公开(公告)号：EP2121773B1

公开(公告)日：2016-11-23

申请号：EP07857394.6

申请日：2007-12-11

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： MORINI, Giampiero ,  DALL'OCCO, Tiziano ,  LIGUORI, Dario ,  PATER, Joachim T. M. ,  VITALE, Gianni

IPC: C08F4/655 ,  C08F10/00

CPC classification number: C08F10/02 ,  C08F110/06 ,  C08F210/06 ,  C08F4/6557 ,  C08F4/6555 ,  C08F2500/12 ,  C08F2500/18 ,  C08F210/16

公开(公告)号：EP2859024B1

公开(公告)日：2016-04-27

申请号：EP13726562.5

申请日：2013-06-05

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： MIGNOGNA, Alessandro ,  GUIDOTTI, Simona ,  KASHULIN, Igor ,  MORINI, Giampiero ,  NIFANT'EV, Ilya ,  PATER, Joachim T. M.

IPC: C08F4/651 ,  C08F110/06

CPC classification number: C08F4/52 ,  C08F4/10 ,  C08F4/16 ,  C08F110/08 ,  C08F4/651 ,  C08F2500/15 ,  C08F2500/17 ,  C08F110/06 ,  C08F2500/12

公开(公告)号：EP2859026A1

公开(公告)日：2015-04-15

申请号：EP13725706.9

申请日：2013-05-30

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： MIGNOGNA, Alessandro ,  ESPOSITO, Simona ,  GUIDOTTI, Simona ,  MORINI, Giampiero ,  PATER, Joachim T. M. ,  PIEMONTESI, Fabrizio ,  VITALE, Gianni

IPC: C08F110/08 ,  C08F4/651

CPC classification number: C08F4/52 ,  C08F4/10 ,  C08F4/16 ,  C08F110/08 ,  C08F4/651 ,  C08F2500/15 ,  C08F2500/17 ,  C08F110/06 ,  C08F2500/12

Abstract: Process for the polymerization of butene-1 carried out in the presence of a catalyst comprising (a) a solid catalyst component comprising Mg, Ti and an electron donor compound of the following formula (I), In which the R groups equal to or different from each other, are C
1 -C
15 hydrocarbon groups, the R
1 -R
2 groups, equal to or different from each other, are hydrogen, halogen or C
1 -C
15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, P, S, N and Si, n and m are integer from 0 to 3 with the proviso that at least one of them is different from 0; (b) An aluminium alkyl cocatalyst and (c) an external electron donor

Abstract translation: 在催化剂存在下进行的丁烯-1的聚合方法，包括（a）包含Mg，Ti的固体催化剂组分和下式（I）的电子给体化合物：其中R基团等于或不同于 彼此是C 1 -C 15烃基，R 1 -R 2基彼此相同或不同，是氢，卤素或C 1 -C 15烃基，任选地含有选自卤素，P ，S，N和Si，n和m是0至3的整数，条件是它们中的至少一个不同于0; （b）烷基铝助催化剂和（c）外电子给体

公开(公告)号：EP2822977A2

公开(公告)日：2015-01-14

申请号：EP13707189.0

申请日：2013-03-05

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： MIGNOGNA, Alessandro ,  GUIDOTTI, Simona ,  MORINI, Giampiero ,  PATER, Joachim T. M.

IPC: C08F4/651 ,  C08F110/06

CPC classification number: C08F4/6494 ,  C07C69/96 ,  C07C2603/18 ,  C08F4/6543 ,  C08F110/06 ,  C08F4/651 ,  C08F2500/12

Abstract: Catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor compound of the following formula (I) in which R1 groups are selected from C
1 -C
15 hydrocarbon groups, R
8 groups, equal or different to each other, are selected from hydrogen, halogen and C
1 -C
15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, O, P, S, N and Si and L is a divalent hydrocarbon group optionally containing heteroatoms selected from halogen, O, P, S, N and Si.

Abstract translation: 用于烯烃聚合的催化剂组分，包括Mg，Ti和下式（I）的电子给体化合物其中R 1基团选自C 1 -C 15烃基，R 8基团彼此相同或不同， 选自氢，卤素和C 1 -C 15烃基，任选地含有选自卤素，O，P，S，N和Si的杂原子，L是任选含有选自卤素，O，P， S，N和Si。

公开(公告)号：EP2794676A1

公开(公告)日：2014-10-29

申请号：EP12797888.0

申请日：2012-12-05

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： GUIDOTTI, Simona ,  MIGNOGNA, Alessandro ,  PATER, Joachim T. M. ,  MORINI, Giampiero

IPC: C08F4/649 ,  C08F110/06 ,  C08F4/651

CPC classification number: C08F4/16 ,  C08F110/06 ,  C08F4/6494 ,  C08F2500/04 ,  C08F2500/12 ,  C08F4/651

Abstract: A catalyst system comprising the product obtained by contacting (a) a solid catalyst component containing Mg, Ti, halogen and at least an electron donor compound selected from phenylene aromatic diesters of a specific formula (b) an alkylaluminum cocatalystand (c) an ester of formula R'OOC-(CR"
2 )
m -COOR' in which m is an integer from 2 to 7, the R' groups, equal to or different from each other, are C
1 -C
10 alkyl groups and the R" groups, independently, are hydrogen or C
1 -C
15 hydrocarbon groups.

公开(公告)号：EP2697271A1

公开(公告)日：2014-02-19

申请号：EP12711393.4

申请日：2012-03-29

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： GUIDOTTI, Simona ,  MORINI, Giampiero ,  ESPOSITO, Simona ,  MIGNOGNA, Alessandro ,  PATER, Joachim T. M. ,  PIEMONTESI, Fabrizio ,  BRITA, Diego

IPC: C08F10/06 ,  C08F4/651

CPC classification number: C08F4/16 ,  C08F10/06 ,  C08F4/651 ,  C08F110/06 ,  C08F2500/12 ,  C08F2500/15 ,  C08F2500/02 ,  C08F210/06 ,  C08F2/001

Abstract: A porous solidcatalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being selected from 1,3-diethers and the other being selected from succinates, characterized by the fact that the molar ratio ID/Ti is from 0.30 to 0.90, where ID is the total molar amount of succinate and 1,3-diether, the molar ratio of the 1,3-diether donor tothe succinate donor is higher than, or equal to, 0.60.

Abstract translation: 一种多孔固体催化剂组分，其包含卤化镁，具有至少一个Ti-卤素键的钛化合物和至少两种电子给体化合物，其中一种电子给体化合物选自1,3-二醚，另一种选自琥珀酸酯，其特征在于， ID / Ti的摩尔比为0.30至0.90，其中ID是琥珀酸酯和1,3-二醚的总摩尔量，1,3-二醚供体与琥珀酸供体的摩尔比高于或等于 ，0.60。

公开(公告)号：EP2630170A1

公开(公告)日：2013-08-28

申请号：EP11772942.6

申请日：2011-10-17

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： MORINI, Giampiero ,  GUIDOTTI, Simona ,  MIGNOGNA, Alessandro ,  PATER, Joachim T. M.

IPC: C08F10/06 ,  C08F4/651 ,  C08F4/654 ,  C08F4/649

CPC classification number: C08F4/16 ,  C08F10/06 ,  C08F110/06 ,  C08F4/6543 ,  C08F4/6494 ,  C08F4/651 ,  C08F2/14 ,  C08F2500/03 ,  C08F2500/12

Abstract: A catalyst system comprising the product obtained by contacting (a) a solid catalyst component containing Mg, Ti, halogen and at least an electron donor compound selected from diolesters of a specific formula (b) an alkylaluminum cocatalyst and (c) an ester of formula R'OOC-(CR"
2 )
m -COOR' in which m is an integer from 2 to 8, the R' groups, equal to or different from each other, are C1-C10 alkyl groups and the R" groups, independently, are hydrogen or C1 -C15 hydrocarbon groups.

Abstract translation: （a）含有Mg，Ti，卤素和至少一种选自特定分子式（b）的二酯和烷基铝助催化剂的电子给体化合物的固体催化剂组分和（c）式 其中m为2至8的整数的R'OOC-（CR“2）m-COOR'，彼此相同或不同的R'基团独立地为C 1 -C 10烷基和R”基团，独立地 是氢或C1-C15烃基。

公开(公告)号：EP2121773A1

公开(公告)日：2009-11-25

申请号：EP07857394.6

申请日：2007-12-11

Applicant: Basell Poliolefine Italia S.R.L.

Inventor： MORINI, Giampiero ,  DALL'OCCO, Tiziano ,  LIGUORI, Dario ,  PATER, Joachim T. M. ,  VITALE, Gianni

IPC: C08F4/655 ,  C08F10/02

CPC classification number: C08F10/02 ,  C08F110/06 ,  C08F210/06 ,  C08F4/6557 ,  C08F4/6555 ,  C08F2500/12 ,  C08F2500/18 ,  C08F210/16

Abstract: A catalyst component comprising Ti, Mg, Al, Cl, and optionally ORI groups in which RI is a C1-C20 hydrocarbon group, optionally containing heteroatoms, up to an amount such as to give a molar ORI /Ti ratio lower than 0.5, characterized by the fact that substantially all the titanium atoms are in valence state of 4, that the porosity (PF), measured by the mercury method and due to pores with radius equal to or lower than 1μm, is at least 0.3 cm3/g, and by the fact that the Cl/Ti molar ratio is lower than 29. The said catalysts are characterized by high morphological stability under the low molecular weight ethylene polymerization conditions while at the same time maintaining characteristics of high activity.

公开(公告)号：EP2697271B1

公开(公告)日：2017-03-22

申请号：EP12711393.4

申请日：2012-03-29

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： GUIDOTTI, Simona ,  MORINI, Giampiero ,  ESPOSITO, Simona ,  MIGNOGNA, Alessandro ,  PATER, Joachim T. M. ,  PIEMONTESI, Fabrizio ,  BRITA, Diego

IPC: C08F10/06 ,  C08F4/651 ,  C08F2/00

CPC classification number: C08F4/16 ,  C08F10/06 ,  C08F4/651 ,  C08F110/06 ,  C08F2500/12 ,  C08F2500/15 ,  C08F2500/02 ,  C08F210/06 ,  C08F2/001

公开(公告)号：EP2771371B1

公开(公告)日：2016-12-07

申请号：EP12770490.6

申请日：2012-10-11

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： NIFANT'EV, Ilya ,  MIGNOGNA, Alessandro ,  BAGROV, Vladimir ,  ESPOSITO, Simona ,  GUIDOTTI, Simona ,  MORINI, Giampiero ,  PATER, Joachim T. M. ,  PIEMONTESI, Fabrizio ,  TOLORAYA, Sophia A.

IPC: C08F4/651 ,  C08F10/00 ,  C08F4/654

CPC classification number: C08F4/6498 ,  C08F10/00 ,  C08F4/6543 ,  C08F4/651