Abstract:
Adducts are provided comprising MgCl2, ethanol and a Lewis base (LB), said compounds being present in molar ratios defined by the following formula MgCl2.(EtOH)n(LB)p in which n is from 2 to 6 and p has values satisfying the following equation p/(n+p)≦̸0.1. The said adducts can be used as precursor in the preparation of high activity ZN catalysts.
Abstract:
The present disclosure relates to a porous solid adduct comprising magnesium chloride and ethanol, characterized by a relationship between the content of alcohol, average pore radius and amount of porosity deriving from pores with radii of 100-1000 nm, and catalyst components produced therefrom that are capable of producing polyolefins with increased porosity.
Abstract:
Solid adducts comprising MgCl 2 , ethanol and water characterized in that the amount of ethanol ranges from 50% to less than 57% by weight, the amount of water is ranges from 0.5 to 5% by weight, the ethanol/water weight ratio is lower than 60 and the porosity determined with Hg method due to pores up to 1 µm and expressed in cm 3 /g, is lower than 0.2.
Abstract:
Adducts comprising a MgC1 2, an alcohol ROH in which R is a C1 -C1O hydrocarbon group, present in a molar ratio with MgC1 2 ranging from 0.5 to 5 and less than 15% wt, based on the total weight of the adduct, of a metal salt of an aliphatic carboxylic acid having from 8 to 22 carbon atoms.
Abstract:
Solid adducts comprising MgCl 2 and water and optionally an organic hydroxy compound (A) selected from hydrocarbon structures containing at least one hydroxy group, said compounds being present in molar ratio defined by the following formula MgCl 2 •(H 2 0) n (A) p in which n is from 0.6 to 6, p ranges from 0 to 3, said adduct having a porosity (P F ), measured by the mercury method and due to pores with radius equal to or lower than 1μm, of at least 0.15 cm 3 /g with the proviso that when p is 0, (P F ) is equal to or higher than 0.3 cm 3 /g.
Abstract:
Solid Lewis adducts comprising MgCl2, a Lewis base (LB) belonging to ethers, esters, ketones, silanes or amines and an alcohol ROH, in which R is a C 1-C 15 hydrocarbon group optionally substituted with heteroatoms containing groups, which compounds are in molar ratios to each other defined by the following formula MgC12(ROH) m(LB)n in which m ranges from 0.05 to 6, n ranges from 0.08 to 6. These adducts allow to prepare catalysts having a good morphological stability and high polymerization activities.