公开(公告)号：KR1020130009033A

公开(公告)日：2013-01-23

申请号：KR1020110069814

申请日：2011-07-14

Applicant: 한국원자력연구원 ,  한국수력원자력 주식회사

Inventor： 김병남 ,  이병철

IPC: C07C303/04 ,  C07C309/30 ,  C08F12/08 ,  H01M8/10

CPC classification number: Y02P70/56 ,  C07C303/08 ,  B01J2219/00047 ,  C07C303/42 ,  C07C309/29

Abstract: PURPOSE: A sulfonated styrene monomer, a manufacturing method thereof and an ion exchange membrane using the same are provided to minimize chemical effects which can be occurred during sulfonation. CONSTITUTION: A manufacturing method of sulfonated styrene monomer comprises the following steps: preparing ionic liquid which prevents the styrene monomer from being polymerized; forming a first mixture by mixing the ionic liquid with chlorosulfonic acid; forming a second mixture by adding the styrene monomer into the first mixture; and irradiating electron beam to the second mixture. The ionic liquid and chlorosulfonic acid are mixed at the weight ratio of 1:0.5-1:1. The first mixture and the styrene monomer are mixed at the weight ratio of 0.05:1-0.15:1.

Abstract translation: 目的：提供磺化苯乙烯单体，其制备方法和使用其的离子交换膜以使磺化过程中可能发生的化学作用最小化。 构成：磺化苯乙烯单体的制造方法包括以下步骤：制备防止苯乙烯单体聚合的离子液体; 通过将离子液体与氯磺酸混合形成第一混合物; 通过将苯乙烯单体加入到第一混合物中形成第二混合物; 并向第二混合物照射电子束。 离子液体和氯磺酸以1:0.5-1:1的重量比混合。 第一混合物和苯乙烯单体以0.05:1-0.15:1的重量比混合。