Abstract:
본 발명은 천연 바이오매스 기반 이산화탄소 흡수제의 제조방법 및 이에 의해 제조된 천연 바이오매스 기반 이산화탄소 흡수제에 관한 것으로, 더욱 상세하게는 천연 식물계 바이오매스 재료가 자체적으로 함유하고 있는 Ca, Mg, K 등의 알칼리 금속 또는 알칼리 토금속 성분을 이산화탄소 흡수제 용도로 활용하는 고효율/저비용의 이산화탄소 흡수제의 제조방법에 관한 것이다. 본 발명에 따르면, 친환경적이고, 공정비용을 대폭 저감시키고, 흡수제의 성능이 향상된 천연 바이오매스 기반 이산화탄소 흡수제를 제공할 수 있다.
Abstract:
Disclosed are an imidazolium-based ionic liquid functionalized with an amine and a method for a separation of carbon dioxide using the same. The imidazolium-based ionic liquid functionalized with the amine according to the present invention has a superior carbon dioxide absorption capacity. The absorbed carbon dioxide can be easily absorbed/desorbed by heating. The liquid of the present invention provides use convenience and can be effectively used in collecting CO2 since the liquid has a selectivity, a thermal stability, a repeatable usability, and a long lifespan.
Abstract:
The present invention relates to ionic liquid using an aromatic cation material for separating carbon dioxide and, more specifically, to ionic liquid which improves carbon dioxide absorption capacity, initial absorption rates, and reclaimable performance compared with existing ionic liquid. The ionic liquid of the present invention is selected among 1-methylimidazolium, 1-ethylimidazolium, and 1-butylimidazolium.
Abstract:
본 발명은 이산화탄소 흡수제에 관한 것으로서, 구체적으로는 이산화탄소 흡수능이 우수하고 반응속도가 빠르며, 이산화탄소 포집 과정에서 재생에너지를 크게 저감할 수 있는 흡수제 및 이를 이용한 이산화탄소 포집 방법에 관한 것이다. 본 발명의 적절한 실시 형태에 따르면, 전체 중량 대비 모노에탄올아민 10~70wt%, 디에탄올아민 10~40wt% 및 트리에탄올아민 5~75wt%을 포함하는 이산화탄소 흡수제를 제공한다.
Abstract:
PURPOSE: A collecting method of carbon dioxide using carbon dioxide absorbent is provided to have excellent absorption of carbon dioxide, fast reaction speed, and sharply reduce in the collecting process of carbon dioxide. CONSTITUTION: A carbon dioxide absorbent comprises monoethanolamine 10-70wt%, diethanolamine 10-40wt%, and triethanolammine 5-75wt%. The absorbent is manufactured by reacting overdose of ammonia and ethylene oxide. The ammonia and ethylene oxide are reacted to the mole ration of 1:1-20:1. A collecting method of carbon dioxide uses aqueous solution including the carbon dioxide absorbent 20-40 wt%. Temperature of the absorbent aqueous solution is 40-80 °C when collecting carbon dioxide.
Abstract:
PURPOSE: A vanadium based alloy hydrogen separating membrane doped with yttrium and a hydrogen separating method using the same are provided to improve a mechanical stability at high temperature as well as a high hydrogen transmittance and have an excellent economical efficiency by not using palladium. CONSTITUTION: A vanadium based alloy hydrogen separating membrane doped with yttrium is doped with the yttrium of a below formula 1. V_100-x-yM_xY_y(I). In the above formula, M is a metal or a transition metal, and x is 0 ≤ x ≤ 20% and y is 0
Abstract:
A carbon dioxide absorbent for a gas-liquid contactor in which potassium carbonate and an enhancer are mixed is provided to offer stabilization of physicochemical material property of a hollow fiber membrane by using a potassium carbonate absorbent. A carbon dioxide absorbent for a gas-liquid contactor includes 5-20 weight% of potassium carbonate and 5-15 weight% of annular amine. A gas-liquid contact system for separation of carbon dioxide includes an absorption reactor(420) and a degassing reactor(490). The absorption reactor absorbs the carbon dioxide from mixed gas.
Abstract:
A method refreshing an adsorber using pressure driving in a fuel reformer is provided to have a simple structure, to be easily operated and reduce consumption of renewable energy by reproducing an adsorber using pressure gradient at temperature same to fuel reformate reaction. A method refreshing an adsorber using pressure driving in a fuel reformer comprises steps of: i) generating hydrogen by injecting water and methane in a reactor 1(REA1), separating the generated carbon dioxide and reproducing the adsorber by maintaining pressure in a reactor 2(REA2) to 0.001~0.2 pressure(atm) and temperature same to the reactor 1; ii) recycling the adsorber by maintaining pressure to 0.001~0.2 pressure(atm) and temperature same to the reactor 2, generating the hydrogen by injecting water and methane in the reactor 2 and separating the generated carbon dioxide; iii) and performing repetitively the i) and the ii).
Abstract:
A unit reaction block that can obtain a high efficient chemical heat pump for cooling and heating by smoothly contacting an inorganic salt as a reaction medium with an ammonia gas as a drive medium in a chemical heat pump and efficiently transferring heat generated during the chemical reaction to the outside, a manufacturing method of the unit reaction block, and a mounting method of the unit reaction block on the chemical heat pump are provided. A thermal conductive unit reaction block for a chemical heat pump is characterized in that a supporting block is inserted between reaction blocks containing a metal chloride in surfaces thereof. The reaction blocks containing the metal chloride in the surfaces thereof are prepared a step(1) of mixing a therm conductive powder material with a binder, and compressing the mixture under high temperature and high pressure to obtain a compressed material, and a step(2) of applying a metal chloride as an adhesive onto a surface of the compressed material, and removing the adhesive. The metal chloride is at least one selected from ZnCl2, CuCl2, SnCl2, PbCl2, BaCl2, CaCl2, SrCl2, MnCl2, FeCl2, CoCl2, MgCl2, and NiCl2. A manufacturing method of a thermal conductive unit reaction block(13) for a chemical heat pump comprises inserting a supporting block(2) having a binder sprayed on the surface thereof between reaction blocks(1) containing a metal chloride in surfaces thereof, and compressing and drying the supporting block inserted between the reaction blocks.
Abstract:
A method of preparing a reactive medium comprising a carbon support impregnated with a metal catalyst and a method for removing NOx by using the reactive medium are provided to complement and replace the selective catalytic reduction process by directly reducing NOx exhausted from actual combustion flue gas by using an inexpensive metal impregnated carbon support without using a reducing agent such as ammonia. A method of preparing a reactive medium for NOx removal comprising a metal catalyst impregnated on a carbon support comprises: adding 47.37 to 49.75 wt.% of water into 0.5 to 5.26 wt.% of a metal catalyst to prepare an aqueous solution; adding 47.37 to 49.75 wt.% of a carbon support into the aqueous solution; and impregnating the carbon support with the aqueous solution in a rotary vacuum dryer by controlling an impregnation temperature to a range from 25 to 90 deg.C, controlling an impregnation speed to a range from 40 to 100 rpm, and controlling an impregnation pressure to a range from 500 to 700 mmHg. A method for removing NOx in an oxygen-free gas by using the reactive medium comprises removing NOx by controlling an injection flow rate of combustion flue gas to a range from 10,000 to 30,000 hr^-1, and controlling an operating temperature of 450 deg.C or more in a reactive medium comprising a carbon support impregnated with a metal catalyst.