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公开(公告)号：KR100449881B1
公开(公告)日：2004-09-22
申请号：KR1020010077234
申请日：2001-12-07
Applicant: 제일모직주식회사
IPC: C08L69/00
Abstract: PURPOSE: A thermoplastic resin composition having excellent flame retardant property, heat resistance and mechanical properties which can be used in a computer housing or other office machinery and tools is provided. CONSTITUTION: The flame retardant thermoplastic resin composition comprises 100 parts by weight of a polycarbonate resin, 0.01 to 1 parts by weight of a perfluorinated alkane sulfonate salt, and 0.01 to 1 parts by weight of a sulfone sulfonate salt. The polycarbonate rein has the weight average molecular weight of 10,000 to 200,000. The perfluorinated alkane sulfonate salt is used as a flame retardant. The resin composition may further comprise 0 to 20 parts by weight of conventional additives, such as a lubricant, a nucleating agent, a stabilizer, a reinforcing agent, pigments and the like.
Abstract translation: 目的：提供一种热塑性树脂组合物，它具有优异的阻燃性，耐热性和机械性能，可用于计算机外壳或其它办公机械和工具。 构成：阻燃热塑性树脂组合物包含100重量份聚碳酸酯树脂，0.01-1重量份全氟化烷烃磺酸盐和0.01-1重量份磺酸磺酸盐。 聚碳酸酯树脂具有10,000至200,000的重均分子量。 全氟烷磺酸盐用作阻燃剂。 该树脂组合物可进一步包含0至20重量份的常规添加剂，如润滑剂，成核剂，稳定剂，增强剂，颜料等。
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公开(公告)号：KR100435571B1
公开(公告)日：2004-06-09
申请号：KR1020010043748
申请日：2001-07-20
Applicant: 제일모직주식회사
IPC: C08L69/00
Abstract: PURPOSE: A flame retardant and thermoplastic resin composition is provided, which use as flame retardant mixture of phosphazene compound and phosphoric acid ester morpholide compound, and fiber glass in a suitable range, so that physical property balance such as flame retardant and heat resistant, and mechanical strength is excellent thus enabling the composition to be used for preparing injection molded sheath of computer monitor and the other apparatus. CONSTITUTION: The flame retardant and thermoplastic resin composition comprises (a) 70 to 99 parts by weight of polycarbonate resin represented by formula I; (b) 1 to 30 parts by weight of organic phosphorus compounds consisting of (b1) 5 to 90 wt.% of phosphazene compound selected from linear phosphazene represented by formula II and cyclic phosphazene represented by formula III, wherein R is selected from the group consisting of alkyl, aryl, alkyl substituted aryl, arylalkyl, alkoxy, aryloxyl, amino and hydroxyl, and k is an integer of 0 to 10, and the alkoxy or aryloxy can be substituted by alkyl, aryl, amino or hydroxyl, and (b2) 95 to 10 wt.% of phosphoric acid ester morpholide compound represented by formula IV, wherein x is 1 or 2, R1 is C6-C20 aryl or alkyl substituted C6-C20 aryl, R2 is C6-C30 aryl or alkyl substituted C6-C30 aryl derivatives, n and m are respectively number average polymerization degree and n+m ranges from 0 to 5; (c) 0.05 to 5 parts by weight of fluoride polyolefine resin having average particle size of 0.05 to 1000 μm and density of 1.2 to 2.3 g/cm¬2; and (d) 5 to 15 parts by weight of fiber glass based on 100 parts by weight of the components of (a)+(b)+(c).
Abstract translation: 目的：提供一种阻燃剂和热塑性树脂组合物，其用作磷腈化合物和磷酸酯吗啉化合物的阻燃剂混合物，以及在合适范围内的玻璃纤维，以使得阻燃和耐热等物理性能平衡 机械强度是优异的，从而使得该组合物可用于制备计算机监视器和其他设备的注塑护套。 构成：阻燃热塑性树脂组合物包含（a）70-99重量份由式I表示的聚碳酸酯树脂; （b）1-30重量份的有机磷化合物，所述有机磷化合物由（b1）5-90重量％的选自由式II表示的直链磷腈和由式III表示的环状磷腈的磷腈化合物组成，其中R选自 由烷基，芳基，烷基取代的芳基，芳烷基，烷氧基，芳氧基，氨基和羟基组成，k是0-10的整数，烷氧基或芳氧基可以被烷基，芳基，氨基或羟基取代， ）95-10重量％由式IV表示的磷酸酯吗啉化合物，其中x是1或2，R1是C6-C20芳基或烷基取代的C6-C20芳基，R2是C6-C30芳基或烷基取代的C6- C30芳基衍生物，n和m分别为数均聚合度和0至5的n + m; （c）0.05-5重量份的平均粒径为0.05-1000μm和密度为1.2-2.3g / cm 2的氟化物聚烯烃树脂; （d）基于100重量份的（a）+（b）+（c）的组分，5-15重量份的玻璃纤维。
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公开(公告)号：KR1020040042611A
公开(公告)日：2004-05-20
申请号：KR1020020071170
申请日：2002-11-15
Applicant: 제일모직주식회사
IPC: C08K5/5399
Abstract: PURPOSE: A flame resistant thermoplastic resin composition is provided, to improve flame retardancy, heat resistance and mechanical strength. CONSTITUTION: The composition comprises 100 parts by weight of a thermoplastic polycarbonate base resin; 5-90 wt% of a linear phosphazene represented by the formula I-a or a cyclic phosphazene compound represented by the formula I-b and 10-95 wt% of an phosphate morpholide-based flame resistant represented by the formula II; 0.01-1.0 parts by weight of a perfluorinated alkane sulfonate salt; and 0.05-5 parts by weight of a fluorinated polyolefin-based resin having an average particle size of 0.05-1,000 micrometers and a density of 1.2-2.3 g/cm¬3. In the formulas I-a and I-b, R is an alkyl, aryl, alkyl-substituted aryl, aralkyl, alkoxy, aryloxy, amino or hydroxyl group; and k is an integer of 0-10. In the formula II, x is 1 or 2; R1 is an alkyl-substituted or unsubstituted aryl group of C6-C20; R2 is an alkyl-substituted or unsubstituted aryl group of C6-C30; and n+m is 0-5.
Abstract translation: 目的：提供阻燃热塑性树脂组合物，以改善阻燃性，耐热性和机械强度。 构成：该组合物包含100重量份的热塑性聚碳酸酯基树脂; 5-90重量％的由式I-a表示的线性磷腈或由式I-b表示的环状磷腈化合物和10-95重量％由式II表示的磷酸吗啉酯类阻燃剂; 0.01-1.0重量份全氟化烷烃磺酸盐; 和0.05-5重量份平均粒径为0.05-1,000微米，密度为1.2-2.3g / cm 3的氟化聚烯烃基树脂。 在式I-a和I-b中，R是烷基，芳基，烷基取代的芳基，芳烷基，烷氧基，芳氧基，氨基或羟基; k为0〜10的整数。 在式II中，x为1或2; R1是C6-C20的烷基取代或未取代的芳基; R2是C6-C30的烷基取代或未取代的芳基; n + m为0-5。
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公开(公告)号：KR1020000055265A
公开(公告)日：2000-09-05
申请号：KR1019990003792
申请日：1999-02-04
Applicant: 제일모직주식회사
Abstract: PURPOSE: Polycarbonate resin compositions are prepared which are excellent in light reflect and impact strength by using polycarbonate resin, rubber modified styrene containing graft copolymers, styrene containing copolymers, rutile titaniumdioxide, ester phosphate, and fluoridized polyolefin resin in suitable ratio. CONSTITUTION: A resin compositions contain (a) 50-99 pts. by wt. of thermoplastic polycarbonate not having halogen; (b) 1-50 pts. by wt. of rubber modified styrene containing graft copolymers; (c) 0-30 pts. by wt. of styrene containing copolymers; (d) 5-20 pts. by wt. of titaniumdioxide having rutile type crystalline structure of average particle size of 0.15-0.25 micrometers to 100 pts. by wt. of the components (a), (b), and (c); (e) 2-20 pts. by wt. of ester phosphate, and (f) 0-2 pts. by wt. of fluoridized polyolefin resin.
Abstract translation: 目的：通过使用聚碳酸酯树脂，含橡胶改性苯乙烯的接枝共聚物，含苯乙烯的共聚物，金红石型二氧化钛，磷酸酯酯和适当的氟化聚烯烃树脂，制得光反射和冲击强度优异的聚碳酸酯树脂组合物。 构成：树脂组合物含有（a）50-99重量份。 以重量计 不含卤素的热塑性聚碳酸酯; （b）1-50点。 以重量计 的橡胶改性苯乙烯接枝共聚物; （c）0-30分。 以重量计 含苯乙烯的共聚物; （d）5-20点。 以重量计 具有平均粒径为0.15-0.25微米至100点的金红石型晶体结构的二氧化钛。 以重量计 的组分（a），（b）和（c）; （e）2-20点。 以重量计 的磷酸酯，和（f）0-2个。 以重量计 的氟化聚烯烃树脂。
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公开(公告)号：KR100182359B1
公开(公告)日：1999-05-15
申请号：KR1019950039887
申请日：1995-11-06
Applicant: 제일모직주식회사
Abstract: 본 발명은 폴리카보네이트 수지의 내열성, 열안정성, 웰드강도 등을 저하시키지 않고, 내약품성, 내충격성, 작업성 등이 우수한 폴리카보네이트계 열가소성 수지 조성물을 제공하기 위한 것으로, 전체 수지 조성물 100 중량부에 대하여 (A) 고분자량 방향족 열가소성 폴리카보네이트 수지 50 내지 98 중량부; (B) (b1) 60 내지 100 중량%의 올레핀계 단량체와 (b2) 0 내지 40 중량%의 비닐계 단량체의 중합체 40 내지 90 중량부에 대하여 (b3) 10 내지 60 중량부의 비닐계 중합체가 그라프트 되어 있는 올레핀계 그라프트 공중합체 2 내지 50 중량부; (C) (c1) 40 내지 90 중량%의 방향족 비닐계 단량체와 (c2) 10 내지 60 중량%의 시안화 비닐계 단량체 및 (c3) 상기 (c1)와 (c2) 조성물 100 중량부에 대하여 (c1)과 (c2) 조성물에 중합가능한 0 내지 40 중량부의 다른 비닐계 단량체를 공중합한 SAN 공중합체 0 내지 30 중량부로 이루어짐을 특징으로 한다.
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Patent Agency Ranking
公开(公告)号：KR100673262B1
公开(公告)日：2007-01-22
申请号：KR1020050046873
申请日：2005-06-01
Applicant: 제일모직주식회사
IPC: C08L77/02
Abstract: 본 발명의 폴리아미드계 열가소성 수지 조성물은 (A) 폴리아미드 수지 75∼99.9 중량부; (B) 선형 폴리페닐렌 설파이드 수지 0.1∼25 중량부; 및 (C) 상기 (A)+(B)의 기초수지 100 중량부에 대하여, 퍼플루오르폴리에테르 화합물 0.1∼5 중량부로 이루어지는 것을 특징으로 한다.
폴리아미드, 폴리페닐렌 설파이드, 퍼플루오르에테르, 열안정성, 내마모성-
公开(公告)号：KR100513976B1
公开(公告)日：2005-09-09
申请号：KR1020030078650
申请日：2003-11-07
Applicant: 제일모직주식회사
IPC: C08L81/02
Abstract: 본 발명에 따른 폴리페닐렌 설파이드계 열가소성 수지 조성물은 (A) 폴리페닐렌 설파이드 수지 60∼95 중량부, (B) 폴리페닐렌 에테르 수지 5∼40 중량부, (C) 상기 구성성분 (A)+(B)로 이루어진 기초수지 100 중량부에 대하여 에폭시기가 2∼3개인 에폭시 화합물 1∼5 중량부, 및 (D) 상기 구성성분 (A)+(B)로 이루어진 기초수지 100 중량부에 대하여 충전제 20∼250 중량부로 이루어지는 것을 특징으로 한다.
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公开(公告)号：KR1020050049129A
公开(公告)日：2005-05-25
申请号：KR1020030083009
申请日：2003-11-21
Applicant: 제일모직주식회사
IPC: C08L81/02
Abstract: 본 발명에 따른 폴리페닐렌 설파이드 열가소성 수지 조성물은 (A) 폴리페닐렌 설파이드 수지 65∼99 중량부; (B) (b
1 ) 올레핀계 단량체 60∼95 중량% 및 비닐계 단량체 5∼40 중량%로 이루어진 중합체 40∼90 중량부에 (b
2 ) 비닐계 중합체 10∼60 중량부가 그라프트 공중합 되어있는 올레핀계 그라프트 공중합체 1∼30 중량부; (C) 에폭시기가 2개 이상인 에폭시 화합물 0∼10 중량부; 및 (D) 충진제 0∼230 중량부;로 이루어지는 것을 특징으로 한다.-
公开(公告)号：KR1020040035980A
公开(公告)日：2004-04-30
申请号：KR1020020062363
申请日：2002-10-14
Applicant: 제일모직주식회사
IPC: C08K5/42
Abstract: PURPOSE: Provided is a flame-resistant thermoplastic composition, which has excellent physical properties including flame-resistance, heat resistance and mechanical strength. CONSTITUTION: The flame-resistant thermoplastic composition comprises: 100 parts by weight of a polycarbonate resin; 0.01-1.0 parts by weight of a perfluoroalkane sulfonate salt; and 5-15 parts by eight of a glass fiber. The perfluoroalkane sulfonate salt used as a flame-retardant is selected from the group consisting of a sodium salt or a potassium salt of perfluoromethane sulfonate, perfluoroethane sulfonate, perfluoropropane sulfonate, perfluorobutane sulfonate, perfluoromethylbutane sulfonate, perfluorohexane sulfonate, perfluoroheptane sulfonate and perfluoroocatne sulfonate; tetraethylammonium perfluorobutane sulfonate; tetraethylammonium perfluoromethyl butane sulfonate; and a mixture thereof.
Abstract translation: 目的：提供阻燃热塑性组合物，其具有优异的物理性能，包括耐火性，耐热性和机械强度。 构成：耐火热塑性组合物包括：100重量份的聚碳酸酯树脂; 0.01-1.0重量份的全氟烷基磺酸盐; 和5-15分之八的玻璃纤维。 用作阻燃剂的全氟烷烃磺酸盐选自全氟甲烷磺酸钠盐或钾盐，全氟乙磺酸盐，全氟丙烷磺酸盐，全氟丁烷磺酸盐，全氟甲基丁烷磺酸盐，全氟己烷磺酸盐，全氟庚烷磺酸盐和全氟代磺酸盐; 全氟丁烷磺酸四乙铵; 四乙基铵全氟甲基丁烷磺酸盐; 及其混合物。
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公开(公告)号：KR1020030046906A
公开(公告)日：2003-06-18
申请号：KR1020010077234
申请日：2001-12-07
Applicant: 제일모직주식회사
IPC: C08L69/00
CPC classification number: C08K5/42 , C08J2300/22 , C08L69/00 , C08L2201/02
Abstract: PURPOSE: A thermoplastic resin composition having excellent flame retardant property, heat resistance and mechanical properties which can be used in a computer housing or other office machinery and tools is provided. CONSTITUTION: The flame retardant thermoplastic resin composition comprises 100 parts by weight of a polycarbonate resin, 0.01 to 1 parts by weight of a perfluorinated alkane sulfonate salt, and 0.01 to 1 parts by weight of a sulfone sulfonate salt. The polycarbonate rein has the weight average molecular weight of 10,000 to 200,000. The perfluorinated alkane sulfonate salt is used as a flame retardant. The resin composition may further comprise 0 to 20 parts by weight of conventional additives, such as a lubricant, a nucleating agent, a stabilizer, a reinforcing agent, pigments and the like.
Abstract translation: 目的：提供可用于计算机外壳或其他办公机械和工具中的阻燃性，耐热性和机械性能优异的热塑性树脂组合物。 构成：阻燃热塑性树脂组合物包含100重量份的聚碳酸酯树脂，0.01-1重量份的全氟烷烃磺酸盐和0.01-1重量份的磺酸磺酸盐。 聚碳酸酯树脂的重均分子量为10,000〜200,000。 全氟化烷烃磺酸盐用作阻燃剂。 树脂组合物还可以含有0〜20重量份的常规添加剂，例如润滑剂，成核剂，稳定剂，增强剂，颜料等。
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