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公开(公告)号：KR101294631B1
公开(公告)日：2013-08-09
申请号：KR1020110040135
申请日：2011-04-28
Applicant: 충남대학교산학협력단
Abstract: 본 발명은 팽윤성과 흡착성이 우수한 이온교환수지에 관한 것으로, 보다 상세하게는 카르복실산이 있는 단량체 아크릴산계와 가교제인 폴리에틸렌글리콜디아크렐레이트(poly(ethylene glycol) diacrylate)의 현탁중합을 통하여 이온교환수지를 제조함을 목적으로 한다. 본 발명은 기공의 형성으로 비표면적이 상승하여 고흡착성의 성질을 가지며, 아크릴기를 함유하고 있어 고 팽윤성을 가지는 특징이 있다. 본 발명은 해수에서 인듐의 흡착에 응용이 가능하다.
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Patent Agency Ranking
公开(公告)号：KR101285086B1
公开(公告)日：2013-07-17
申请号：KR1020120018808
申请日：2012-02-24
Applicant: 충남대학교산학협력단
CPC classification number: B01D71/82 , B01D61/44 , B01D69/02 , B01D2325/42 , C08J5/2218
Abstract: PURPOSE: An anion exchange membrane for nitrate nitrogen removal and a manufacturing method thereof are provided to reduce the processing cost due to the optimum synthetic condition without requiring complex processes, and to have the excellent selectivity to nitrate nitrogen. CONSTITUTION: A manufacturing method of an anion exchange membrane for nitrate nitrogen removal comprises the following steps: a step of manufacturing a first polymer by polymerizing 4-vinylbenzyl chloride, styrene and acrylic monomer; a step of manufacturing a second polymer by reacting an aminating agent, which is any one selected from tripropylamine and tributylamine, or their mixture, with the first polymer; and a step of manufacturing an anion exchange membrane by using the second polymer.
Abstract translation: 目的：提供一种用于除去硝酸盐的阴离子交换膜及其制造方法，以减少由于最佳合成条件而导致的加工成本，而不需要复杂的工艺，并且对硝酸盐氮具有优异的选择性。 构成：用于硝酸盐去除的阴离子交换膜的制造方法包括以下步骤：通过聚合4-乙烯基苄基氯，苯乙烯和丙烯酸单体制备第一聚合物的步骤; 通过将选自三丙胺和三丁胺或其混合物中的任何一种的胺化剂与第一聚合物反应制备第二聚合物的步骤; 以及通过使用第二聚合物制造阴离子交换膜的步骤。
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公开(公告)号：KR1020120122134A
公开(公告)日：2012-11-07
申请号：KR1020110040137
申请日：2011-04-28
Applicant: 충남대학교산학협력단
CPC classification number: C08F228/02 , B01J47/014 , C08F2/18 , C08F222/1006
Abstract: PURPOSE: An ion exchange resin is provided to have high absorptive property because a specific surface area is increased by forming pores, to have excellent swelling performance by containing acryl group, and to be used for absorption of cobalt in seawater. CONSTITUTION: A manufacturing method of an ion exchange resin comprises: a step of suspension polymerization of an acrylic acid monomer indicated in chemical formula 1 and poly(ethylene glycol) diacrylate indicated in chemical formula 2. In the chemical formulas, R1 is H or a methyl group and n is an integer from 7-14. An initiator is one compound or a mixture of two compounds selected from benzoyl peroxide, dicumyl peroxide and azobisisobutyronitrile.
Abstract translation: 目的：提供离子交换树脂以具有高的吸收性，因为通过形成孔增加比表面积，通过含有丙烯酰基具有优异的溶胀性能，并用于在海水中吸收钴。 构成：离子交换树脂的制造方法包括：化学式1表示的丙烯酸单体和化学式2所示的聚（乙二醇）二丙烯酸酯的悬浮聚合工序。在化学式中，R 1为H或 甲基，n为7-14的整数。 引发剂是选自过氧化苯甲酰，过氧化二异丙苯和偶氮二异丁腈的两种化合物或两种化合物的混合物。
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公开(公告)号：KR1020120122132A
公开(公告)日：2012-11-07
申请号：KR1020110040135
申请日：2011-04-28
Applicant: 충남대학교산학협력단
CPC classification number: C08F20/06 , B01J47/014 , C08F2/18 , C08F222/1006
Abstract: PURPOSE: An ion exchange resin for recovering indium with excellent swelling performance and absorptivity because indium can be moderately collect from seawater. CONSTITUTION: A manufacturing method of an ion exchange resin for recovering indium comprises: a step of suspension polymerization of an acrylic acid monomer indicated in chemical formula 1 and poly(ethylene glycol) diacrylate indicated in chemical formula 2. In chemical formulas, R1 is H or a methyl group and n is an integer from 7-14. A solvent of an initiator is toluene. The acrylic acid monomer is 16-20 weight% based on total weight of ion exchange resin for indium collection.
Abstract translation: 目的：用于回收铟的离子交换树脂，具有优异的溶胀性能和吸收性，因为铟可以从海水适度收集。 构成：用于回收铟的离子交换树脂的制造方法包括：化学式1所示的丙烯酸单体和化学式2所示的聚（乙二醇）二丙烯酸酯的悬浮聚合工序。在化学式中，R1为H 或甲基，n为7-14的整数。 引发剂的溶剂是甲苯。 丙烯酸单体为铟收集用离子交换树脂的总重量的16-20重量％。
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公开(公告)号：KR1020120078653A
公开(公告)日：2012-07-10
申请号：KR1020110147367
申请日：2011-12-30
Applicant: 충남대학교산학협력단
Abstract: PURPOSE: A manufacturing method of high porous lithium manganese oxide based epoxy spherical composite using a template carbonization and a spray-drying method are provided to synthesize lithium manganese oxide having low-density, large specific surface area, and high porosity. CONSTITUTION: A manufacturing method of lithium manganese oxide based epoxy spherical composite comprises the following steps: mixing a binder resin composition with an inorganic compound; spraying the mixture on a fluorinated plate and manufacturing a spherical shaped composite by heat-treating; and acid processing the spherical shaped composite. The lithium manganese oxide based spherical shaped composite has a specific surface area of 40-60m^2/g and a pore volume range of 0.20-0. 40cm^3/g. The heating is processed at 450-520 deg. Celsius for 3-6 hours. In the mixing step, the binder resin composition comprises 5-15 parts by weight of imidazole based compound and 80-100 parts by weight of epoxy resin based on 100.0, parts by weight of phenol type curing agent. 30-70 wt% of solvent is included based on 100.0 wt% of the total weight portion. In the mixing step, the binder resin composition and the inorganic compound are mixed at a weight ratio of 1:1-3:1.
Abstract translation: 目的：提供一种使用模板碳化和喷雾干燥方法制备高多孔锂锰氧化物基环氧球形复合材料的方法，以合成具有低密度，大比表面积和高孔隙率的锂锰氧化物。 构成：基于锰酸锂的环氧球形复合材料的制造方法包括以下步骤：将粘合剂树脂组合物与无机化合物混合; 将混合物喷涂在氟化板上，通过热处理制造球形复合材料; 和酸处理球形复合材料。 基于锰酸锂的球形复合材料的比表面积为40-60m ^ 2 / g，孔体积范围为0.20-0。 40厘米^ 3 / g以下。 加热在450-520度处理。 摄氏3-6小时。 在混合步骤中，粘合剂树脂组合物包含基于100重量份苯酚型固化剂的5-15重量份咪唑基化合物和80-100重量份环氧树脂。 基于总重量的100.0重量％，包括30-70重量％的溶剂。 在混合步骤中，将粘合剂树脂组合物和无机化合物以1：1-3：1的重量比混合。
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公开(公告)号：KR1020120007153A
公开(公告)日：2012-01-20
申请号：KR1020100067743
申请日：2010-07-14
Applicant: 충남대학교산학협력단
Abstract: PURPOSE: The preparation of an organic-inorganic hybrid ion-exchanging membrane is provided to improve the ion conductivity and the ion exchanging capability of the ion-exchanging membrane by blending antimony oxide, styrene-butadiene-styrene, sulfonated polystyrene. CONSTITUTION: Sulfonic acid group substituted polystyrene and styrene-butadiene-styrene are mixed under inert gas. Antimony oxide is added into and mixed with the mixture. The mixture is coated on a base material. A hybrid ion-exchanging membrane is obtained based on a cross-linking reaction at a temperature between 80 and 100 degrees Celsius. The sulfonic acid group substituted polystyrene is obtained by adding polystyrene and sulfonic acid into chloromethane, and a sulfonization process is implemented.
Abstract translation: 目的：提供有机 - 无机杂化离子交换膜的制备，以通过混合氧化锑，苯乙烯 - 丁二烯 - 苯乙烯，磺化聚苯乙烯来提高离子交换膜的离子传导性和离子交换能力。 构成：将磺酸基取代的聚苯乙烯和苯乙烯 - 丁二烯 - 苯乙烯在惰性气体下混合。 将氧化锑加入并与混合物混合。 将混合物涂覆在基材上。 基于交联反应在80至100摄氏度的温度下获得混合离子交换膜。 磺酸基取代的聚苯乙烯通过将聚苯乙烯和磺酸加入到氯甲烷中而获得，并且实现了磺化过程。
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