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    Pigments based on LiSbO3 and LiNbO3 related structures
    22.
    发明授权
    Pigments based on LiSbO3 and LiNbO3 related structures 有权

    公开(公告)号：US10202510B2

    公开(公告)日：2019-02-12

    申请号：US14929949

    申请日：2015-11-02

    Applicant: The Shepherd Color Company

    Inventor： William M. Yuhasz

    IPC: C09C1/00 ,  C09C1/36 ,  C01G30/02 ,  C01G33/00 ,  C01G35/00 ,  C01G51/00 ,  C04B28/02 ,  C04B14/30 ,  C01G30/00 ,  C08K3/24 ,  C08K9/02 ,  C04B103/54

    Abstract: The present invention involves pigments derived from compounds with the LiSbO3-type or LiNbO3-type structures. These compounds possess the following formulations M1M5Z3, M1M2M4M5Z6, M1M32M5Z6, M1M2M3M6Z6, M12M4M6Z6, M1M5M6Z6, or a combination thereof. The cation M1 represents an element with a valence of +1 or a mixture thereof, the cation M2 represents an element with a valence of +2 or a mixture thereof, the cation M3 represents an element with a valence of +3 or a mixture thereof, the cation M4 represents an element with a valence of +4 or a mixture thereof, the cation M5 represents an element with a valence of +5 or a mixture thereof, and the cation M6 represents an element with a valence of +6 or a mixture thereof. The cation M is selected from H, Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Fe, Ru, Co, Ni, Cu, Ag, Zn, B, Al, Ga, In, Si, Ge, Sn, P, Sb, or Te. The anion Z is selected from N, O, S, Se, Cl, F, hydroxide ion or a mixture thereof. Along with the elements mentioned above vacancies may also reside on the M or Z sites of the above formulations such that the structural type is retained. The above formula may also include M dopant additions below 20 atomic %, where the dopant is selected from H, Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Fe, Ru, Co, Ni, Cu, Ag, Zn, B, Al, Ga, In, Si, Ge, Sn, P, Sb, Bi, Te, or mixtures thereof.

    PIGMENTS BASED ON LiSbO3 AND LiNbO3 RELATED STRUCTURES
    24.
    发明申请
    PIGMENTS BASED ON LiSbO3 AND LiNbO3 RELATED STRUCTURES 审中-公开

    公开(公告)号：US20190203053A1

    公开(公告)日：2019-07-04

    申请号：US16225574

    申请日：2018-12-19

    Applicant: The Shepherd Color Company

    Inventor： William M. Yuhasz

    IPC: C09C1/00 ,  C01G51/00 ,  C09C3/04 ,  C09C1/36 ,  C09C1/62

    CPC classification number: C09C1/0096 ,  C01G51/42 ,  C01P2002/52 ,  C01P2002/72 ,  C01P2002/76 ,  C01P2002/77 ,  C01P2002/84 ,  C01P2004/51 ,  C01P2004/61 ,  C01P2006/62 ,  C01P2006/63 ,  C01P2006/64 ,  C01P2006/66 ,  C09C1/3607 ,  C09C1/627 ,  C09C3/041 ,  C09D7/61

    Abstract: The present invention involves pigments derived from compounds with the LiSbO3-type or LiNbO3-type structures. These compounds possess the following formulations M1M5Z3, M1M2M4M5Z6, M1M32M5Z6, M1M2M3M6Z6, M12M4M6Z6, M1M5M6Z6, or a combination thereof. The cation M1 represents an element with a valence of +1 or a mixture thereof, the cation M2 represents an element with a valence of +2 or a mixture thereof, the cation M3 represents an element with a valence of +3 or a mixture thereof, the cation M4 represents an element with a valence of +4 or a mixture thereof, the cation M5 represents an element with a valence of +5 or a mixture thereof, and the cation M6 represents an element with a valence of +6 or a mixture thereof. The cation M is selected from H, Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Fe, Ru, Co, Ni, Cu, Ag, Zn, B, Al, Ga, In, Si, Ge, Sn, P, Sb, or Te. The anion Z is selected from N, O, S, Se, Cl, F, hydroxide ion or a mixture thereof. Along with the elements mentioned above vacancies may also reside on the M or Z sites of the above formulations such that the structural type is retained. The above formula may also include M dopant additions below 20 atomic %, where the dopant is selected from H, Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Fe, Ru, Co, Ni, Cu, Ag, Zn, B, Al, Ga, In, Si, Ge, Sn, P, Sb, Bi, Te, or mixtures thereof.

    PIGMENTS BASED ON LiSbO3 AND LiNbO3 RELATED STRUCTURES
    26.
    发明申请
    PIGMENTS BASED ON LiSbO3 AND LiNbO3 RELATED STRUCTURES 审中-公开
    基于LiSbO3和LiNbO3的颜料相关结构

    公开(公告)号：US20160122548A1

    公开(公告)日：2016-05-05

    申请号：US14929949

    申请日：2015-11-02

    Applicant: The Shepherd Color Company

    Inventor： William M. Yuhasz

    IPC: C09C1/00 ,  C09C1/36

    CPC classification number: C09C1/0096 ,  C01G30/002 ,  C01G30/026 ,  C01G33/006 ,  C01G35/006 ,  C01G51/006 ,  C01P2002/52 ,  C01P2002/72 ,  C01P2002/76 ,  C01P2002/77 ,  C01P2002/80 ,  C01P2002/84 ,  C01P2004/51 ,  C01P2004/61 ,  C01P2006/62 ,  C01P2006/63 ,  C01P2006/64 ,  C01P2006/65 ,  C01P2006/66 ,  C04B14/30 ,  C04B28/02 ,  C04B2103/54 ,  C08K3/24 ,  C08K9/02 ,  C09C1/00 ,  C09C1/36

    Abstract: The present invention involves pigments derived from compounds with the LiSbO3-type or LiNbO3-type structures. These compounds possess the following formulations M1M5Z3, M1M2M4M5Z6, M1M32M5Z6, M1M2M3M6Z6, M12M4M6Z6, M1M5M6Z6, or a combination thereof. The cation M1 represents an element with a valence of +1 or a mixture thereof, the cation M2 represents an element with a valence of +2 or a mixture thereof, the cation M3 represents an element with a valence of +3 or a mixture thereof, the cation M4 represents an element with a valence of +4 or a mixture thereof, the cation M5 represents an element with a valence of +5 or a mixture thereof, and the cation M6 represents an element with a valence of +6 or a mixture thereof. The cation M is selected from H, Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Fe, Ru, Co, Ni, Cu, Ag, Zn, B, Al, Ga, In, Si, Ge, Sn, P, Sb, or Te. The anion Z is selected from N, O, S, Se, Cl, F, hydroxide ion or a mixture thereof. Along with the elements mentioned above vacancies may also reside on the M or Z sites of the above formulations such that the structural type is retained. The above formula may also include M dopant additions below 20 atomic %, where the dopant is selected from H, Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Fe, Ru, Co, Ni, Cu, Ag, Zn, B, Al, Ga, In, Si, Ge, Sn, P, Sb, Bi, Te, or mixtures thereof.

    Abstract translation: 本发明涉及衍生自具有LiSbO 3型或LiNbO 3型结构的化合物的颜料。 这些化合物具有以下配方M1M5Z3，M1M2M4M5Z6，M1M32M5Z6，M1M2M3M6Z6，M12M4M6Z6，M1M5M6Z6或其组合。 阳离子M1表示价数为+1的元素或其混合物，阳离子M2表示价数为+2的元素或其混合物，阳离子M3表示价数为+3的元素或其混合物 阳离子M4表示价数为+4的元素或其混合物，阳离子M5表示价数为+5的元素或其混合物，阳离子M6表示价数为+6的元素或 的混合物。 阳离子M选自H，Li，Na，K，Rb，Cs，Mg，Ca，Sr，Ba，Sc，Y，La，Ce，Pr，Nd，Sm，Eu，Gd，Tb，Dy， Er，Tm，Yb，Lu，Ti，Zr，Hf，V，Nb，Ta，Cr，Mo，W，Mn，Fe，Ru，Co，Ni，Cu，Ag，Zn，B，Al， Si，Ge，Sn，P，Sb或Te。 阴离子Z选自N，O，S，Se，Cl，F，氢氧根离子或其混合物。 与上述元素一起，空位也可以存在于上述配方的M或Z位点上，从而保留了结构类型。 上述公式还可以包括低于20原子％的M掺杂剂添加剂，其中掺杂剂选自H，Li，Na，K，Rb，Cs，Mg，Ca，Sr，Ba，Sc，Y，La，Ce，Pr， Nd，Sm，Eu，Gd，Tb，Dy，Ho，Er，Tm，Yb，Lu，Ti，Zr，Hf，V，Nb，Ta，Cr，Mo，W，Mn，Fe，Ru，Co，Ni， Cu，Ag，Zn，B，Al，Ga，In，Si，Ge，Sn，P，Sb，Bi，Te或其混合物。

    CORE-SHELL COMPOSITE INORGANIC METAL OXIDES AND METHOD OF PREPARING FOR PREVENTION OF THERMAL OXIDATIVE DEGRADATION IN POLYMER AND RESIN COMPOSITIONS
    28.
    发明申请
    CORE-SHELL COMPOSITE INORGANIC METAL OXIDES AND METHOD OF PREPARING FOR PREVENTION OF THERMAL OXIDATIVE DEGRADATION IN POLYMER AND RESIN COMPOSITIONS 有权
    核壳复合无机金属氧化物及其制备方法，用于防止聚合物和树脂组合物中的热氧化降解

    公开(公告)号：US20150291778A1

    公开(公告)日：2015-10-15

    申请号：US14665260

    申请日：2015-03-23

    Applicant: The Shepherd Color Company ,  LPKF Laser & Electronics AG

    Inventor： Michael D. MUSICK ,  David ZIEMNIK ,  James P. WHITE ,  Robin Alexander KRÜGER ,  Bernd RÖSENER ,  Malte Sebastian FENGLER

    IPC: C08K9/10 ,  C08L55/02 ,  B23K26/00 ,  C08L69/00

    CPC classification number: C08K9/10 ,  C01P2002/70 ,  C01P2004/04 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2004/84 ,  C08L55/02 ,  C08L69/00 ,  C09C3/063 ,  H05K3/185 ,  H05K2201/0236 ,  H05K2203/107

    Abstract: This invention relates to products of aqueous and other chemical synthetic routes for encapsulation of a core material with an inorganic shell and finished compositions of a core-shell particulate material for application in thermoplastic, thermoset, and coatings resins prior to compounding or application or subsequent thermal processing steps. Disclosed is a composition of particles containing a shell of inorganic oxides or mixed-metal inorganic oxides and a core material of complex inorganic colored pigment, laser direct structuring additives, laser marking, or other beneficial metal oxides, metal compounds, or mixed-metal oxide materials, wherein the shell material is comprised of any single oxide or combination of oxides is taught. Preferred elements of composition for the shell are oxides and silicates of B, Ni, Zn, Al, Zr, Si, Sn, Bi, W, Mo, Cr, Mg, Mn, Ce, Ti, and Ba (or mixtures thereof). Applications may include, but are not limited to, coatings or plastic articles or materials for molded interconnect devices, durable goods, housings, assemblies, devices, and articles that are to be exposed to additional thermal processing. The resulting core-shell materials function in plastic and coatings formulations by minimizing or eliminating detrimental interactions with the resins and metal containing additives resulting in loss of mechanical properties.

    Abstract translation: 本发明涉及用于将芯材料与无机壳包封的水性和其它化学合成路线的产品以及用于在复合或应用或后续热处理之前用于热塑性，热固性和涂料树脂的芯 - 壳颗粒材料的成品组合物 处理步骤。 公开了包含无机氧化物或混合金属无机氧化物的壳的颗粒和复合无机着色颜料的核心材料，激光直接结构化添加剂，激光标记或其它有益金属氧化物，金属化合物或混合金属氧化物的组合物 材料，其中壳材料由任何单一氧化物或氧化物的组合组成。 壳的组成的优选元素是B，Ni，Zn，Al，Zr，Si，Sn，Bi，W，Mo，Cr，Mg，Mn，Ce，Ti和Ba（或其混合物）的氧化物和硅酸盐。 应用可以包括但不限于用于模制的互连装置，耐用品，外壳，组件，装置和待暴露于额外热处理的制品的涂层或塑料制品或材料。 所得的核 - 壳材料通过最小化或消除与树脂和含金属的添加剂的有害相互作用导致机械性能的损失，在塑料和涂料配方中起作用。

    PIGMENTS BASED ON LiSbO3 AND LiNbO3 RELATED STRUCTURES
    29.
    发明公开
    PIGMENTS BASED ON LiSbO3 AND LiNbO3 RELATED STRUCTURES 审中-公开
    基于LiSbO3和LiNbO3相关结构的颜料

    公开(公告)号：EP3224201A1

    公开(公告)日：2017-10-04

    申请号：EP15795083.3

    申请日：2015-11-02

    Applicant: The Shepherd Color Company

    Inventor： YUHASZ, William, M.

    IPC: C01G30/00 ,  C01G33/00 ,  C01G35/00 ,  C01G51/00 ,  C09C1/00 ,  C09C1/36 ,  C01G30/02 ,  C08K3/22 ,  C08K3/24

    CPC classification number: C09C1/0096 ,  C01G30/002 ,  C01G30/026 ,  C01G33/006 ,  C01G35/006 ,  C01G51/006 ,  C01P2002/52 ,  C01P2002/72 ,  C01P2002/76 ,  C01P2002/77 ,  C01P2002/80 ,  C01P2002/84 ,  C01P2004/51 ,  C01P2004/61 ,  C01P2006/62 ,  C01P2006/63 ,  C01P2006/64 ,  C01P2006/65 ,  C01P2006/66 ,  C04B14/30 ,  C04B28/02 ,  C04B2103/54 ,  C08K3/24 ,  C08K9/02 ,  C09C1/00 ,  C09C1/36

    Abstract: The present invention involves pigments derived from compounds with the LiSb0
    3 -type or LiNb0
    3 -type structures. These compounds possess the following formulations M
    1 M
    5 Z
    3 , M
    1 M
    2 M
    4 M
    5 Z
    6 , M
    1 M
    3
    2 M
    1 M
    2 M
    3 M
    6 Z
    6 , M
    1
    2 M
    4 M
    6 Z
    6 , M
    1 M
    5 M
    6 Z
    6 , or a combination thereof. The cation M
    1 represents an element with a valence of +1 or a mixture thereof, the cation M
    2 represents an element with a valence of +2 or a mixture thereof, the cation M
    3 represents an element with a valence of +3 or a mixture thereof, the cation M
    4 represents an element with a valence of +4 or a mixture thereof, the cation M
    5 represents an element with a valence of +5 or a mixture thereof, and the cation M
    6 represents an element with a valence of +6 or a mixture thereof. The cation M is selected from H, Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Fe, Ru, Co, Ni, Cu, Ag, Zn, B, Al, Ga, In, Si, Ge, Sn, P, Sb, or Te. The anion Z is selected from N, O, S, Se, CI, F, hydroxide ion or a mixture thereof. Along with the elements mentioned above vacancies may also reside on the M or Z sites of the above formulations such that the structural type is retained. The above formula may also include M dopant additions below 20 atomic %, where the dopant is selected from H, Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Fe, Ru, Co, Ni, Cu, Ag, Zn, B, Al, Ga, In, Si, Ge, Sn, P, Sb, Bi, Te, or mixtures thereof.

    Abstract translation: 本发明涉及源自具有LiSbO 3型或LiNbO 3型结构的化合物的颜料。 这些化合物具有下述配方M1M5Z3，M1M2M4M5Z6，M1M32M5Z6，M1M2M3M6Z6，M12M4M6Z6，M1M5M6Z6，或它们的组合。 阳离子M1表示+1价的元素或其混合物，阳离子M2表示+2价的元素或其混合物，阳离子M3表示+3价的元素或其混合物 中，阳离子M4代表具有+4价或它们的混合物的元素，阳离子M5表示具有5价或它们的混合物的元素，并且所述阳离子M6表示具有6或一价的元素 其混合物。 阳离子M选自H，Li，Na，K，Rb，Cs，Mg，Ca，Sr，Ba，Sc，Y，La，Ce，Pr，Nd，Sm，Eu，Gd，Tb，Dy， Er，Tm，Yb，Lu，Ti，Zr，Hf，V，Nb，Ta，Cr，Mo，W，Mn，Fe，Ru，Co，Ni，Cu，Ag，Zn，B，Al，Ga， Si，Ge，Sn，P，Sb或Te。 阴离子Z选自N，O，S，Se，Cl，F，氢氧根离子或其混合物。 除了上面提到的元素外，空位也可以位于上述配方的M或Z位置，从而保留结构类型。 上述公式还可以包括低于20原子％的M掺杂剂添加，其中掺杂剂选自H，Li，Na，K，Rb，Cs，Mg，Ca，Sr，Ba，Sc，Y，La，Ce，Pr， Nd，Sm，Eu，Gd，Tb，Dy，Ho，Er，Tm，Yb，Lu，Ti，Zr，Hf，V，Nb，Ta，Cr，Mo，W，Mn，Fe，Ru，Co，Ni， Cu，Ag，Zn，B，Al，Ga，In，Si，Ge，Sn，P，Sb，Bi，Te或其混合物。

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