이산화탄소 분리용 아민 관능화된 이미다졸륨 이온성 액체 및 그 용도
    22.
    发明公开
    이산화탄소 분리용 아민 관능화된 이미다졸륨 이온성 액체 및 그 용도 无效
    用于分离二氧化碳及其使用的胺的基于离子液体的离子液体

    公开(公告)号:KR1020140014740A

    公开(公告)日:2014-02-06

    申请号:KR1020120081513

    申请日:2012-07-26

    Abstract: Disclosed are an imidazolium-based ionic liquid functionalized with an amine and a method for a separation of carbon dioxide using the same. The imidazolium-based ionic liquid functionalized with the amine according to the present invention has a superior carbon dioxide absorption capacity. The absorbed carbon dioxide can be easily absorbed/desorbed by heating. The liquid of the present invention provides use convenience and can be effectively used in collecting CO2 since the liquid has a selectivity, a thermal stability, a repeatable usability, and a long lifespan.

    Abstract translation: 公开了用胺官能化的咪唑鎓离子液体和使用其分离二氧化碳的方法。 用根据本发明的胺官能化的咪唑鎓离子液体具有优异的二氧化碳吸收能力。 吸收的二氧化碳可以通过加热容易地吸收/解吸。 本发明的液体提供使用的便利性,并且可以有效地用于收集二氧化碳,因为液体具有选择性,热稳定性,可重复的可用性和长的使用寿命。

    이산화탄소 흡수성능이 우수한 흡수제
    25.
    发明公开
    이산화탄소 흡수성능이 우수한 흡수제 有权
    吸收高碳二氧化碳负荷比

    公开(公告)号:KR1020130023561A

    公开(公告)日:2013-03-08

    申请号:KR1020110086410

    申请日:2011-08-29

    Abstract: PURPOSE: A collecting method of carbon dioxide using carbon dioxide absorbent is provided to have excellent absorption of carbon dioxide, fast reaction speed, and sharply reduce in the collecting process of carbon dioxide. CONSTITUTION: A carbon dioxide absorbent comprises monoethanolamine 10-70wt%, diethanolamine 10-40wt%, and triethanolammine 5-75wt%. The absorbent is manufactured by reacting overdose of ammonia and ethylene oxide. The ammonia and ethylene oxide are reacted to the mole ration of 1:1-20:1. A collecting method of carbon dioxide uses aqueous solution including the carbon dioxide absorbent 20-40 wt%. Temperature of the absorbent aqueous solution is 40-80 °C when collecting carbon dioxide.

    Abstract translation: 目的:提供使用二氧化碳吸收剂的二氧化碳的收集方法,具有优良的二氧化碳吸收,快速的反应速度,并且在二氧化碳的收集过程中急剧减少。 构成:二氧化碳吸收剂包括10-70wt%的单乙醇胺,10-40wt%的二乙醇胺和5-75wt%的三乙醇胺。 吸收剂是通过使过量的氨和环氧乙烷反应来制造的。 氨和环氧乙烷的摩尔比为1:1-20:1。 二氧化碳的收集方法使用包含20-40重量%的二氧化碳吸收剂的水溶液。 当收集二氧化碳时,吸收剂水溶液的温度为40-80℃。

    기액 접촉기용 이산화탄소 흡수제
    27.
    发明公开
    기액 접촉기용 이산화탄소 흡수제 无效
    用于气液接触器的二氧化碳吸收剂溶液

    公开(公告)号:KR1020090041491A

    公开(公告)日:2009-04-29

    申请号:KR1020070107024

    申请日:2007-10-24

    CPC classification number: Y02A50/2342 B01J20/043 B01J20/22

    Abstract: A carbon dioxide absorbent for a gas-liquid contactor in which potassium carbonate and an enhancer are mixed is provided to offer stabilization of physicochemical material property of a hollow fiber membrane by using a potassium carbonate absorbent. A carbon dioxide absorbent for a gas-liquid contactor includes 5-20 weight% of potassium carbonate and 5-15 weight% of annular amine. A gas-liquid contact system for separation of carbon dioxide includes an absorption reactor(420) and a degassing reactor(490). The absorption reactor absorbs the carbon dioxide from mixed gas.

    Abstract translation: 提供混合有碳酸钾和增强剂的气液接触器的二氧化碳吸收剂,以通过使用碳酸钾吸收剂来稳定中空纤维膜的物理化学性质。 用于气液接触器的二氧化碳吸收剂包括5-20重量%的碳酸钾和5-15重量%的环状胺。 用于分离二氧化碳的气液接触系统包括吸收反应器(420)和脱气反应器(490)。 吸收反应器从混合气体中吸收二氧化碳。

    연료개질 장치에서 압력구동을 이용한 이산화탄소 흡착제재생방법
    28.
    发明授权
    연료개질 장치에서 압력구동을 이용한 이산화탄소 흡착제재생방법 失效
    燃料改造中压力控制的二氧化碳吸附再生方法

    公开(公告)号:KR100884701B1

    公开(公告)日:2009-02-19

    申请号:KR1020070084574

    申请日:2007-08-22

    CPC classification number: Y02P20/133

    Abstract: A method refreshing an adsorber using pressure driving in a fuel reformer is provided to have a simple structure, to be easily operated and reduce consumption of renewable energy by reproducing an adsorber using pressure gradient at temperature same to fuel reformate reaction. A method refreshing an adsorber using pressure driving in a fuel reformer comprises steps of: i) generating hydrogen by injecting water and methane in a reactor 1(REA1), separating the generated carbon dioxide and reproducing the adsorber by maintaining pressure in a reactor 2(REA2) to 0.001~0.2 pressure(atm) and temperature same to the reactor 1; ii) recycling the adsorber by maintaining pressure to 0.001~0.2 pressure(atm) and temperature same to the reactor 2, generating the hydrogen by injecting water and methane in the reactor 2 and separating the generated carbon dioxide; iii) and performing repetitively the i) and the ii).

    Abstract translation: 提供了一种使用燃料重整器中的压力驱动来清洗吸附器的方法,具有简单的结构,易于操作,并且通过使用与燃料重整反应相同的温度的压力梯度再生吸附器来减少可再生能源的消耗。 使用在燃料重整器中使用压力驱动来刷新吸附器的方法包括以下步骤:i)通过在反应器1(REA1)中注入水和甲烷产生氢气,通过保持反应器2中的压力分离生成的二氧化碳并再生吸附器( REA2)至0.001〜0.2压力(atm)和与反应器1相同的温度; ii)通过将压力保持在与反应器2相同的压力至0.001〜0.2的压力(atm)和温度下再循环,通过在反应器2中注入水和甲烷并分离生成的二氧化碳来产生氢; iii)并重复执行i)和ii)。

    냉각 및 난방을 위한 화학열펌프용 열전도성 단위반응블록및 이의 제조방법
    29.
    发明授权
    냉각 및 난방을 위한 화학열펌프용 열전도성 단위반응블록및 이의 제조방법 有权
    用于冷却和加热的制冷单元反应块及其制造方法

    公开(公告)号:KR100760380B1

    公开(公告)日:2007-09-19

    申请号:KR1020060092004

    申请日:2006-09-21

    CPC classification number: F25B17/08 B01J20/02 F28F1/10

    Abstract: A unit reaction block that can obtain a high efficient chemical heat pump for cooling and heating by smoothly contacting an inorganic salt as a reaction medium with an ammonia gas as a drive medium in a chemical heat pump and efficiently transferring heat generated during the chemical reaction to the outside, a manufacturing method of the unit reaction block, and a mounting method of the unit reaction block on the chemical heat pump are provided. A thermal conductive unit reaction block for a chemical heat pump is characterized in that a supporting block is inserted between reaction blocks containing a metal chloride in surfaces thereof. The reaction blocks containing the metal chloride in the surfaces thereof are prepared a step(1) of mixing a therm conductive powder material with a binder, and compressing the mixture under high temperature and high pressure to obtain a compressed material, and a step(2) of applying a metal chloride as an adhesive onto a surface of the compressed material, and removing the adhesive. The metal chloride is at least one selected from ZnCl2, CuCl2, SnCl2, PbCl2, BaCl2, CaCl2, SrCl2, MnCl2, FeCl2, CoCl2, MgCl2, and NiCl2. A manufacturing method of a thermal conductive unit reaction block(13) for a chemical heat pump comprises inserting a supporting block(2) having a binder sprayed on the surface thereof between reaction blocks(1) containing a metal chloride in surfaces thereof, and compressing and drying the supporting block inserted between the reaction blocks.

    Abstract translation: 一种单元反应块,其能够通过使无机盐作为反应介质与化学热泵中的氨气作为驱动介质平滑接触而获得高效的化学热泵,并有效地将化学反应期间产生的热量传递至 提供了单元反应块的制造方法以及化学热泵上的单元反应块的安装方法。 用于化学热泵的导热单元反应块的特征在于,在其表面中含有金属氯化物的反应块之间插入支撑块。 制备其表面含有金属氯化物的反应块,制备将热导粉末材料与粘合剂混合并在高温高压下压缩混合物以获得压缩材料的步骤(1),并且将步骤(2) )将金属氯化物作为粘合剂施加到压缩材料的表面上,并且去除粘合剂。 金属氯化物是选自ZnCl 2,CuCl 2,SnCl 2,PbCl 2,BaCl 2,CaCl 2,SrCl 2,MnCl 2,FeCl 2,CoCl 2,MgCl 2和NiCl 2中的至少一种。 一种用于化学热泵的导热单元反应块(13)的制造方法,包括在其表面上插入具有喷涂在其表面的反应块(1)的粘合剂的支撑块(2),并在其表面包含金属氯化物的反应块 并干燥插入反应块之间的支撑块。

    금속 촉매가 함침된 탄소 지지체를 포함하는 반응매체제조와 이를 이용한 질소산화물 제거 방법
    30.
    发明授权
    금속 촉매가 함침된 탄소 지지체를 포함하는 반응매체제조와 이를 이용한 질소산화물 제거 방법 失效
    금속촉매가함침된된탄소지지체를포함하는반응매체제조와이를이용한질소산화물제거방

    公开(公告)号:KR100746704B1

    公开(公告)日:2007-08-06

    申请号:KR1020060089207

    申请日:2006-09-14

    Abstract: A method of preparing a reactive medium comprising a carbon support impregnated with a metal catalyst and a method for removing NOx by using the reactive medium are provided to complement and replace the selective catalytic reduction process by directly reducing NOx exhausted from actual combustion flue gas by using an inexpensive metal impregnated carbon support without using a reducing agent such as ammonia. A method of preparing a reactive medium for NOx removal comprising a metal catalyst impregnated on a carbon support comprises: adding 47.37 to 49.75 wt.% of water into 0.5 to 5.26 wt.% of a metal catalyst to prepare an aqueous solution; adding 47.37 to 49.75 wt.% of a carbon support into the aqueous solution; and impregnating the carbon support with the aqueous solution in a rotary vacuum dryer by controlling an impregnation temperature to a range from 25 to 90 deg.C, controlling an impregnation speed to a range from 40 to 100 rpm, and controlling an impregnation pressure to a range from 500 to 700 mmHg. A method for removing NOx in an oxygen-free gas by using the reactive medium comprises removing NOx by controlling an injection flow rate of combustion flue gas to a range from 10,000 to 30,000 hr^-1, and controlling an operating temperature of 450 deg.C or more in a reactive medium comprising a carbon support impregnated with a metal catalyst.

    Abstract translation: 提供了一种制备包含用金属催化剂浸渍的碳载体的反应介质的方法以及通过使用反应介质去除NOx的方法,以通过使用通过直接还原从实际燃烧烟气排出的NOx而补充并替代选择性催化还原过程 不使用氨等还原剂而廉价的金属浸渍碳载体。 一种制备包含浸渍在碳载体上的金属催化剂的用于除去NOx的反应介质的方法,包括:将47.37至49.75重量%的水加入0.5至5.26重量%的金属催化剂中以制备水溶液; 向该水溶液中加入47.37至49.75重量%的碳载体; 以及通过将浸渍温度控制在25-90℃的范围内,将浸渍速度控制在40-100rpm的范围内,并将浸渍压力控制在 范围从500到700 mmHg。 通过使用反应介质去除无氧气体中的NO x的方法包括通过将燃烧烟气的喷射流量控制在10,000至30,000hr -1的范围内并控制450℃的操作温度来去除NO x。 在包含浸渍有金属催化剂的碳载体的反应介质中进行。

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