的防治不希望的植物。

    SUBSTITUTED 4-BENZOYL-PYRAZOLES
    26.
    发明申请
    SUBSTITUTED 4-BENZOYL-PYRAZOLES 审中-公开
    取代的4- Benzoylpyrazoles

    公开(公告)号:WO1998029392A1

    公开(公告)日:1998-07-09

    申请号:PCT/EP1997007210

    申请日:1997-12-19

    CPC classification number: A01N43/56 C07D231/24

    Abstract: The invention concerns 4-benzoyl-pyrazoles of formula (I), in which the variables have the following meanings: R , R stand for hydrogen, nitro, halogen, cyano, rhodano, alkyl, halogen alkyl, alkoxyalkyl, alkenyl, alkinyl, -OR , -OCOR , -OSO2R , -SH, -S(O)nR , -SO2OR , -SO2NR R , -NR SO2R or -NR COR ; R stands for hydrogen, cyano, alkyl, halogen alkyl, -OR , -SR or -NR R ; R stands for hydrogen, optionally substituted alkyl, cycloalkyl, alkenyl, cycloalkenyl, alkinyl, -COR , -CO2R , -COSR or -CONR R ; X stands for oxygen or NR ; n equals 0, 1 or 2; R stands for hydrogen, alkyl, halogen alkyl, alkoxyalkyl, alkenyl or alkinyl; R stands for alkyl or halogen alkyl; R stands for alkyl, halogen alkyl, alkoxyalkyl, alkenyl or alkinyl; R stands for hydrogen or alkyl; R stands for alkyl, alkenyl, alkinyl, phenyl or benzyl; R stands for alkyl, halogen alkyl, alkenyl or alkinyl; Q stands for optionally substituted pyrazol linked in position 4. Also disclosed are the salts of these compounds useful in agriculture; processes and intermediate products for preparing the compounds of formula (I), agents containing the same and the use of these derivatives or agents containing the same for controlling undesirable plants.

    Abstract translation: 本发明涉及式(I),其中各变量具有以下含义的4-苯甲酰基吡唑,R <1>,R <2>为氢,硝基,卤素,氰基,氰硫基,烷基,卤代烷基,烷氧基烷基,烯基,炔 ,-OR <5>,-OCOR <6>,-OSO 2 R <6>,-SH,-S(O)NR <7>,-SO 2 OR <5>,-SO 2 <5> - [R <8>,-NR <8> SO 2 <6>或NR <8> COR <6>; [R <3>是氢,氰基,烷基,卤代烷基,-OR <7>,-SR <7>,或-NR <7> - [R <10>; [R <4>为氢,任选取代的烷基,环烷基,烯基,环烯基,炔基,-COR <9>,-CO 2 R <9>,-COSR <9>或-CONR <8> - [R <9>; X是氧或NR <8>; n为0,1或2; [R <5>是氢,烷基,卤代烷基,烷氧基烷基,链烯基或炔基; [R <6>是烷基或卤代烷基; [R <7>是烷基,卤代烷基,烷氧基烷基,烯基或炔基; [R <8>是氢或烷基; [R <9>是烷基,烯基,炔基,苯基或苄基; [R <10>为烷基,卤代烷基,链烯基或炔基; Q为任选取代的吡唑中的4位被链接; 及其可农用盐; 的方法和中间体用于制备式(I)的化合物; 含有这些组合物; 和使用这些衍生物或组合物的包含它们的防治不希望的植物。

    SUBSTITUTED 2-BENZOYL-CYCLOHEXAN-1,3-DIONES WITH HERBICIDAL EFFECT
    27.
    发明申请
    SUBSTITUTED 2-BENZOYL-CYCLOHEXAN-1,3-DIONES WITH HERBICIDAL EFFECT 审中-公开
    取代的2-苯甲酰基环己烷-1,3-二酮与除草活性

    公开(公告)号:WO1998029384A1

    公开(公告)日:1998-07-09

    申请号:PCT/EP1997007214

    申请日:1997-12-19

    Abstract: The invention concerns 2-benzoyl-cyclohexan-1,3-diones of formula (I), in which R , R stand for hydrogen, nitro, halogen, cyano, rhodano, alkyl, halogen alkyl, alkoxyalkyl, alkenyl, alkinyl, -OR , -OCOR , -OSO2R , -SH, -S(O)nR , -SO2OR , -SO2NR R , -NR SO2R or -NR COR ; R stands for hydrogen, cyano, alkyl, halogen alkyl, -OR , -SR or -NR R ; R stands for hydrogen, optionally substituted alkyl, cycloalkyl, alkenyl, cycloalkenyl, alkinyl, -COR , -CO2R , -COSR or -CONR R ; X stands for oxygen or NR ; n equals 0, 1 or 2; R stands for hydrogen, alkyl, halogen alkyl, alkoxyalkyl, alkenyl or alkinyl; R stands for alkyl or halogen alkyl; R stands for alkyl, halogen alkyl, alkoxyalkyl, alkenyl or alkinyl; R stands for hydrogen or alkyl; R stands for alkyl, alkenyl, alkinyl, phenyl or benzyl; R stands for alkyl, halogen alkyl, alkenyl or alkinyl; Q stands for an optionally substituted cyclohexan-1,3-dione ring linked in position 2. Also disclosed are the salts of these compounds useful in agriculture; processes and intermediate products for preparing the compounds of formula (I), agents containing the same and the use of these derivatives or agents containing the same for controlling undesirable plants.

    Abstract translation: 本发明涉及式(I)的2-苯甲酰基环己烷-1,3-二酮,其中R <1>,R <2>为氢,硝基,卤素,氰基,氰硫基,烷基,卤代烷基,烷氧基烷基,烯基,炔基, -OR <5>,-OCOR <6>,-OSO 2 R <6>,-SH,-S(O)NR <7>,-SO 2 OR <5>,-SO 2 <5> - [R <8>,-NR < 8> SO 2 <6>或NR <8> COR <6>; [R <3>是氢,氰基,烷基,卤代烷基,-OR <7>,-SR <7>,或-NR <7> - [R <10>; [R <4>为氢,任选取代的烷基,环烷基,烯基,环烯基,炔基,-COR <9>,-CO 2 R <9>,-COSR <9>或-CONR <8> - [R <9>; X是氧或NR <8>; n为0,1或2; [R <5>是氢,烷基,卤代烷基,烷氧基烷基,链烯基或炔基; [R <6>是烷基或卤代烷基; [R <7>是烷基,卤代烷基,烷氧基烷基,烯基或炔基; [R <8>是氢或烷基; [R <9>是烷基,烯基,炔基,苯基或苄基; [R <10>为烷基,卤代烷基,链烯基或炔基; Q在2位上任选取代的联环己烷-1,3-二酮环; 及其可农用盐; 的方法和中间体用于制备式(I)的化合物; 含有这些组合物; 和使用这些衍生物或组合物的包含它们的防治不希望的植物。

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