公开(公告)号：CA2175271A1

公开(公告)日：1996-11-10

申请号：CA2175271

申请日：1996-04-29

Applicant: BREITSCHEIDEL BORIS ,  POLANEK PETER ,  VOIT GUIDO ,  WITZEL TOM ,  LINDEN GERD ,  HESSE MICHAEL

Inventor： BREITSCHEIDEL BORIS ,  POLANEK PETER ,  VOIT GUIDO ,  WITZEL TOM ,  LINDEN GERD ,  HESSE MICHAEL

IPC: B01J23/78 ,  B01J23/889 ,  B01J27/185 ,  B01J27/187 ,  C07B61/00 ,  C07C209/48 ,  C07C209/52 ,  C07C211/03 ,  B01J23/75 ,  C07C211/36 ,  C07C209/44

Abstract: Cobalt catalysts whose catalytically active composition comprises from 55 to 98 % by weight of cobalt, from 0.2 to 15 % by weight of phosphorus, from 0.2 to 15 % by weight of manganese and from 0.05 to 5 % by weight of alkali metal, calculated as oxide, are prepared by calcining the catalyst composition, reducing it at final temperatures of from 200 to 400.degree. C in a stream of hydrogen and subsequently surface-oxidizing it by treatment in a stream of air at final temperatures of from 20 to 60.degree. C and can be used in a process for hydrogenating organic nitriles and/or imines.

公开(公告)号：CA2175271C

公开(公告)日：2007-06-19

申请号：CA2175271

申请日：1996-04-29

Applicant: BREITSCHEIDEL BORIS ,  POLANEK PETER ,  VOIT GUIDO ,  WITZEL TOM ,  LINDEN GERD ,  HESSE MICHAEL

Inventor： BREITSCHEIDEL BORIS ,  POLANEK PETER ,  VOIT GUIDO ,  WITZEL TOM ,  LINDEN GERD ,  HESSE MICHAEL

IPC: B01J27/187 ,  B01J23/75 ,  B01J23/78 ,  B01J23/889 ,  B01J27/185 ,  C07B61/00 ,  C07C209/44 ,  C07C209/48 ,  C07C209/52 ,  C07C211/03 ,  C07C211/36

Abstract: Cobalt catalysts whose catalytically active composition comprises from 55 to 98 % by weight of cobalt, from 0.2 to 15 % by weight of phosphorus, from 0.2 to 1.5 % by weight of manganese and from 0.05 to 5 % by weight of alkali metal, calculated as oxide, are prepared by calcining the catalyst composition, reducing it at final temperatures of from 200 to 400.degree.C in a stream of hydrogen and subsequently surface-oxidizing it by treatment in a stream of air at final temperatures of from 20 to 60.degree.C and can be used in a process for hydrogenating organic nitriles and/or imines.

公开(公告)号：CA2156576C

公开(公告)日：2004-10-05

申请号：CA2156576

申请日：1995-08-21

Applicant: WITZEL TOM ,  VOIT GUIDO

Inventor： WITZEL TOM ,  VOIT GUIDO

IPC: C07B61/00 ,  C07C209/26 ,  C07C209/48 ,  C07C209/52 ,  C07C211/36 ,  C07C253/30 ,  C07C209/68

Abstract: 3-Aminomethyl-3,5,5-trimethylcyclohexylamine is prepared by reacting 3-cyano-3,5,5-trimethylcyclohexanone with 3-amino-methyl-3,5,5-trimethylcyclohexylamine and subsequently or simultaneously adding ammonia under a hydrogen pressure of from 50 to 300 bar in the presence of a hydrogenation catalyst at from 20 to 150.degree.C, by a process in which the reaction is carried out without removing the water of reaction.

公开(公告)号：CA2255235A1

公开(公告)日：1999-06-18

申请号：CA2255235

申请日：1998-12-15

Applicant: ROS KARL-HEINZ ,  BREITSCHEIDEL BORIS ,  WITZEL TOM ,  VOIT GUIDO ,  LUYKEN HERMANN ,  WAHL PETER

Inventor： ROS KARL-HEINZ ,  BREITSCHEIDEL BORIS ,  WITZEL TOM ,  VOIT GUIDO ,  LUYKEN HERMANN ,  WAHL PETER

IPC: C07C209/26 ,  C07C209/48 ,  C07C209/52 ,  C07C211/36

Abstract: A process for the preparation of 3-aminomethyl-3,5,5-trimethylcyclohexylamine having a cis/trans isomer ratio of at least 70:30 by a) imination of 3-cyano-3,5,5-trimethylcyclohexanone with ammonia in the presence of an imination catalyst at temperatures of from 20.degree. to 150.degr ee.C and pressures of from 1.5 to 30 MPa to form 3-cyano-3,5,5-trimethylcyclohexanone imine followed by b) hydrogenation of the 3-cyano-3,5,5-trimethylcyclohexanone imine in the presence of ammonia over a catalyst containing copper and/or a Group VIII metal at a temperature of from 80.degree. to 160.degree.C and under a pressure o f from 5 to 30 MPa, wherein the catalytic hydrogenation of the 3-cyano-3,5,5-trimethylcyclohexanone imine is carried out in the presence of an acid used in an amount such as to giv e an acid number of from 0.1 to 2, based on 3-cyano-3,5,5-trimethylcyclohexanone used.

公开(公告)号：CA2170555A1

公开(公告)日：1996-09-04

申请号：CA2170555

申请日：1996-02-28

Applicant: VOIT GUIDO ,  WITZEL TOM ,  BREITSCHEIDEL BORIS ,  HARDER WOLFGANG ,  LUYKEN HERMANN ,  PAUL AXEL ,  ROBETA KARL HEINZ ,  WAHL PETER

Inventor： VOIT GUIDO ,  WITZEL TOM ,  BREITSCHEIDEL BORIS ,  HARDER WOLFGANG ,  LUYKEN HERMANN ,  PAUL AXEL ,  ROBETA KARL-HEINZ ,  WAHL PETER

IPC: B01J23/46 ,  B01J23/75 ,  B01J23/755 ,  C07B61/00 ,  C07C209/48 ,  C07C211/36

Abstract: A process for the preparation of 3-aminomethyl-3,5,5-trimethylcyclohexylamine from 3-cyano-3,5,5-trimethyl-cyclohexanone in three spatially separated reaction spaces, which comprises a) reacting the 3-cyano-3,5,5-trimethylcyclohexanone with excess ammonia on acidic metal-oxide catalysts in a first reaction space at from 20 to 150.degree.C and from 50 to 300 bar, b) hydrogenating the resultant reaction products using hydrogen in a second reaction space in the presence of excess ammonia on hydrogenation catalysts, with or without basic components or on neutral or basic supports at from 50 to 100.degree.C and at from 50 to 300 bar, and c) hydrogenating the resultant reaction products in the presence of hydrogen in a third reaction space on hydrogenation catalysts, with or without basic components or on neutral or basic supports at from 110 to 160.degree.C and at from 150 to 300 bar.

公开(公告)号：CA2170555C

公开(公告)日：2006-06-27

申请号：CA2170555

申请日：1996-02-28

Applicant: VOIT GUIDO ,  WITZEL TOM ,  BREITSCHEIDEL BORIS ,  HARDER WOLFGANG ,  LUYKEN HERMANN ,  PAUL AXEL ,  ROS KARL-HEINZ ,  WAHL PETER

Inventor： VOIT GUIDO ,  WITZEL TOM ,  BREITSCHEIDEL BORIS ,  HARDER WOLFGANG ,  LUYKEN HERMANN ,  PAUL AXEL ,  ROS KARL-HEINZ ,  WAHL PETER

IPC: B01J23/46 ,  C07C211/36 ,  B01J23/75 ,  B01J23/755 ,  C07B61/00 ,  C07C209/48

Abstract: A process for the preparation of 3-aminomethyl-3,5,5- trimethylcyclohexylamine from 3-cyano-3,5,5-trimethyl- cyclohexanone in three spatially separated reaction spaces, which comprises a) reacting the 3-cyano-3,5,5-trimethylcyclohexanone with excess ammonia on acidic metal-oxide catalysts in a first reaction space at from 20 to 150.degree.C and from 50 to 300 bar, b) hydrogenating the resultant reaction products using hydrogen in a second reaction space in the presence of excess ammonia on hydrogenation catalysts, with or without basic components or on neutral or basic supports at from 50 to 100.degree.C and at from 50 to 300 bar, and c) hydrogenating the resultant reaction products in the presence of hydrogen in a third reaction space on hydrogenation catalysts, with or without basic components or on neutral or basic supports at from 110 to 160.degree.C and at from 150 to 300 bar.