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    METHOD FOR INHIBITING SCORCH IN CROSSLINKABLE COMPOSITIONS
    21.
    发明申请
    METHOD FOR INHIBITING SCORCH IN CROSSLINKABLE COMPOSITIONS 审中-公开
    用于抑制可交联组合物中的分光光度的方法

    公开(公告)号：WO2009149001A1

    公开(公告)日：2009-12-10

    申请号：PCT/US2009/045808

    申请日：2009-06-01

    Applicant: UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY LLC ,  PERSON, Timothy J. ,  EATON, Robert F. ,  COGEN, Jeffrey M.

    Inventor： PERSON, Timothy J. ,  EATON, Robert F. ,  COGEN, Jeffrey M.

    IPC: C08K5/00

    CPC classification number: C08K5/32 ,  C08K5/3435

    Abstract: Methods and compositions for controlling polymer crosslinking are provided. The crosslinking composition includes a crosslinkable polymer, a free radical initiator, and an amine. The amine is an alkoxyaminc or a hydroxylamine. The crosslinking composition is heated to a processing temperature. The amine undergoes a cleavage reaction at or below the processor temperature to produce nitroxyl radicals in situ . The tree radical initiator forms polymer radicals at the processing temperature. The nitroxyl radicals formed in situ cap the polymer radicals to control crosslinking.

    Abstract translation: 提供了用于控制聚合物交联的方法和组合物。 交联组合物包括可交联聚合物，自由基引发剂和胺。 胺是烷氧基氨基或羟胺。 将交联组合物加热至加工温度。 胺在处理器温度或低于处理器温度下经历裂解反应，以原位产生硝酰自由基。 树自由基引发剂在加工温度下形成聚合物自由基。 形成的硝酰自由基原位盖住聚合物自由基以控制交联。

    GAS PHASE POLYMERIZATION AND METHOD OF CONTROLLING SAME
    25.
    发明申请
    GAS PHASE POLYMERIZATION AND METHOD OF CONTROLLING SAME 审中-公开
    气相聚合及其控制方法

    公开(公告)号：WO2004111097A1

    公开(公告)日：2004-12-23

    申请号：PCT/US2004/016549

    申请日：2004-05-26

    Applicant: UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY CORPORATION ,  PARRISH, John, R. ,  LAMBERT, Glenn, A. ,  THOMAS, Daniel, N.

    Inventor： PARRISH, John, R. ,  LAMBERT, Glenn, A. ,  THOMAS, Daniel, N.

    IPC: C08F10/00

    CPC classification number: C08F10/00 ,  C08F210/16 ,  C08F2400/02 ,  Y02P20/582 ,  Y10S526/901 ,  C08F2/00 ,  C08F2/34 ,  C08F210/14

    Abstract: A process for controlling a continuous gas phase exothermic process in a reactor comprising: (i) effecting a gas phase exothermic reaction under a set of operating conditions in the presence of a cooling agent, the cooling agent having a pre-selected concentration and feed rate of an induced cooling agent; (ii) determining a maximum production rate (I) without regard to limitations due to the cooling agent under the operating conditions; (iii) determining a maximum production rate (II) with regard to limitations due to the cooling agent under the operating conditions; (iv) calculating an optimal concentration of the induced cooling agent such that the difference between (I) and (II) is minimized; and (v) adjusting the feed rate of the induced cooling agent to achieve the concentration value calculated in (iv).

    Abstract translation: 一种用于控制反应器中的连续气相放热过程的方法，包括：（i）在冷却剂存在下在一组操作条件下进行气相放热反应，所述冷却剂具有预先选择的浓度和进料速率 的诱导冷却剂; （ii）确定最大生产率（I），而不考虑在操作条件下由于冷却剂的限制; （iii）确定在运行条件下由冷却剂引起的限制的最大生产率（II）; （iv）计算诱导的冷却剂的最佳浓度，使得（I）和（II）之间的差异最小化; 和（v）调节诱导的冷却剂的进料速率以达到（iv）中计算的浓度值。

    BIS-CHELATING LIGAND AND USE THEREOF IN CARBONYLATION PROCESSES
    26.
    发明申请
    BIS-CHELATING LIGAND AND USE THEREOF IN CARBONYLATION PROCESSES 审中-公开
    双向排列配对及其在碳化工艺中的应用

    公开(公告)号：WO2004035595A1

    公开(公告)日：2004-04-29

    申请号：PCT/US2003/030380

    申请日：2003-09-26

    Applicant: UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY CORPORATION ,  PENG, Wei-Jun ,  HOLLADAY, Jonathon, E.

    Inventor： PENG, Wei-Jun ,  HOLLADAY, Jonathon, E.

    IPC: C07F9/6574

    CPC classification number: C07F15/008 ,  B01J31/1608 ,  B01J31/185 ,  B01J2231/321 ,  B01J2531/80 ,  B01J2531/821 ,  B01J2531/822 ,  B01J2531/827 ,  B01J2531/845 ,  C07C45/50 ,  C07F9/65746 ,  C07C47/42

    Abstract: A novel bis-chelating composition characterized by formula I: wherein M is a Group VB element; RI and R2 are each independently selected from hydrogen and monovalent hydrocarbyl radicals; or R1 and R2 are bonded together to form a diradical; or one of RI or R2 is hydrogen or a monovalent hydrocarbyl radical, while the other of R1 or R2 is a hydrocarbyl radical bonded to an atom in Ar; wherein Ar is selected from 1,2-arylenes; Q is selected from 1,2-arylenes, 2,2'-bisarylenes and alkyl diradicals; and W is selected from II, III, IV, or V: wherein M is as defined hereinbefore; each R is independently selected from hydrogen and monovalent hydrocarbyl radicals; X is selected from alkyl and aryl diradicals; Ar 1 and Ar 2 are each independently selected from 1,2-arylenes; Ar 3 and Ar 4 are each independently selected from monovalent aryl radicals; and n in formula IV is 0 or 1. The composition finds utility as a ligand in catalysts for carbonylation processes.

    Abstract translation: 特征在于式I的新型双螯合组合物：其中M是VB族元素; R 1和R 2各自独立地选自氢和一价烃基; 或者R 1和R 2结合在一起形成双基; 或R 1或R 2中的一个为氢或一价烃基，而R 1或R 2中的另一个为与Ar中的原子键合的烃基; 其中Ar选自1,2-亚芳基; Q选自1,2-亚芳基，2,2'-双芳烯和烷基双基; W选自II，III，IV或V：其中M如上所定义; 每个R独立地选自氢和一价烃基; X选自烷基和芳基双基; Ar 1和Ar 2各自独立地选自1,2-亚芳基; Ar 3和Ar 4各自独立地选自单价芳基; 式IV中的n为0或1.该组合物用作用于羰基化方法的催化剂中的配体。

    SOLID, PARTICULATED, SPRAY DRIED, HETEROGENOUS CATALYST COMPOSITION
    27.
    发明申请
    SOLID, PARTICULATED, SPRAY DRIED, HETEROGENOUS CATALYST COMPOSITION 审中-公开
    固体，颗粒状，喷雾干燥，异构催化剂组合物

    公开(公告)号：WO2003102037A1

    公开(公告)日：2003-12-11

    申请号：PCT/US2003/016266

    申请日：2003-05-22

    Applicant: UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY CORPORATION ,  COOK, Jessica, A. ,  SCHOEB-WOLTERS, Ann Marie

    Inventor： COOK, Jessica, A. ,  SCHOEB-WOLTERS, Ann Marie

    IPC: C08F10/00

    CPC classification number: C08F10/06 ,  C08F4/65912 ,  C08F4/65925 ,  C08F210/16 ,  C08F4/65904 ,  C08F210/14 ,  C08F2500/12

    Abstract: A solid, particulated, heterogeneous, spray-dried, catalyst composition for the polymerization of addition polymerizable monomers comprising: a) a Group 4 metallocene compound; b) a solid Group 4 metal-magnesium halide complex comprising moieties of at least magnesium, a Group 4 transition metal, and a halide; c) finely divided, inert filler, and d) an optional binder capable of joining components a) and b) and optionally c) into a particulated, heterogeneous, agglomerate without adversely affecting the catalytic properties thereof, and a method for the manufacture thereof comprising forming a mixture of the above composition in a liquid diluent and spray-drying the same to remove diluent.

    Abstract translation: 一种用于聚合可加聚单体的固体，颗粒状，异相，喷雾干燥的催化剂组合物，其包含：a）第4族茂金属化合物; b）固体第4族金属 - 卤化镁配合物，其包含至少镁，第4族过渡金属和卤化物的部分; c）细分散的惰性填料，和d）能够将组分a）和b）和任选地c）连接成颗粒状，非均匀的附聚物而不会不利地影响其催化性能的任选的粘合剂及其制备方法，包括 在液体稀释剂中形成上述组合物的混合物并将其喷雾干燥以除去稀释剂。

    SEMICONDUCTING SHIELD COMPOSITIONS
    29.
    发明申请
    SEMICONDUCTING SHIELD COMPOSITIONS 审中-公开
    半导体屏蔽组合物

    公开(公告)号：WO2002073630A2

    公开(公告)日：2002-09-19

    申请号：PCT/US2002/006044

    申请日：2002-02-28

    Applicant: UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY CORPORATION

    Inventor： HAN, Suh, Joon ,  LEE, Wei-Kuo

    IPC: H01B1/24

    CPC classification number: H01B3/441 ,  C08L23/08 ,  C08L23/0846 ,  C08L23/16 ,  C08L2312/00 ,  H01B1/24 ,  C08L2666/04

    Abstract: A conducting polymer composite comprising: (i) a phase I material consisting essentially of a polymer copolymer of ethylene and an unsaturated ester having 4 to 20 carbon atoms, said copolymer having a crystallinity of 0 to about 30 percent as determined by differential scanning calorimetry analysis and having a melt viscosity η I ; (ii) a phase II material having a crystallinity of 0 to about 30 percent as determined by differential scanning calorimetry analysis and having a melt viscosity of η II , said phase II material consisting essentially of (A) a non-polar copolymer of ethylene, an alpha-olefin having 3 to 12 carbon atoms, and, optionally, a diene, or (B) a non-polar elastomer, either of which, when mixed with phase I material, will not enter into a completely homogeneous state, but is compatible with the phase I material; and (iii) a conducting filler material dispersed in the phase I material and/or the phase II in an amount sufficient to be equal to or greater than the amount required to generate a continuous conducting network in the phase I and phase II materials, with the proviso that the phase I and phase II materials, in the molten state, have the following relationship: (η I ÷η II )x(V II ÷V I )=0.5 to 2.0 wherein V I and V II are the volume fractions of the phase I and phase II materials, respectively, and V I +V II =1.

    Abstract translation: 一种导电聚合物复合材料，其包含：（i）基本上由乙烯和具有4至20个碳原子的不饱和酯的聚合物共聚物组成的相I材料，所述共聚物通过差示扫描量热法分析测定的结晶度为0至约30％ 并具有熔体粘度ηI; （ii）通过差示扫描量热分析测定的具有0至约30％的结晶度的II相材料，其熔体粘度为ηII，所述II相材料基本上由（A）乙烯的非极性共聚物， 具有3至12个碳原子的α-烯烃，和任选的二烯，或（B）非极性弹性体，当与I相材料混合时，它们不会进入完全均匀的状态，而是相容的 与I相材料; 和（iii）分散在I相材料和/或II相中的导电填料，其量足以等于或大于在I相和II相材料中产生连续导电网络所需的量， 条件是熔融状态下的相I和相II材料具有以下关系：（ηI÷ηII）x（VII÷VI）= 0.5至2.0其中VI和VII是相I和相的体积分数 II材料，VI + VII = 1。

    SEPARATION OF REACTION PRODUCTS CONTAINING ORGANOPHOSPHORUS COMPLEXES
    30.
    发明申请
    SEPARATION OF REACTION PRODUCTS CONTAINING ORGANOPHOSPHORUS COMPLEXES 审中-公开

    公开(公告)号：WO2001068247A3

    公开(公告)日：2001-09-20

    申请号：PCT/US2001/040286

    申请日：2001-03-14

    Applicant: UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY CORPORATION

    Inventor： KANEL, Jeffrey, Scott ,  BRYANT, David, Robert ,  ROESCH, Brian, Michael ,  PHILLIPS, Ailene, Gardner

    IPC: C07B63/00

    Abstract: This invention relates to a process for separating one or more products from a reaction product fluid comprising a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, said one or more products, one or more nonpolar reaction solvents and one or more polar reaction solvents, in which said reaction product fluid exhibits phase behavior depicted by Fig. 1, wherein said process comprises (1) supplying said reaction product fluid from a reaction zone to a separation zone, (2) controlling concentration of said one or more nonpolar reaction solvents and said one or more polar reaction solvents, temperature and pressure in said separation zone sufficient to obtain by phase separation two immiscible liquid phases depicted by regions 2, 4 and 6 of Fig. 1 comprising a polar phase and a nonpolar phase and to prevent or minimize formation of three immiscible liquid phases depicted by region 5 of Fig. 1 and one homogeneous liquid phase depicted by regions 1, 3 and 7 of Fig. 1, and (3) recovering said polar phase from said nonpolar phase or said nonpolar phase from said polar phase.

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